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Catalytic Hydrogenation with Amorphous and Crystalline Pd8 0Si2 0

Published online by Cambridge University Press:  15 February 2011

Bill C. Giessen ,
Sabri S. Mahmoud ,
David A. Forsyth  and
Markus Hediger
Bill C. Giessen
Affiliation:
Materials Science Division, Institute of Chemical Analysis * Department of Chemistry, Northeastern University, Boston, Massachusetts 02115, U.S.A.
Sabri S. Mahmoud
Affiliation:
Materials Science Division, Institute of Chemical Analysis * Department of Chemistry, Northeastern University, Boston, Massachusetts 02115, U.S.A.
David A. Forsyth
Affiliation:
Materials Science Division, Institute of Chemical Analysis * Department of Chemistry, Northeastern University, Boston, Massachusetts 02115, U.S.A.
Markus Hediger
Affiliation:
Materials Science Division, Institute of Chemical Analysis * Department of Chemistry, Northeastern University, Boston, Massachusetts 02115, U.S.A.
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Abstract

Several metallic glasses in the form of ribbons were screened for activity as hydrogenation catalysts. Pd80Si20 and (Ni50Fe50)80B20 showed activity in reducing cyclohexene. Pd 80 Si20 was further examined for differences between the glassy and crystalline phases in the selectivity shown during hydrogenation reactions of n-hexenes, phenylethyne, α-pinene, and cyclododecene. No significant differences were found for catalytic selectivity in regard to cis-trans isomerization, double bond migration, and stereochemistry of addition under the reaction conditions used. Minor differences were observed in hydrogen-deuterium exchange.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 8 , 1981 , 255
Copyright
Copyright © Materials Research Society 1982

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Footnotes

*

Communication No. 116 from the Institute of Chemical Analysis

References

REFERENCES

1.Yokoyama, A., Homiyama, H., Inoue, H., Masumotoand, T., Kimura, H.M., J. Catal., 68, 355 (1981).10.1016/0021-9517(81)90104-4Google Scholar
2.Brower, W.E. Jr., Matyjaszczyk, M., Smith, G.V. and Fettit, T., Meeting Abstract in J. Metals, 97 (1979).Google Scholar
3.Polk, D.E. and Giessen, B.C. “Metallic Glasses”, Gilman, J.J. and Leamy, H.J., Eds., ASM Materials Science Seminar Series, American Society for Metals, Metals Park, Ohio, 1978, Chapter 1.Google Scholar
4.Forsyth, D.A., Hediger, M., Mahmoud, S.S. and Giessen, B.C., Analyt. Chem., submitted.Google Scholar
5.Forsyth, D.A., Mahmoud, S.S. and Giessen, B.C., Org. Magn. Reson., in press.Google Scholar