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Characterization of Silicon Carbide thin Films Deposited by Laser Ablation on [001] and [111] Silicon Wafers

Published online by Cambridge University Press:  25 February 2011

L. Rimai
Affiliation:
Ford Motor Co. Research Staff P.O. Box 2053, MD 3028 Dearborn MI 48121–2053
R. Agar
Affiliation:
Ford Motor Co. Research Staff P.O. Box 2053, MD 3028 Dearborn MI 48121–2053
E. M. Logothetis
Affiliation:
Ford Motor Co. Research Staff P.O. Box 2053, MD 3028 Dearborn MI 48121–2053
W. H. Weber
Affiliation:
Ford Motor Co. Research Staff P.O. Box 2053, MD 3028 Dearborn MI 48121–2053
J. Hangas
Affiliation:
Ford Motor Co. Research Staff P.O. Box 2053, MD 3028 Dearborn MI 48121–2053
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Abstract

Stoichiometric films of 3C SiC, 50 to 1000 nm thick were deposited on Si wafers by laser ablation of ceramic stoichiometric SiC targets. Films grown at substrate temperatures above 1000° C on [001] and above 900° C on [111] show orientation epitaxial to the Si substrate along the film normal. Depending on the deposition conditions, the oriented crystallite dimension along this direction ranges from 20 nm to over 100 nm. The crystallite dimensions in the film plane range from 20 to 70 nm. Raman spectra show the expected TO and LO lines from SiC but indicate that the films sometimes contain other material, for example (30 to 50 Å) graphitic inclusions or small amounts of polycrystalline silicon.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

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References

REFERENCES

1. Powell, J. A. and Matus, L. G. in Amorphous and Crystalline Silicon Carbide and Related Materials, Springer Proceedings in Physics, edited by Harris, G. L and Yang, C. Y.-W. Vol. 34, p 2, Springer, Berlin, 1989.Google Scholar
2. Matus, L. G. and Powell, J. A., in Amorphous and Crystalline Silicon Carbide and Related Materials, Springer Proceedings in Physics, edited by Harris, G. L. and Yang, C. Y.-W. Vol. 34, p 40, Springer, Berlin, 1989.Google Scholar
3. Nishino, S. and Saraie, J., in Amorphous and Crystalline Silicon Carbide and Related Materials, Springer Proceedings in Physics, edited by Harris, G. L. and Yang, C. Y.-W. Vol. 34, p 45, Springer, Berlin, 1989.Google Scholar
4. Chaudhry, M. I. and Wright, R. L., J. Mater. Res. 5, 1595 (1990).Google Scholar
5. Onuma, Y., Nagaune, F. and Kamimura, K. in Amorphous and Crystalline Silicon Carbide and Related Materials, Springer Proceedings in Physics, edited by Harris, G. L. and Yang, C Y.-W. Vol. 34, p 142, Springer, Berlin, 1989.Google Scholar
6. Powell, J. A., Larkin, D. J., Matus, L. G., Choyke, W. J., Bradshaw, J. L., Henderson, L., Yoganathan, M., Yang, J. and Pirouz, P., Appl. Phys. Lett. 56, 1442 (1990).Google Scholar
7. Inoue, Y., Nakashima, S., Mitsuishi, A., Tabata, S., and Tsuboi, S., Solid State Commun. 48, 1071 (1983).Google Scholar
8. Balooch, M., Tench, R. J., Sielhaus, W. J., Allen, M. J., Connor, A. L. and Olander, D. R., Appl. Phys. Lett. 57, 1540 (1990).Google Scholar
9. Tench, R. J., Balooch, M., Connor, A. L., Bernardez, L., Oison, B., Allen, M. J., Siekhaus, W. J. and Olander, D. R., in Laser Ablation for Materials Synthesis, edited by Paine, D. C and Bravman, J. C., Mat. Res. Soc. Symposium Proc. Vol 191, p 61, 1990.Google Scholar
10. Rimai, L., Ager, R., Logothetis, E. M., Weber, W. H. and Hangas, J., Appl. Phys. Lett. 59, 2266(1991).Google Scholar
11. Feng, Z. C., Mascarenhas, A. J., Choyke, W. J. and Powell, J. A., J. Appl. Phys. 64, 3176 (1988)Google Scholar
12. Tuinstra, F. and Koenig, J. L., J. Chem. Phys. 53, 1126 (1970)Google Scholar
13. Hon, D. T. and Faust, L., Appl. Phys. 1, 241 (1973)Google Scholar
14. Richter, H., Wang, Z.P., and Ley, L., Solid State Commun. 39, 625 (1981).CrossRefGoogle Scholar
15. Knight, D. S. and White, W. B., J. Mater. Res. 4, 385 (1989)CrossRefGoogle Scholar