Published online by Cambridge University Press: 10 February 2011
The growth modes and resulting microstructures of GaN films grown by Metalorganic Vapor Phase Epitaxy (MOVPE) on (0001) sapphire with either a simple nitridation of the surface and N2 as carrier gas or with a treatment of the nitridated surface under silane and ammonia with a mixture of H2 and N2 as carrier gas have been investigated. The second process results in a three dimensional first stage of the growth before a coalescence of the islands and the smoothing of the surface. Using this growth process, the defects density can be decreased down to 3.108 cm−2. This reduction in defect density has a drastic effect on photoluminescence properties of the material, and the luminescence efficiency can be increased by a factor of 20. It is also observed that the strain of this material is much higher as compared with material grown with the first process.