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Published online by Cambridge University Press: 21 February 2011
Heteroepitaxial InxGa1−xAs/GaAs structures have been formed by pulsed laser induced mixing of molecular beam deposited In films (˜200Å) on Si doped n+-GaAs (100) substrates. The Si dopant and deposited In are redistributed in a rapid melt-solidification process driven by a XeCl pulsed excimer laser. It is found, from high resolution cross-sectional transmission electron microscopy, that the epitaxial layers are crystalline and lattice matched to the substrate except for the misfit dislocations lying along the InxGa1−xAs/GaAs interface. These interfacial dislocations are used to identify the laser melted and unmelted regions. The dip and pile-up regions in the Si SIMS profiles are attributed to a segregation effect. Numerical simulation based on the liquid-solid interface velocity dependent segregation coefficient is used to investigate this effect and has approximated the trends in the measured characteristic In and Si profiles.