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Activated Carbons for High Power Energy Storage: Below the Surface of Non-Faradaic Reactions

Published online by Cambridge University Press:  26 February 2011

Prabeer Barpanda
Affiliation:
[email protected], Rutgers University, Deaprtment of Materials Science and Engineering, Energy Storage Research Group,, 671, Rt-1, New Jersey Tech Centre,, North Brunswick, NJ, 08902, United States, 1-732-986-3945, 1-732-932-6855
Glenn G Amatucci
Affiliation:
[email protected], Rutgers University, Department of Materials Science and Engineering, North Brunswick, NJ, 08902, United States
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Abstract

The effect of iodine doping on the electrochemical performance of activated carbons for non-aqueous symmetric and asymmetric hybrid supercapacitors was investigated. The incorporation of iodine via high energy mechanical milling techniques significantly modified the physical and electrochemical properties of activated carbon precursors. The increasing amount of iodine into carbons leads to a unique combination of lower surface area coupled with higher volumetric and gravimetric electrochemical capacitance. Iodine modification of the carbon resulted in a 100% increase in volumetric capacitance. This improvement was a result of improved non-faradaic capacitance and the development of faradaic capacity.

Type
Research Article
Copyright
Copyright © Materials Research Society 2007

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References

REFERENCES

1. Conway, B.E., Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications, Kluwer-Plenum Publications Company, New York (1999).Google Scholar
2. Amatucci, G., DuPasquier, A., Zheng, T., J. Electrochem Soc, 148(8), A930 (2001).Google Scholar
3. Liu, T.C., Pell, W.G., Conway, B.E., Electrochim Acta, 42, 3541 (1997).Google Scholar
4. Barpanda, P., Fanchini, G., Amatucci, G.G., J. Electrochem Soc, Communicated.Google Scholar
5. Hahn, M., Baertschi, M., Kotz, R. et al Electrochem Solid State Lett, 7(2), A33 (2004).Google Scholar
6. Barpanda, P., Fanchini, G., Amatucci, G.G., Chem Mater, In preparation.Google Scholar