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121Sb MöSsbauer Studies of Graphite–SbF5 Intercalation Compounds

Published online by Cambridge University Press:  15 February 2011

D. H. Mcdaniel ,
P. Boolchand ,
W. J. Bresser  and
P. C. Eklund
D. H. Mcdaniel
Affiliation:
University Of Cincinnati, Cincinnati, OH 45221, USA
P. Boolchand
Affiliation:
University Of Cincinnati, Cincinnati, OH 45221, USA
W. J. Bresser
Affiliation:
University Of Cincinnati, Cincinnati, OH 45221, USA
P. C. Eklund
Affiliation:
University of Kentucky, Lexington, KY 40506, USA
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Abstract

Stage 2 samples of graphite-SbF5 intercalVtion compounds were prepared by reacting SbF5 with HOPG at 200°C for 5 days. 121Sb Mössbauer spectra taken at 4.2K reveal an intense and narrow feature in the Sb(5+) region and a weak and broad feature in the Sb(3+) region. Interpretation of these data in terms of possible Sb(5+) and Sb(3+) intercalant species is discussed in connection with chemical aspects of intercalation.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 20: Symposium H – Intercalated Graphite , 1982 , 377
Copyright
Copyright © Materials Research Society 1983

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