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Competition Between Gettering by Implantation-Induced Cavities in Silicon and Internal Gettering Associated with SIO2 Precipitation

Published online by Cambridge University Press:  03 September 2012

S. A. McHugo
Affiliation:
Dept. of Materials Science and Mineral Eng., University of California, Berkeley, CA 94720 presently at: Advanced Light Source Center, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, [email protected]
E. R. Weber
Affiliation:
Dept. of Materials Science and Mineral Eng., University of California, Berkeley, CA 94720
S. M. Myers
Affiliation:
Sandia National Laboratories, P.O. Box 5800, Albuquerque, NM 87185
G. A. Petersen
Affiliation:
Sandia National Laboratories, P.O. Box 5800, Albuquerque, NM 87185
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Abstract

The gettering behavior of Cu and Fe was investigated in CZ silicon containing both internal-gettering sites in the bulk due to SiO2 precipitation and a device-side layer of cavities formed by He ion implantation and annealing. The objective was to quantify the effectiveness of impurity gettering at cavities relative to the widely used internal-gettering process. Both rapid thermal anneals and furnace anneals were used during the gettering sequences to reveal transient effects as well as the final, thermodynamically-equilibrated condition. For temperatures of 700, 800 and 850°C, the cavity gettering was observed to dominate the internal gettering as indicated both by the number of gettered atoms in the cavities and the residual solution concentration in the device region. The results are interpreted in detail by numerically solving the diffusion equation with sink-related source terms based on earlier, fundamental studies of the underlying mechanisms of internal and cavity gettering.

Type
Research Article
Copyright
Copyright © Materials Research Society 1997

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References

1. The National Technology Roadmap for Semiconductors (Semiconductor Industry Assoc., San Jose, CA, 1994), p. 110 Google Scholar
2. Materials Research Society Bulletin (Materials Research Society, Pittsburgh, PA, August 1994)Google Scholar
3. Tice, W.K. and Tan, T.Y., Mater. Res. Soc. Symp. Proc. 2, 367 (1981)Google Scholar
4. Gilles, D., Weber, E.R. and Hahn, S.K., Phys. Rev. Lett. 64, 196 (1990)Google Scholar
5. Aoki, M., Itakura, A. and Sasaki, N., Appl. Phys. Lett. 68, 51 (1995)Google Scholar
6. Wong, H., Cheung, N.W. and Chu, P.K., Appl. Phys. Lett. 52, 889 (1988)Google Scholar
7. Skorupa, W., Kogler, R., Schmalz, K., Gaworzewski, P., Morgenstren, G. and Syhre, H., Nuc. Instr. and Meth. in Phys. Res. B 74, 70 (1993)Google Scholar
8. Overwijk, M.H.F., Politiek, J., Kruif, R.C.M.d. and Zalm, P.C., Nuc. Instr. and Meth. in Phys. Res. B 96, 257 (1995)Google Scholar
9. Barbero, C.J., Corbett, J.W., Deng, C. and Atzmon, Z., J. Appl. Phys. 78, 3012 (1995)Google Scholar
10. Stolk, P.A., Benton, J.L., Eaglesham, D.J., Jacobson, D.C., Cheng, J.-Y., Poate, J.M., Myers, S.M. and Haynes, T.E., Appl. Phys. Lett. 68, 51 (1995)Google Scholar
11. Myers, S.M., Follstaedt, D.M., Bishop, D.M. and Medernach, J.W., in: Semiconductor Silicon, 7th International Symposium on Silicon Materials Science & Tech., edited by Huff, H.R., Bergholz, W. and Sumino, K., (The Electrochemical Society, Pennington, NJ, 1994), p. 808819 Google Scholar
12. Wong-Leung, J., Nygren, E. and Williams, J.S., Appl. Phys. Lett. 67, 416 (1995)Google Scholar
13. Raineri, V., Battaglia, A. and Rimini, E., Nuc. Instr. and Meth. in Phys. Res. B 96, 249 (1995)Google Scholar
14. Myers, S.M., Petersen, G.A. and Seager, C.H., J. Appl. Phys. 80, 3717 (1996)Google Scholar
15. Myers, S.M. and Follstaedt, D. M., J. Appl. Phys. 79, 1337 (1996)Google Scholar
16. McHugo, S.A., Mizuno, M., Kirscht, F.G. and Weber, E.R., Appl. Phys. Lett. 66, 2840 (1995)Google Scholar
17. Ziegler, J.F., Biersack, J.P. and Littmark, U., in: “The Stopping and Range of Ions in Solids”, (Pergamon, New York, 1985)Google Scholar
18. Griffioen, C.C., Evans, J.H., de Jong, P.C. and Van Veen, A., Nucl. Instrum. Methods B 27, 417 (1987)Google Scholar
19. Follstaedt, D.M., Myers, S.M., Petersen, G.A. and Medernach, J.W., J. Elec. Matls. 25, 151 (1996)Google Scholar
20. Weber, E.R., Appl. Phys. A 30, 1 (1983)Google Scholar
21. McHugo, S.A., Weber, E.R., Myers, S.M. and Petersen, G.A., submitted to J. Appl. Phys., 1996 Google Scholar
22. Miller, D.C. and Rozgonyi, G.A., in: “Handbook on Semiconductors”, ed. Keller, S. P. (North-Holland Publishing Company, 1980) p. 217246.Google Scholar
23. McHugo, S.A., Weber, E.R., Myers, S.M. and Petersen, G.A., Appl. Phys. Lett. 69, 3060 (1996)Google Scholar