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51V and 133Cs MAS NMR Investigation of Crystalline Trivanadate and Hexavanadate Phases.

Published online by Cambridge University Press:  26 February 2011

Olivier Durupthy ,
Jocelyne Maquet ,
Nathalie Steunou ,
Christian Bonhomme  and
Jacques Livage
Olivier Durupthy
Affiliation:
[email protected] Chimie de la Matière condensée de Paris UMR 7574 University Paris 6 4 place jussieu Paris cedex 05 75252 France
Jocelyne Maquet
Affiliation:
[email protected] Chimie de la Matière condensée de Paris UMR 7574 University Paris 6 4 place jussieu Paris cedex 05 75252 France
Nathalie Steunou
Affiliation:
[email protected] Chimie de la Matière condensée de Paris UMR 7574 University Paris 6 4 place jussieu Paris cedex 05 75252 France
Christian Bonhomme
Affiliation:
[email protected] Chimie de la Matière condensée de Paris UMR 7574 University Paris 6 4 place jussieu Paris cedex 05 75252 France
Jacques Livage
Affiliation:
[email protected] Chimie de la Matière condensée de Paris UMR 7574 University Paris 6 4 place jussieu Paris cedex 05 75252 France
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Abstract

A complete solid state NMR characterization of the vanadium oxides Cs[V3O8] and Cs2[V6O16].0.7H2O is proposed. We used 51V and 133Cs MAS NMR to investigate the local environment of cesium and vanadium nuclei and 2D 1H- 133Cs CP MAS HETCOR experiments to explore the connectivities between cesium ions and water molecules in the interlamellar space.

Keywords

Vnuclear magnetic resonance (NMR)sol-gel
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 984: Symposium MM – Magnetic Resonance in Material Science , 2006 , 0984-MM07-03
Copyright
Copyright © Materials Research Society 2007

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References

1. Guyomard, D., in New Trends in Electrochemical Technology: Energy Storage Systems in Electronics, ed. T., Osaka, D., Matta (Gordon & Breach, Philadelphia, 2000) p 253.Google Scholar
2. Pistoia, G., Pasquali, M., Wang, G. and Li, L., J. Electrochem. Soc. 137, 2365 (1990).Google Scholar
3. Durupthy, O., Steunou, N., Coradin, T., Maquet, J., Bonhomme, C., Livage, J., J. Mater. Chem. 15, 1090 (2005).Google Scholar
4. Oka, Y., Yao, T., Yamamoto, N., Mater. Res. Bull. 32, 1201 (1997).Google Scholar
5. Oka, Y., Yao, T., N. Yamamoto J. Solid State Chem. 140, 219 (1998).Google Scholar
6. Amoureux, J. P., Fernandez, C., Dumazy, Y., 37th Rocky Mountain conference, 1995. This program is accessible within Dmfit 2004 at http://crhmt- europe.cnrs.orleans.fr/dmfit/help/dmfit.htm.Google Scholar
7. Skibsted, J., Nielsen, N.C., Bildsoe, H., Jakobsen, H. J., J. Am. Chem. Soc. 115, 7351 (1993).Google Scholar
8. Nielsen, U. G., Jakobsen, H. J., Skibsted, J., Inorg. Chem. 39, 2135 (2000).Google Scholar
9. Nielsen, U. G., Jakobsen, H. J., J. Skibsted,. J. Phys. Chem. B 105, 420 (2001).Google Scholar