Hostname: page-component-586b7cd67f-r5fsc Total loading time: 0 Render date: 2024-11-29T08:17:25.495Z Has data issue: false hasContentIssue false

Contact Dependence of α-Sexithienyl Thin Film Transistor Characteristics

Published online by Cambridge University Press:  10 February 2011

Y. Y. Lin
Affiliation:
Electronic Materials and Processing Research Laboratory, The Pennsylvania State University, University Park, PA 16802
D. J. Gundlach
Affiliation:
Electronic Materials and Processing Research Laboratory, The Pennsylvania State University, University Park, PA 16802
T. N. Jackson
Affiliation:
Electronic Materials and Processing Research Laboratory, The Pennsylvania State University, University Park, PA 16802
Get access

Abstract

We have fabricated thin film transistors (TFTs) using ca-sexithienyl (α-6T) as the active material and have investigated the dependence of transistor characteristics on the choice of source/drain contact metal. Using α-6T synthesized from terthiophene and purified by vacuum gradient sublimation, we have fabricated TFTs with material deposited by evaporation onto substrates held at both room and elevated temperature. We have studied devices fabricated by depositing the active material onto previously patterned source/drain contacts and also by depositing the source/drain contacts after the active layer deposition, in both cases with the gate contact and dielectric underneath the active material. For both device types we find a clear dependence on the choice of source/drain contact metal with correlation to the metal work function. For our devices the best performance is obtained using metals with largest work function (Pd, Pt, or Au), intermediate performance is obtained using a metal with somewhat smaller work function (Cr), and significantly degraded performance is obtained using a metal with relatively small work function (Al). Despite the apparent correlation to the metal work function, we cannot yet rule out oxidation or other chemical effects with the more reactive metals. We have also examined doping of the α-6T layer as a possible route to improved contacts and find that FeCI3 can be used to shift the threshold voltage of α-6T TFTs by more than 50 V.

Type
Research Article
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Gamier, F., Horowitz, G., Peng, X., and Fichou, D., Advanced Materials, 2, p.592, (1990).Google Scholar
2. Dodabalapur, A., Torsi, L., and Katz, H.E., Science, 268, p.271, (1995).Google Scholar
3. Fichou, D., Horowitz, G., Nishikitani, Y. and Gamier, F., Chemtronics, 3, p.176, (1988).Google Scholar
4. Burroughes, J.H., Bradley, D.D.C., Brown, A.R., Marks, R.N., Machay, K., Friend, R.H., Bums, P.L. and Holmes, A.B., Nature, 347, p.539, (1990).Google Scholar
5. Kagan, J. and Arora, S., Heterocycles, 20, p.1937, (1983).Google Scholar
6. Luan, S. and Neudeck, G.W, J. Appl. Phys. 72(2), p.766, (1992).Google Scholar