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The Rheology of Cementitious Materials

Published online by Cambridge University Press:  31 January 2011

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Abstract

The introduction of a new generation of dispersants in concrete allow this material to exhibit self-compacting properties in its fresh state and high durability and mechanical strength in its hardened state. These properties translate into many practical advantages for the construction field.Two of the most important are reducing the ecological impact of this sector of industry and reducing the labor-intensive work associated with placing ordinary concrete by vibration. In this article, it will be shown that knowledge of colloidal science has proven essential in the development of this new generation of dispersants for concrete. Indeed, the polymer molecules used in these dispersants are specifically designed to induce steric repulsion between cement particles, reducing their agglomeration and allowing high workability of fresh concrete prior to setting. While the linkage between interparticle forces and the rheological behavior of cement pastes is still only semiquantitative, recent advances in the modeling of concrete rheology show very promising results in terms of handling aggregates with a wide distribution of particle sizes and shapes. However, accurate modeling requires reliable input on the interaction of the dispersant with the hydrating cement at the molecular level, which is identified as a future research challenge.

Type
Research Article
Copyright
Copyright © Materials Research Society 2004

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References

1Mehta, P.K, in Proc. of the 6th CANMET/ACI International Conference on Fly-Ash, Silica Fume, Slag and Natural Pozzolans in Concrete, Vol.1, edited by Malhotra, V.M. (American Concrete Institute, Detroit, 1998) p.1.Google Scholar
2Dodson, V.H., Concrete Admixtures (Van Nostrand Reinhold, New York, 1990).Google Scholar
3Aïtcin, P.C., Jolicoeur, C. and MacGregor, J.G., Concr. Int. 16 (5) (1994) p.45.Google Scholar
4Ramachandran, V.S., Malhotra, V.M., Jolicoeur, C., and Spiratos, N.Superplasticizers: Properties and Applications in Concrete, CANMET Publication MTL 97-14 (CANMET, Ottawa, 1998).Google Scholar
5Flatt, R.J., Cem. Concr. Res. 34 (2004) p.399.CrossRefGoogle Scholar
6Flatt, R.J., in Polymers in Particulate Systems: Properties and Applications, edited by Hackley, V.A., Somasundaran, P., and Lewis, J.A. (Marcel Dekker, New York, 2001) p.247.Google Scholar
7Lewis, J.A., Matsuyama, H.Kirby, G.Morissette, S., and Young, J.F., J.Am. Ceram. Soc. 83 (2000) p.1905.Google Scholar
8Ducker, W.A., Senden, T.J., and Pashley, R.M., Nature 353 (1991) p.239.CrossRefGoogle Scholar
9Kauppi, A. P.Banfill, F.B.Bowen, P.Galmiche, L., Houst, Y.F., Lafuma, F.Mäder, U., Perche, F.Petersen, B.G., Reknes, K.Schober, I.Siebold, A. and Swift, D. in Proc. 11th Int. Congr. on the Chemistry of Cement, Vol. 2, edited by Grieve, G. and Owen, G. (Cement Association of Canada, Ottawa, 2003) p.528.Google Scholar
10Kauppi, A.Andersson, K.M., and Bergström, L., “Probing the Effect of Superplasti-cizer Adsorption on the Surface Forces Using the Colloidal Probe AFM Technique,” Cem. Concr. Res. submitted for publication.Google Scholar
11Flatt, R.J., Houst, Y.F., Bowen, P.Hofmann, H.Widmer, J.Sulser, U.Maeder, U. and Bürge, T.A., in Proc. 5th CANMET/ACI Int. Conf. on Superplasticizers and Other Chemical Admixtures in Concrete, edited by Malhotra, V.M. (American Concrete Institute, Detroit, 1997) p.743.Google Scholar
12Pedersen, H.G., “Particle interactions: An AFM study of colloidal systems,” PhD thesis, Technical University of Denmark, 1998.Google Scholar
13Damme, H. Van, Mansoutre, S.Colombet, P.Lesaffre, C. and Picart, D.C.R. Physique 3 (2002) p.229.Google Scholar
14Powers, T.C., The Properties of Fresh Concrete (John Wiley & Sons, New York, 1968).Google Scholar
15Larrard, F. de, Concrete Mixture Proportioning: A Scientific Approach (E&FN Spon, London, 1999).Google Scholar
16Bonen, D. and Sarkar, S.L., Cem. Concr. Res. 25 (1995) p.1423.CrossRefGoogle Scholar
17Fernon, V.Vichot, A.Goanvic, N. Le, Colombet, P.Corazza, F. and Costa, U. in Proc. 5th CANMET/ACI Int. Conf. on Superplasticizers and Other Chemical Admixtures in Concrete, edited by Malhotra, V.M. (American Concrete Institute, Detroit, 1997) p.225.Google Scholar
18Flatt, R.J. and Houst, Y.F., Cem. Concr. Res. 31 (2001) p.1169.CrossRefGoogle Scholar
19Yamada, K. and Hanehara, S.Concr. Sci. and Eng. 3 (2001) p.135.Google Scholar
20Flatt, R.J., “Towards a Prediction of Super-plasticized Concrete Rheology,” Mater. and Struct. in press.Google Scholar
21Hoogerbrugge, P.J. and Koelman, J.M.V.A.Europhys. Lett. 19 (1992) p.155.Google Scholar
22Peyret, R. and Taylor, D.Computational Methods for Fluid Flow (Springer-Verlag, New York, 1983).CrossRefGoogle Scholar
23Allen, M.P. and Tildesley, D.J., Computer Simulation of Liquids (Clarendon Press, Oxford, 1987).Google Scholar
24Espanol, P. and Warren, P.Europhys. Lett. 30 (1995) p.191.CrossRefGoogle Scholar
25Marsh, C.Backx, G. and Ernst, M.H., Euro-phys. Lett. 38 (1997) p.441.CrossRefGoogle Scholar
26Koelman, J.M.V.A. and Hoogerbrugge, P.J., Europhys. Lett. 21 (1993) p.363.CrossRefGoogle Scholar
27Garboczi, E.J., Cem. Conc. Res. 32 (2002) p.1621.CrossRefGoogle Scholar
28Ferraris, C. and Martys, N.J. Res. Natl. Inst. Stand. Technol. 108 (2003) p.229.CrossRefGoogle Scholar