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Chemisorption of Moisture-Induced Hydrogen and the Embrittlement Effects in Transition Metal Aluminides

Published online by Cambridge University Press:  22 February 2011

Jian-Sheng Wang*
Affiliation:
Division of Applied Sciences, Harvard University, Cambridge, MA 02138.
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Abstract

Based on simple thermodynamic models free energies of chemisorption of water vapor in transition metal aluminides and enthalpies and entropies of formation of solid solutions of hydrogen in the aluminides are derived. Susceptibilities of the aluminides to moisture-induced embrittlement are evaluated with these thermodynamic properties and compared with the susceptibilities to hydrogen-induced embrittlement.

Type
Research Article
Copyright
Copyright © Materials Research Society 1995

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