Hostname: page-component-cd9895bd7-fscjk Total loading time: 0 Render date: 2024-12-27T01:41:10.323Z Has data issue: false hasContentIssue false

An Approach to High Quality a-Ge:H by VHF Deposition

Published online by Cambridge University Press:  01 January 1993

Ralf Zedlitz
Affiliation:
Institut für Physikalische Elektronik, Universität Stuttgart, Pfaffenwaldring 47, D-7000 Stuttgart 80, F.R.Germany
Moritz Heintze
Affiliation:
Institut für Physikalische Elektronik, Universität Stuttgart, Pfaffenwaldring 47, D-7000 Stuttgart 80, F.R.Germany
Gottfried H. Bauer
Affiliation:
Institut für Physikalische Elektronik, Universität Stuttgart, Pfaffenwaldring 47, D-7000 Stuttgart 80, F.R.Germany
Get access

Abstract

Amorphous hydrogenated germanium a-Ge:H was deposited by very high frequency glow discharge (VHF-GD) at frequencies between 25 and 220MHz, low pressure (2.5Pa) and high deposition rates (≤4Á /s) on both electrodes of a parallel plate reactor. The films are comparable to material deposited on the powered electrode of a conventional RF-GD. Mobility-lifetime products ηµτ for photogenerated charge carriers around 10-7cm2/V and a Fermi level position at EC-EF≈400meV indicate good opto-electronic properties. The IR spectra show that the samples are free of oxydization and incorporate slightly more voids than the RF material. Measurements of ion energy Ei and flux Фi in the substrate plane show that “hard&” preparation conditions are obtained comparable to the deposition on the powered electrode of an RF-GD.

Type
Research Article
Copyright
Copyright © Materials Research Society 1993

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] Curtins, H., Wyrsch, N., Favre, M., Prasad, K., Breset, M. and Shah, A.V., MRS Symp.Proc. 95 (1987) 249 Google Scholar
[2] Finger, F., Kroll, U., Viret, V., Shah, A., Beyer, W., Tang, X.-M., Weber, J., Howling, A., Hollenstein, C., J.Appl.Phys. 71 (1992) 5665 Google Scholar
[3] Shah, A., Dutta, J., Wyrsch, J., Prasad, K. Prasad, Curtins, H., Finger, F., Howling, A., Hollenstein, C., MRS Symp.Proc. 258 (1992) 15 Google Scholar
[4] Heintze, M., Zedlitz, R. and Bauer, G.H., this volumeGoogle Scholar
[5] Kaspar, W., Plättner, R., Eichmeier, J., J.Non-Cryst.Sol. 137&138 (1991) 799 Google Scholar
[6] Paul, W., Jones, S.J., Turner, W.A. and Wickboldt, P., J.Non-Cryst.Sol. 141 (1992) 271 Google Scholar
[7] Karg, F., Böhm, H., Pierz, K., J.Non-Cryst.Sol. 114 (1989) 477 Google Scholar
[8] Wetsel, A.E., Jones, S.J., Turner, W.A., Pang, D., Paul, W., Zawawi, I. El, Bouizem, Y., Chahed, L., Theye, M.L., Marques, F.C., Chambouleyron, I., MRS Symp.Proc 192 (1990) 547 Google Scholar
[9] Kaspar, W., Böhm, H., Hirschauer, B., J.Appl.Phys. 71 (1992) 4168 Google Scholar
[10] Müller, K.-H., Phys.Rev. B35 (1987) 7906 Google Scholar
[11] Yehoda, J.E., Yang, B., Vedam, K. and Messier, R., J.Vac.Sci.Technol. A6 (1988) 1631 Google Scholar
[12] Surendra, M. and Graves, D.B., Appl.Phys.Lett. 59 (1991) 2091 Google Scholar
[13] Zedlitz, R., Heintze, M. and Bauer, G.H., MRS Symp. Proc. 258 (1992) 147 Google Scholar
[14] Liu, J., Huppert, G.L. and Sawin, H.H., J. Appl. Phys. 68 (1990) 3916 Google Scholar
[15] Mahan, A.H., Raboisson, P. and Tsu, R., Appl.Phys.Lett. 50(6), 335 (1987)Google Scholar
[16] Cardona, M., phys.stat.sol.(b) 118 (1983) 463 Google Scholar
[17] Heintze, M., Eberhardt, K., Kessler, F., Bauer, G.H. in Proc. 10th EC Photovoltaic Solar Energy Conference ed. by Luque, A. et al. Kluwer Acad.Publ., Dortrecht (1991) 1075 Google Scholar
[18] Eberhardt, K. et al. , presented at: 11th EC Photovolt. Sol. En. Conf. (Montreux 1992)Google Scholar
[19] Graeff, C.F.O., to be published;Google Scholar