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Cathodoluminescence of Am3+ in zircon, (Zr,Pu,…)SiO4, and garnet, (Y,Gd,…)3(Al,Ga,…)5O12

Published online by Cambridge University Press:  11 February 2011

Maria V. Zamoryanskaya ,
John M. Hanchar ,
Boris E. Burakov  and
Vladimir M. Garbuzov
Maria V. Zamoryanskaya
Affiliation:
V.G. Khlopin Radium Institute, 28, 2-nd Murinskiy ave., St. Petersburg, 194021, Russia, fax: (7)-(812)-346–1129; e-mail: [email protected] and [email protected];
John M. Hanchar
Affiliation:
The George Washington University, Department of Earth and Environmental Sciences, Washington DC, 20006, USA, fax: 202–994–0450, e-mail: [email protected]
Boris E. Burakov
Affiliation:
V.G. Khlopin Radium Institute, 28, 2-nd Murinskiy ave., St. Petersburg, 194021, Russia, fax: (7)-(812)-346–1129; e-mail: [email protected] and [email protected];
Vladimir M. Garbuzov
Affiliation:
V.G. Khlopin Radium Institute, 28, 2-nd Murinskiy ave., St. Petersburg, 194021, Russia, fax: (7)-(812)-346–1129; e-mail: [email protected] and [email protected];
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Abstract

Ceramic waste forms based on garnet, (Y,Gd,An‥)3(Al,Ga,An‥)5O12, and zircon, (Zr,An‥)SiO4, where An=U, Pu, Np, Am, and Cm have been proposed for the immobilization of weapons-grade plutonium and other actinides. The lattice capacity of these materials depends on the valence state and ionic radius of the substitute ions. The method of cathodoluminescence (CL) allows the determination of the valence state of different ions (e.g., some transition metals, lanthanides, and actinides) in ceramic. There is a lack of information in the literature concerning CL properties of actinide ions. Cathodoluminescence images and emission spectra of synthetic yttrium-aluminum garnet, gallium-gadolinium garnet and zircon doped with Am were studied. Americium ion has three groups of lines of CL in visible region at 1.6eV, 1.9eV and 2.3eV. The interpretation of these lines has been done using the results of absorption spectra of Am in solution and in crystal LaCl3. There are f-f transitions of Am3+ ion. The ratio of intensities and the structure of these lines depend on the matrix. However, the spectral positions of these lines in two types of garnets and in zircon coincide. It was conclude that these lines can be used for identification of Am3+ ion in different crystalline matrices.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 757: Symposium II – Scientific Basis for Nuclear Waste Management XXVI , 2002 , II3.24
Copyright
Copyright © Materials Research Society 2003

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References

REFERENCES

1. Burakov, B. E., Proc. Intern. Conf. SAFE WASTE'93, 13–18/06/1993, Avignon, France, 2, 19–28 (1993).Google Scholar
2. Anderson, E.B., Burakov, B.E., Vasiliev, V.G., Proc. Intern. Conf. SAFE WASTE'93, 13–18/06/1993, Avignon, France, 2, 29–33 (1993).Google Scholar
3. Prunier, C., Salvatores, M., Guerin, Y., Zatta, A., Proc. Intern. Conf. SAFE WASTE'93, 13–18/06/1993, Avignon, France, 2, 298–311 (1993).Google Scholar
4. Ewing, R. C., Lutze, W., Weber, W. J., J. Mater. Res., 10, 243–246 (1995).Google Scholar
5. Ewing, R. C., Weber, W. J., Lutze, W., Disposal of Weapon Plutonium, ed. Merz, E.R. and Walter, C.E., Kluwer Academic Publishers, Dordrecht, pp. 65–83 (1996).Google Scholar
6. Burakov, B. E., Anderson, E. E., Ya, B.. Galkin, Starchenko, V. A., Vasiliev, V. G., Disposal of Weapon Plutonium ed. Merz, E.R. and Walter, C.E., Kluwer Academic Publishers, Dordrecht, pp. 85–89 (1996).Google Scholar
7. Burakov, B.E., Strykanova, E.E., Proc. Intern. Symp. Waste Management’98, CD-ROM, sess. 34 - 05, (1998).Google Scholar
8. Burakov, B.E., Anderson, E.B., Proc. 2nd NUCEF Intern. Symp. NUCEF'98, 16–17/11/1998, Hitachinaka, Ibaraki, Japan, JAERI-Conf.99–004 (Part I), 295–306 (1998).Google Scholar
9. Burakov, B.E., Anderson, E.B., Knecht, D.A., in Environmental Issues and Waste Management Technologies IV, 349–356 (1999).Google Scholar
10. Burakov, B.E., Anderson, E.B., Knecht, D.A., Zamoryanskaya, M.V., Strykanova, E.E., Yagovkina, M.V., Mat. Res. Soc. Symp. Proc. Scientific Basis for Nuclear Waste Management XXII, 556, 55–62 (1999).Google Scholar
11. Burakov, B.E., Anderson, E.B., Zamoryanskaya, M.V., Petrova, M.A., Mat. Res. Soc. Symp. Proc. Scientific Basis for Nuclear Waste Management XXIII, 608, 419–422 (2000).Google Scholar
12. Burakov, B.E., Anderson, E.B., Zamoryanskaya, M.V., Yagovkina, M.A., Strykanova, E.E., Nikolaeva, E. V., Mat. Res. Soc. Symp. Proc. Scientific Basis for Nuclear Waste Management XXIV, Sydney, Australia, 663 (2001).Google Scholar
13. Anderson, E.B., Burakov, B.E., Proc. Intern. Conf. GLOBAL'01, 9/13/2001, CD-ROM, paper 010 (2001).Google Scholar
14. Burakov, B.E., Anderson, E.B., Zamoryanskaya, M.V., Nikolaeva, E.V., Strykanova, E.E., Yagovkina, M.A., Proc. Intern. Conf. GLOBAL'01, 9/13/2001, CD-ROM, paper 006 (2001).Google Scholar
15. Burakov, B.E., Anderson, E.B., Proc. Intern. Conf. ICEM'01, 30/09–4/10/2001, CD-ROM, sess. 39 (2001).Google Scholar
16. Burakov, B.E., Hanchar, J.M., Zamoryanskaya, M.V., Garbuzov, V.M., Zirlin, V.A., Radiochimica Acta 89, 1–3 (2002).Google Scholar
17. Zamoryanskaya, M.V., Vainshenker, I.A., Zamoryanskyi, A.N., Equipment and Technique of Experiment, 4, p. 16 (1987), in Russian.Google Scholar
18. Carnall, W.T. and Crosswhite, H.M., Optical spectra and electronic structure of actinide ions in compounds and in solution, Argonne National Laboratory, (1985).Google Scholar
19. Hessler, J.P., Carnall, W.T., Am. Chem. Soc. Symposium Series, 131, p. 349 (1980).Google Scholar