Hostname: page-component-78c5997874-g7gxr Total loading time: 0 Render date: 2024-11-19T05:03:37.569Z Has data issue: false hasContentIssue false

An Analysis Of Void Nucleation In Passivated Interconnect Lines Due To Vacancy Condensation And Interface Contamination

Published online by Cambridge University Press:  15 February 2011

R. J. Gleixner
Affiliation:
Department of Materials Science and Engineering, Stanford University, Stanford, CA 94305–2205
W. D. Nix
Affiliation:
Department of Materials Science and Engineering, Stanford University, Stanford, CA 94305–2205
Get access

Abstract

Nucleation of voids due to vacancy condensation in passivated aluminum lines is analyzed within the context of classical nucleation theory. A discussion of sources of hydrostatic tensile stress in such lines provides a reasonable upper limit of 2 GPa. The void nucleation rate is then calculated at various sites within the line. Results suggest that nucleation rates are far too low to account for observed rates of voiding. Void nucleation at a flaw at the line/passivation interface is then considered as an alternative nucleation mechanism. Such flaws may be created by contaminants introduced during fabrication of the line. In this case, nucleation is feasible at greatly reduced stresses, well within the observed values. Furthermore, a simple model of void growth indicates that a fast atomic transport path, such as a grain boundary, must intersect the void for an appreciable growth rate. These results suggest that void nucleation in aluminum interconnect lines occurs at flaws at the sidewall of the line and that stress-induced and electromigration-induced voiding can be controlled by eliminating interfacial contamination.

Type
Research Article
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Materials Reliability in Microelectronics III, edited by Rodbell, K. P., Filter, W. F., Frost, H. J., and Ho, P. S. (Materials Research Society, Pittsburgh, PA 1993), vol. 309.Google Scholar
2 Stress-Induced Phenomena in Metallization: 2nd Intl. Workshop, edited by Ho, P. S., Li, C.-Y., and Totta, P. (American Institute of Physics, New York 1994).69, 12 (1991)Google Scholar
3 Korhonen, M.A., Paskiet, C.A., and Li, C.-Y. J Apply Phys. 69 12 (1991)Google Scholar
4 Bower, F. and Freund, L. B., in Stress-Induced Phenomena in Metallization: 2nd Intl. Workshop, edited by Ho, P. S., Li, C.-Y., and Totta, P. A. (American Institute of Physics, New York, 1994), pp. 137152.Google Scholar
5 Trattles, J. T., O'Neill, A. G., and Mecrow, B. C., J. Appl. Phys. 75, 7799 (1994).Google Scholar
6 Arzt, E., Kraft, O., and Mdckl, U. E., in Thin Films: Stresses and Mechanical Properties IV, edited by Townsend, P. H., Weihs, T. P., Sanchez, J. E. Jr., and Borgesen, P. (Materials Research Society, Pittsburgh, PA 1994), vol. 388, pp. 397408.Google Scholar
7 Greenbaum, B, Sauter, A.I., Flinn, P.A. Nix, W.D., Appl. Phys. Lett. 58 1845 (1845)Google Scholar
9 Sauter, A. I., Dissertation, Ph. D., Stanford University, 1991, chap. 4.Google Scholar
10 Raj, R. and Ashby, M. F., Acta Metall. Mater. 23, 653 (1975).Google Scholar
11 Hirth, E. P.. Kraft, O.,. Nix, W. D.,Sanchez, J. E. J., J. Apply. Phys. 76, 1563 (1994).Google Scholar
13 Christian, J. W., The Theory of Transformations in Metals and Alloys: Part I (Pergamon, Oxford, 1975), chap. 10.Google Scholar
14 Frost, H. J. and Ashby, M., Deformation-Mechanism Maps (Pergamon, Oxford, 1982), p. 21.Google Scholar
15 Shewmon, P, Diffusion in Solids (TMS, Warrendale, PA, 1989), p. 78.Google Scholar
16 Murr, L. E., Interfacial Phenomena in Metals and Alloys (Addison-Wesley, Reading, MA, 1975)p124 Google Scholar
17 Nikolopoulos, P., Journal of Materials Science 20, 3993 (1995).Google Scholar
18 Gleixner, R. J. and Nix, W. D., submitted to J. Appl. Phys.Google Scholar
19 Flinn, P. A., MRS Bulletin XX(11), 70 (1995).Google Scholar
20 Abe, H., Tanabe, S., Kondo, Y., and Ikubo, M., in Japan Society of Applied Physics, 39th Spring Meeting, (1992), p. 658.Google Scholar
21 Murarka, P. and Peckerar, M. C., Electronic Materials: Science and Technology (Academic Press, San Diego 1989) pp.522523 Google Scholar
22 Marieb, T., Ph.D. Dissertation, Starnford University, 1994.Google Scholar