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Transparent glass-ceramics for optical applications

Published online by Cambridge University Press:  06 March 2017

O. Dymshits ,
M. Shepilov  and
A. Zhilin
O. Dymshits
Affiliation:
NITIOM Vavilov State Optical Institute, Russia; [email protected]
M. Shepilov
Affiliation:
NITIOM Vavilov State Optical Institute, Russia; [email protected]
A. Zhilin
Affiliation:
NITIOM Vavilov State Optical Institute, Russia; [email protected]
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Abstract

The design, properties, and applications of transparent glass-ceramics are reviewed. Interference effects in light scattering by transparent glass-ceramics are discussed. The scattering coefficient of transparent glass-ceramics is found to be significantly less than that for the case of independent Rayleigh scattering by nanocrystals; its wavelength dependence is qualitatively different. A reduction in interference effects achieved by precipitation of nanocrystals of different crystalline phases with different scattering properties results in glass-ceramics with high diffuse reflection. The origin of the low coefficient of thermal expansion of glass-ceramics is discussed based on the temperature dependence of the unit cell parameters of β-quartz solid solutions measured by in situ high-temperature x-ray diffraction. Transparent glass-ceramics doped with Co2+ and Ni2+ ions for thermal shock-resistant color filters, for broadband near-infrared (IR) optical amplifiers, and for passive Q-switching of eye-safe Er lasers are presented. Glass-ceramics with rare-earth titanates, titanates-zirconates, and niobates in dual roles of nucleators and active crystals are reviewed.

Keywords

nanostructureoptical propertiesabsorptionluminescence
Type
Research Article
Information
MRS Bulletin , Volume 42 , Issue 3: Glass-ceramics , March 2017 , pp. 200 - 205
Copyright
Copyright © Materials Research Society 2017 

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