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“Aggregation in Block Copolymer Solutions”

Published online by Cambridge University Press:  21 February 2011

M. Olvera de la Cruz
M. Olvera de la Cruz*
Affiliation:
Department of Materials Science and Engineering, Northwestern University, Evanston, Il 60208 U.S.A.
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Abstract

The ability to produce block copolymers has led to new materials with unique properties. The chemical connectivity of incompatible blocks forces segregation to occur at distances of the order of the block sizes. In block copolymer melts, the segregated domains form periodic ordered structures called microphases. Most block copolymers are strongly incompatible. In such cases, in order to ensure equilibrium microphase separated samples, the microphases are prepared from solution. Microphase separation in semidilute solutions of block copolymers in nonselective good solvent is analyzed. The solvent effects on the thermodynamics in the weak segregation limit are discussed. The concentration of block copolymer at the transition in good solvents, scales as φt N−.62 and in ϑ solvents as N−.5. The transitions between microphase morphologies as a function of block copolymer concentration are studied.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 177: Symposium V – Macromolecular Liquids , 1989 , 53
Copyright
Copyright © Materials Research Society 1990

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References

REFERENCES

1. Block Copolymers, Aggarwal, S.L., Ed., Plenum Press, NY (1970).Google Scholar
2. Leibler, L., Macromolecules, 13, 1602, (1980).Google Scholar
3. Alward, D.B., Kinning, D.J., Thomas, E.L., Fetters, L.J., Macromolecules, 19, 215, (1986).Google Scholar
4. Semenov, A.N., Sov. Phys. JETP, 61, 783, (1985).Google Scholar
5. Flory, P., Principles of Polymer Chemistry, Cornell University, Ithaca, (1953).Google Scholar
6. Meier, D.J., J. Polym. Sci., C., 26, 81, (1969).Google Scholar
7. Leary, D.F., Williams, M.C., J. Polymer Sci., B. 8, 335, (1970).Google Scholar
8. Helfand, E., Wasserman, Z., Polym. Eng. Sci., 17, 582, (1977).Google Scholar
9. Inoue, T., Soen, T., Hashimoto, T., Kawai, H., J. Polym. Sci., Part A-2, 7, 1283, (1969).Google Scholar
10. Hasegawa, H., Hashimoto, T., Kawai, H., Lodge, T.P., Amis, E.J., Glinka, C.J., Han, C.C., Macromolecules, 18, 67, (1985), and references therein.Google Scholar
11. Mayes, A.M. and de la Cruz, M. Olvera (to be published).Google Scholar
12. Fredrickson, G.H. and Helfand, E., J. Chem. Phys., 87, 697, (1987).Google Scholar
13. Mayes, A.M. and de la Cruz, M. Olvera (in preparation).Google Scholar
14. Hashimoto, T., Shibayama, M. and Kawai, H., Macromolecules, 13, 1237, (1980).Google Scholar
15. Broseta, D., Leibler, L. and Joanny, J.F., Macromolecules, 20, 1935, (1987).Google Scholar
16. deGennes, P.G., “Scaling Concepts in Polymer Physics”, Cornell University Press, Ithaca, NY, 1979.Google Scholar
17. Joanny, J.F., Leibler, L., Ball, R., J. Chem. Phys. 81, 4640, (1984).Google Scholar
18. de la Cruz, M. Olvera J. Chem. Phys. 90, 1995 (1989).Google Scholar
19. Fredrickson, G.H. and Leibler, L., Macromolecules 22, 1238 (1989). J.F. Joanny and L. Leibler (preprint).Google Scholar