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Ceramic Thin Films on Organic Self-Assembled Monolayers: Synthesis and the Mechanism of Formation

Published online by Cambridge University Press:  10 February 2011

U. Sampathkumaran ,
S. Supothina ,
R. Wang  and
M. R. De Guire
U. Sampathkumaran
Affiliation:
Department of Materials Science and Engineering, Case Western Reserve University, Cleveland, OH 44106–7204, USA., [email protected]
S. Supothina
Affiliation:
Department of Materials Science and Engineering, Case Western Reserve University, Cleveland, OH 44106–7204, USA., [email protected]
R. Wang
Affiliation:
School of Dentistry, Case Western Reserve University, Cleveland, OH 44106–7204, USA., [email protected]
M. R. De Guire
Affiliation:
Department of Materials Science and Engineering, Case Western Reserve University, Cleveland, OH 44106–7204, USA., [email protected]
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Abstract

In recent years, several research groups have pursued biomimetic or bio-inspired techniques for the synthesis of ceramic thin films from aqueous solutions at low temperatures. The substrates range from inorganic materials (metals, glass, single-crystal silicon) without special surface preparation, to functionalized organic surfaces such as self-assembled organic monolayers (SAMs). Our results on the deposition of tin (IV) oxide (SnO2, cassiterite) and hydroxyapatite (Ca10(PO4)6(OH)2) thin films on SAMs will be reviewed. The former system forms films via assembly of nano-scale particles on the substrate, while the latter system appears to form films via heterogeneous nucleation. In both cases, the role of the substrate in film formation is discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 599: Symposium DD – Mineralization in Natural & Synthetic Biomaterials , 1999 , 177
Copyright
Copyright © Materials Research Society 2000

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