Hostname: page-component-586b7cd67f-t7czq Total loading time: 0 Render date: 2024-11-29T14:14:00.739Z Has data issue: false hasContentIssue false
  • English
  • Français

Carbon Onion Films-Molecular Interactions of Multi-Layer Fullerenes

Published online by Cambridge University Press:  31 January 2011

Raed A. Alduhaileb ,
Virginia M. Ayres ,
Benjamin W. Jacobs ,
Xudong Fan ,
Kaylee McElroy ,
Martin Crimp ,
Atsushi Hirata  and
Mutsumi Horikoshi
Raed A. Alduhaileb
Affiliation:
[email protected], Michigan State University, East Lansing, Michigan, United States
Virginia M. Ayres
Affiliation:
[email protected], Michigan State University, East Lansing, Michigan, United States
Benjamin W. Jacobs
Affiliation:
[email protected], Michigan State University, East Lansing, Michigan, United States
Xudong Fan
Affiliation:
[email protected], Michigan State University, East Lansing, Michigan, United States
Kaylee McElroy
Affiliation:
[email protected], Michigan State University, East Lansing, Michigan, United States
Martin Crimp
Affiliation:
[email protected], Michigan State University, East Lansing, Michigan, United States
Atsushi Hirata
Affiliation:
[email protected], Tokyo Institute of Technology, Tokyo, Japan
Mutsumi Horikoshi
Affiliation:
[email protected], Tokyo Institute of Technology, Tokyo, Japan
Get access

Abstract

The evolution of carbon onion structure from spherical to polyhedral is correlated with changes in the sp3/sp2 ratio as a function of increasing synthesis temperature using electron energy loss spectroscopy, scanning electron microscopy, and high resolution electron microscopy. Results that are obtained using asymmetric f-variance versus symmetric Gaussian deconvolution of electron energy loss spectra are compared. The possibility of a separate peak at 287 eV is discussed.

Keywords

Clubricantchemical synthesis
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1204: Symposium K – Nanotubes and Related Nanostructures-2009 , 2009 , 1204-K05-70
Copyright
Copyright © Materials Research Society 2010

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Hirata, A., Igarashi, M. and Kaito, T., Tribol. Int. 37, 899 (2004).Google Scholar
2. Mykhaylyka, O. O., Solonin, Y. M., Batchelder, D. N. and Brydson, R., J. Appl. Phys. 97, 074302 (2005).Google Scholar
3. Osswald, S., Yushin, G., Mochalin, V., Kucheyev, S. O. and Gogotsi, Y., J. Am. Chem. Soc. 128, 11635 (2006).Google Scholar
4. Egerton, R., “Chapter 3: Electron Scattering Theory,” Electron Energy Loss Spectroscopy in the Electron Microscope (Plenum Press, New York, NY, 1986) pp. 129–228.Google Scholar
5. Brydson, R., Zhili, Z. and Brown, A., “Revisiting the Determination of Carbon sp3/sp2 Ratios via Analysis of the EELS Carbon K-edge,” EMC 2008: Vol 1: Instrumentation and Methods, edited by Luysberg, M., Tillmann, K. and Weirich, T. (Springer-Verlag, Berlin, Germany, 2008) pp. 357–358.Google Scholar
6. Papworth, A. J., Kiely, C. J., Burden, A. P., Silva, S. R. and Amaratunga, G. A., Phys. Rev. B62, 12628 (2000).Google Scholar