Hostname: page-component-586b7cd67f-2plfb Total loading time: 0 Render date: 2024-11-29T08:06:18.887Z Has data issue: false hasContentIssue false
  • English
  • Français

785 nm Raman Spectroscopy of CVD Diamond Films

Published online by Cambridge University Press:  01 February 2011

Paul William May ,
James A Smith  and
Keith N Rosser
Paul William May
Affiliation:
[email protected], University of Bristol, School of Chemistry, Cantock's Close, Bristol, BS8 1TS, United Kingdom, +44 (0)117 9289927, +44 (0)117 9251295
James A Smith
Affiliation:
[email protected], University of Bristol, School of Chemistry, Cantock's Close, Bristol, BS8 1TS, United Kingdom
Keith N Rosser
Affiliation:
[email protected], University of Bristol, School of Chemistry, Cantock's Close, Bristol, BS8 1TS, United Kingdom
Get access

Abstract

Raman spectroscopy is a powerful technique often used to study CVD diamond films, however, very little work has been reported for the Raman study of CVD diamond films using near infrared (785 nm) excitation. Here, we report that when using 785 nm excitation, the Raman spectra from thin polycrystalline diamond films exhibit a multitude of peaks (over 30) ranging from 400-3000 cm−1. These features are too sharp to be photoluminescence, and are a function of film thickness. For films >30 μm thick, freestanding films, and for films grown in diamond substrates the Raman peaks disappear, suggesting that the laser is probing the disordered small-grained interface between the diamond and substrate. Some of the peaks change in relative intensity with time (‘blinking’), and the spectra are very sensitive to position on the substrate – this is reminiscent of the behaviour seen in SERS spectra.

Keywords

diamondRaman spectroscopynanostructure
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1039: Symposium P – Diamond Electronics–Fundamentals to Applications II , 2007 , 1039-P15-02
Copyright
Copyright © Materials Research Society 2008

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Filik, J., Spectroscopy Europe 17, (2005) 10.Google Scholar
2. Prawer, S., Nemanich, R.J., Phil. Trans. R. Soc. Lond.A 362, (2004) 2537.Google Scholar
3. Koós, M., Veres, M., Tóth, S., Füle, M., Raman spectroscopy of CVD carbon thin films excited by near-infrared light, in: Messina, G., Santangelo, S. (Eds.), Carbon: The Future Material for Advanced Technology Applications, Springer Series Topics in Applied Physics, 100 (2005), p. 423 (Springer, Berlin, 2005).Google Scholar
4. Ferrari, A.C., Robertson, J., Phil. Trans. R. Soc. Lond. A 362, (2004) 2477 Google Scholar
5. Roy, D., Chhowalla, Manish, Wang, H., Sano, N., Alexandrou, I., Clyne, T.W., Amaratunga, G.A.J., Chem. Phys. Lett. 373, (2003) 52.Google Scholar
6. Hird, J.R., Bloomfield, M., Hayward, I.P., Phil. Mag. 87, (2007) 267 10.1080/14786430600953772Google Scholar
7. Filik, J., Harvey, J.N., Allan, N.L., May, P.W., Dahl, J.E.P., Liu, S., and Carlson, R.M.K., Spectrochimica Acta A: Mol. Biomol. Spect. 64, (2006) 681.10.1016/j.saa.2005.07.070Google Scholar
8. Filik, J., Harvey, J.N., Allan, N.L., May, P.W., Dahl, J.E.P., Liu, S., Carlson, R.M.K., Phys. Rev. B. 74, (2006) 035423.10.1103/PhysRevB.74.035423Google Scholar
9. Pedroza-Montero, M., Chernov, V., Castañeda, B., Meléndrez, R., Gonçalves, J. A. N., Sandonato, G.M., Bernal, R., Cruz-Vázquez, C., Brown, F., Cruz-Zaragoza, E., Barboza-Flores, M., Phys. Stat. Sol. (a) 202, (2005) 2154.Google Scholar
10. Balzaretti, N.M., Feldman, A. Etz, E.S., Gat, R., J. Mater. Res. 14, (1999) 3720.Google Scholar
11. Veres, M., Tóth, S., Füle, M., Koós, M., abstract book from ‘New Diamond and NanoCarbons’ conference, Osaka Japan, 2007.Google Scholar
12. Leeds, S.M., Davis, T.J., May, P.W., Pickard, C.D.O. and Ashfold, M.N.R., Diamond Relat. Maters. 7, (1998) 233.Google Scholar
13. Burton, J.C., Long, F.H., Ferguson, I.T., J. Appl. Phys. 86, (1999) 2073.Google Scholar
14. Zaitsev, A.M., Optical Properties of Diamond: A Data Handbook (Springer, Berlin, 2001).Google Scholar
15. Knight, D.S. and White, W.B., J. Mater. Res. 4, (1989) 385.Google Scholar
16. Gogotsi, Y.G., Kailer, A. and Nickel, K.G., J. Appl. Phys. 84, (1998) 1299.Google Scholar
17. Zhao, X.-Z., Cherian, K.A., Roy, R., White, W.B., J. Mater. Res. 13, (1998) 1974.Google Scholar
18. May, P.W., Overton, P., Smith, J.A., Rosser, K.N., MRS Symp. Proc. (Fall 2007), in press.Google Scholar
19.Selected Papers on Surface-Enhanced Raman Scattering, edited by. Kerker, M., SPIE Milestone Series MS 10, (Spie Billingham, Wa, USA, 1990).Google Scholar
20. Veres, M., Fule, M., Toth, S., Koos, M., Pocsik, I., Diamond Relat. Mater. 13, (2004) 1412.Google Scholar
21. Perevedentseva, E., Karmenyan, A., Chung, P.-H. and Cheng, C.-L., J. Vac. Sci. Technol. B, 23, (2005) 1980.Google Scholar
22. White, D.S., Weimer, R., Pilione, L., White, W.B., Appl. Phys. Lett. 56, (1990) 1320.Google Scholar
23. Roy, D., Barber, Z.H., Clyne, T.W., J. Appl. Phys. 91, (2002) 6085.Google Scholar
24. López-Ríos, T., Sandré, É., Leclercq, S., and Sauvain, É., Phys. Rev. Lett. 76, (1996) 4935.Google Scholar