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Coaxial Electrospinning for Nanostructured Advanced Materials

Published online by Cambridge University Press:  01 February 2011

Ignacio G. Loscertales ,
Juan E. Díaz Gómez ,
M. Lallave ,
J. M. Rosas ,
Jorge Bedia ,
J. Rodríguez-Mirasol ,
T. Cordero ,
M. Marquez ,
S. Shenoy  and
G. E. Wnek
...Show all authors
Ignacio G. Loscertales
Affiliation:
[email protected], Universidad de Málaga, Ingeniería Mecánica y Mecánica de Fluidos, Plaza El Ejido, s/n, Malaga, 29013, Spain, +34-95-213-1323, +34-95-213-7468
Juan E. Díaz Gómez
Affiliation:
[email protected], Yflow SL, Marie Curie 4-12, Campanillas, Málaga, 29590, Spain
M. Lallave
Affiliation:
[email protected], Yflow SL, Marie Curie 4-12, Campanillas, Málaga, 29590, Spain
J. M. Rosas
Affiliation:
[email protected], ETS Ingenieros Industriales, Universidad de Málaga,, Dep. Ingeniería Química, Plaza El Ejido, s/n, Málaga, 29013, Spain
Jorge Bedia
Affiliation:
[email protected], ETS Ingenieros Industriales, Universidad de Málaga, Dep. Ingeniería Química, Plaza El Ejido, s/n, Málaga, 29013, Spain
J. Rodríguez-Mirasol
Affiliation:
[email protected], ETS Ingenieros Industriales, Universidad de Málaga, Dep. Ingeniería Química, Plaza El Ejido, s/n, Málaga, 29013, Spain
T. Cordero
Affiliation:
[email protected], ETS Ingenieros Industriales, Universidad de Málaga, Dep. Ingeniería Química, Plaza El Ejido, s/n, Málaga, 29013, Spain
M. Marquez
Affiliation:
[email protected], Research Center, Philip Morris USA, 4201 Commerce Road, Richmond, VA, 23234, United States
S. Shenoy
Affiliation:
[email protected], Virginia Commonwealth University, Chemical and Life Sciences Engineering, Richmond, VA, 23284-3028, United States
G. E. Wnek
Affiliation:
[email protected], Case Western Reserve University, Department of Macromolecular Science and Engineering, Cleveland, OH, 44106-7217, United States
T. Thorsen
Affiliation:
[email protected], Massachusetts Institute of Technology, Department of Mechanical Engineering, 77 Massachusetts Ave, Cambridge, MA, 02139-4307, United States
A. Fernández-Nieves
Affiliation:
[email protected], Harvard University, Division of Engineering and Applied Sciences, 40 Oxford Street, Cambridge, MA, 02138, United States
A. Barrero
Affiliation:
[email protected], Escuela Superior de Ingenieros, Universidad de Sevilla, Dep. Ingeniería Energética y Mecánica de Fluidos, Sevilla, 41092, Spain
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Abstract

Electro-hydro-dynamic (EHD) compound jets, with diameters in the micro and nanometric size range, from conical menisci of two co-flowing liquids, is a consolidated platform for the production of nanofibers with inner structure, in a process so-called coaxial electrospinning or co-electrospinning. In contrast to other multi-step template based procedures, the EHD methodology is much more simple and general since, firstly, a solid template is needless and, secondly, the process is seldom affected by the chemistry of the liquids. This gentle process allows selecting the liquid precursors depending on the application sought for the nanofibers. Here, we review different products obtained by this EHD technique: (1) solid and hollow carbon nanofibers from different precursors (polyacrylonitrile, polyvinylpyrrolidone and lignin), (2) nanofibers of biocompatible polymers encapsulating liquids in the form of beads, (3) spinning nanofibers of alginate and (4) in-fiber encapsulation of active microgels.

Keywords

core/shellcompositefiber
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 948: Symposium B – Structure, Processing and Properties of Polymer Nanofibers for Emerging Technologies , 2006 , 0948-B06-01
Copyright
Copyright © Materials Research Society 2007

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References

REFERENCES

1. Salata, O. V., J. Nanobiotechnol. 2 (2004) p. 3.Google Scholar
2. Serp, D., Cantana, E., Heinzen, C., Stockar, U. Von, Marison, I. W., Biotechnol. Bioeng. 70 (2000) p. 41.Google Scholar
3. Dersch, R., Steinhart, M., Boudriot, U., Greiner, A., Wendorff, J. H., Polym. adv. Technol. 16 (2005) p. 276.Google Scholar
4. Choi, Y. K., Sugimoto, K. I., Song, S. M. and Endo, M., Materials Letters 59 (2005) p. 3514. Figure 7. a) Microgel response in water at different pHs and temperatures. b) and c) microgels trapped inside PVP hydrogel dipped in a basic (b) and an acidic (c) aqueous solution, respectively. Scale bars are 6 μm. a) b) c)Google Scholar
5. Utada, A. S., Lorenceau, E., Link, D. R., Kaplan, P. D., Stone, H. A., Weitz, D. A., Science 308 (2005) p. 537.Google Scholar
6. Bognitzki, M; Hou, H; Ishaque, M.; Frese, T; Hellwig, M Schwarte, C.; Schaper, A; Wendorff, J. H.; Greiner, A AdV. Mater. 2000, 12, 637.Google Scholar
7. Ai, S; Lu, G; He, Q; Li, J J. Am. Chem. Soc. 2003, 125, 11140.Google Scholar
8. Liu, S. M.; Gan, L. M.; Zhang, W. D.; Zeng, H. C. Chem. Mater. 2002, 14, 1391.Google Scholar
9. Cao, H. Q.; Xu, Y; Hong, J. M.; Liu, H. B.; Yin, G; Li, B. L. Tie, C.Y.; Xu, Z AdV. Mater. 2001, 13, 1393.Google Scholar
10. Zelenski, C. M.; Dorhout, P. K. J. Am. Chem. Soc. 1998, 120, 734.Google Scholar
11. Martin, C. R. Science 1994, 266, 1961.Google Scholar
12. Cepak, V. M.; Martin, C. R. Chem. Mater. 1999, 11, 1363.Google Scholar
13. Martin, C. R. Chem. Mater. 1996, 8, 1738.Google Scholar
14. Loscertales, I. G., Barrero, A., Guerrero, I., Cortijo, R., Marquez, M., and Gañan Calvo, A. M., Science 295 (2002) p. 1695 Google Scholar
15. Larsen, G., Velarde-Ortiz, R., Minchow, K., Barrero, A., and Loscertales, I. G., J. Am. Chem. Soc. 125 (2003) p. 1154.Google Scholar
16. Sun, Z., Zussman, E., Yarin, A. L., Wendorff, J. H., and Greiner, A., Adv. Matter. 15 (2003) p. 1929.Google Scholar
17. Loscertales, I. G., Barrero, A., Marquez, M., Spretz, R., Velarde-Ortiz, R., and Larsen, G., J. Am. Chem. Soc. 126 (2004) p. 5376.Google Scholar
18. Li, D., and Xia, Y., Nano Lett. 4 (2004) p. 933.Google Scholar
19. Yu, J. H., Fridrikh, S. V., and Rutledge, G. C., Adv. Mater. 16 (2004) p. 1562.Google Scholar
20. Chun, I., Reneker, D. H., Fong, H., Famg, X., Deitzel, J., Tan, N. B., and Kearns, K., J. Adv. Mater. 31 (1996) p. 36.Google Scholar
21. Zussman, E., Yarin, A. L., Bazilevsky, A.V., Avrahami, R., and Feldman, M., Adv. Matter. 18 (2006) p. 348.Google Scholar
22. Iovleva, M. M., Smirnova, V. N., and Budnitskii, G. A., Fibre Chem. 33 (2001) p. 262.Google Scholar
23. Beattie, P. D. et. al., “Fluid diffusion layers for fuel cells”, United States Patent: 6,667,127 (December 23, 2003).Google Scholar
24. Kubo, S., Uraki, Y. and Sano, Y., Carbon 36 (1998) p. 1119.Google Scholar
25. Kadla, J.F., Kubo, S., Venditti, R.A., Gilbert, R.D., Compere, A.L., and Griffith, W., Carbon 40 (2002) p. 2913.Google Scholar
26. Kadla, J.F., Kubo, S., Venditti, R.A., and Gilbert, R.D., J. of Appl. Polym. Sci. 85 (2002) p. 1353.Google Scholar
27. Rivas, M. L., Bedia, J., Ruiz-Rosas, R., Rodríguez-Mirasol, J., Cordero, T., Otero, J. C., Marquez, M., Barrero, A., Loscertales, I. G., Alcell lignin as a new precursor for carbon nanofibers-nanotubes production by electrospinning, in preparation.Google Scholar
28. Sanders, E. H., Kloefkorn, R., Bowlin, G. L., Simpson, D. G., and Wnek, G. E., Macromolecules 36 (2003) p. 3803.Google Scholar
29. Kenawy, E., Bowlin, G. L., Mansfield, K., Layman, J., Simpson, D. G., Sanders, E. H., and Wnek, G. E., J. Controlled Release 81 (2002) p. 57.Google Scholar
30. Díaz, J. E., Barrero, A., Márquez, M., and Loscertales, I. G., Adv. Funct. Mater. 16 (2006) p. 2110.Google Scholar
31. Rudhardt, D., Fernandez-Nieves, A., Link., D. R., and Weitz, D. A., Appl. Phys. Lett. 82 (2003) p. 2610.Google Scholar
32. Fernandez-Nieves, A., Link, D. R., and Weitz, D. A., Appl. Phys. Lett. 88 (2006) p. 121911.Google Scholar
33. Viswanathamurthi, P., Bhattarai, N., Kim, C.K., Kim, H.Y., and Lee, D.R., Inorg. Chem.Commu. 7 (2004) p. 679.Google Scholar
34. McCann, J. T., Li, D. and Xia, Y., J. Mater. Chem. 15 (2005) p. 735.Google Scholar
35. Panels, J. E. and Joo, Y. L., J. Nanomater. 2006 (2006) ID 41327.Google Scholar
36. Wang, M., Yu, J. H., Kaplan, D. L., and Rutledge, G. C., Macromolecules 39 (2006), p. 1102.Google Scholar
37. Jiang, H., Hu, Y., Li, Y., Zhao, P., Zhu, K., and Chen, W., J. Controlled Release 108 (2005) p. 237.Google Scholar
38. Diaz, J. E., Lallave, M., Galan, D., Marquez, M., Barrero, A., Loscertales, I. G., Fiber Society Spring 2005 Conf., St. Gallen, Switzerland, May 25 – 27, 2005.Google Scholar
39. Bhattarai, N., Li, Z., Edmondson, D., and Zhang, M., Adv. Mater. 18 (2006) p. 1463.Google Scholar
40. Lu, J., Zhu, Y., Guo, Z., Hu, P., and Yu, J., Polymer 47 (2006) p. 8026.Google Scholar
41. Fernández-Nieves, A., Fernández-Barbero, A., Vincent, B., and Nieves, F. J. de las, Macromolecules 33 (2000) p. 2114.Google Scholar
42. Saunders, B., Vincent, B., Adv. Colloid Interface Sci. 80 (1999) p. 1.Google Scholar