Hostname: page-component-cd9895bd7-jn8rn Total loading time: 0 Render date: 2024-12-27T01:45:05.494Z Has data issue: false hasContentIssue false
  • English
  • Français

Ag Ion-Exchange Reactions of Cu2P3I2 and Cu2P1.8As1.2I2

Published online by Cambridge University Press:  11 February 2011

Buddhimathie Jayasekera  and
Stephanie L. Brock
Buddhimathie Jayasekera
Affiliation:
Wayne State University, Detroit, MI 48202, U.S.A.
Stephanie L. Brock
Affiliation:
Wayne State University, Detroit, MI 48202, U.S.A.
Get access

Abstract

A variety of ion exchange techniques for Cu2P3I2 and its mixed pnictogen analog Cu2P1.8As1.2I2 have been studied. Ag2P3I2 is an existing material, previously prepared from Cu2P3I2 by ion exchange of Ag+ for Cu+ in aqueous medium. This method is compared to non-aqueous (ionic liquid) and solid state routes for ion exchange. Additionally, the new compound Ag2P1.8As1.2I2 with cell parameters a = 15.838(17) Å, b = 13.684(10) Å, c = 15.580(17) Å and β = 117.63(7)°, has been prepared by reaction of Cu2P1.8As1.2I2 with AgNO3 in aqueous solution.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 755: Symposium DD – Solid-State Chemistry of Inorganic Materials IV , 2002 , DD6.12
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Moller, M. H., Jeitshko, W., J. Solid State Chem. 65, 178–189 (1986).Google Scholar
2. Freudenthaler, E., Pfitzner, A., Solid State Ionics 101–103, 1053–1059 (1997).Google Scholar
3. Freudenthaler, E., Pfitzner, A., Sinclair, D. C., Mater. Res. Bull. 31, 171–176, (1996).Google Scholar
4. Jayasekera, B., Brock, S. L., Inorg. Chem. Submitted (2002).Google Scholar
5. Welton, T., Chem. Rev. 99, 2071–2083 (1999).Google Scholar
6. Hughbanks, T., Sun, D., Inorg. Chem. 39, 1964–1968 (2000).Google Scholar
7. Chondroudis, K., Kanatzidis, M. G., J. Solid State Chem. 136, 328–332 (1998).Google Scholar