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Colloidal Crystal Wires from Directed Assembly

Published online by Cambridge University Press:  01 February 2011

Feng Li ,
Xavier Badel ,
Jan Linnros  and
John B. Wiley
Feng Li
Affiliation:
Department of Chemistry and the Advanced Materials Research Institute, University of New Orleans, New Orleans, LA 70148-2820U.S.A.
Xavier Badel
Affiliation:
Department of Microelectronics and Information Technology, KTH Royal Institute of Technology, SE-164 40 Kista, Sweden
Jan Linnros
Affiliation:
Department of Microelectronics and Information Technology, KTH Royal Institute of Technology, SE-164 40 Kista, Sweden
John B. Wiley
Affiliation:
Department of Chemistry and the Advanced Materials Research Institute, University of New Orleans, New Orleans, LA 70148-2820U.S.A.
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Abstract

Colloidal crystal wires with tubular-like packings are prepared by the directed assembly of spheres into cylindrical one-dimensional channels. Silica spheres are infiltrated into porous silicon membranes, treated with silane, and annealed. Single annealing cycles are found to result in colloidal crystal wires with varied packing geometries, while repeated annealing produces a thin translucent silica sheath around the wires. Packing in the wires varies with the relative channel diameter of the silicon membrane where typical wires contain 4 to 7 helical strands. Both chiral and achiral packing geometries are observed. The fabrication of these wires is discussed and the relationship between channel size and packing structure detailed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 872: Symposium J – Micro- and Nanosystems—Materials and Devices , 2005 , J20.3
Copyright
Copyright © Materials Research Society 2005

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References

1 Blaaderen, A. van, MRS. Bulletin, 85, 29, (2004).Google Scholar
2 Manoharan, V. N. and Pine, D. J., MRS Bulletin, 29, 91, (2004).Google Scholar
3 Colvin, V. L., MRS Bulletin, 26, 637 (2001).Google Scholar
4See for example: Ganser-Pornillos, B. K., Schwedler, U. K. von, Stray, K. M., Aiken, C., and Sundquist, W. I., J. Virology, 78, 2545(2004).Google Scholar
5 Erickson, R. O., Science, 181, 705 (1973).Google Scholar
6a) Jiang, P., Bertone, J. F., Hwang, K. S., and Colvin, V. L., Chem. Mater. 11, 2132 (1999).Google Scholar
(b) Jiang, P., Bertone, J. F., and Colvin, V. L., Science, 291, 453 (2001).Google Scholar
7 Yin, Y., Lu, Y., Gates, B., and Xia, Y., J. Am. Chem. Soc. 123, 8718 (2001).Google Scholar
8 Yin, Y., and Xia, Y., J. Am. Chem. Soc. 125, 2048 (2003).Google Scholar
9 Miguez, H., Yang, S. M., Tétreault, N., and Ozin, G. A., Adv. Mater. 14, 1805 (2002).Google Scholar
10 Moon, J. H., Kim, S., Yi, G.-R., Lee, Y.-H., and Yang, S. M., Langmuir 20, 2033 (2004).Google Scholar
11 Li, F., He, J., Zhou, W. L., and Wiley, J. B., J. Am. Chem. Soc., 125, 2048 (2003).Google Scholar
12 Pickett, G. T., Gross, M., and Okuyama, H. Phys. Rev. Lett., 85, 3652 (2000).Google Scholar
13 Li, F., Badel, X., Linnros, J., and Wiley, J. B. J. Am. Chem. Soc., 127, 3268 (2005).Google Scholar
14 Lehmann, V., J. Electrochem. Soc., 140, 2836 (1993).Google Scholar
15 Badel, Xavier, Ph.D. Dissertation, KTH Royal Institute of Technology, Kista, Sweden, 2005.Google Scholar