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QLEDs for displays and solid-state lighting

Published online by Cambridge University Press:  12 September 2013

Geoffrey J. Supran ,
Yasuhiro Shirasaki ,
Katherine W. Song ,
Jean-Michel Caruge ,
Peter T. Kazlas ,
Seth Coe-Sullivan ,
Trisha L. Andrew ,
Moungi G. Bawendi  and
Vladimir Bulović
Geoffrey J. Supran
Affiliation:
Massachusetts Institute of Technology;[email protected]
Yasuhiro Shirasaki
Affiliation:
Massachusetts Institute of Technology;[email protected]
Katherine W. Song
Affiliation:
Massachusetts Institute of Technology;[email protected]
Jean-Michel Caruge
Affiliation:
QD Vision;[email protected]
Peter T. Kazlas
Affiliation:
QD Vision;[email protected]
Seth Coe-Sullivan
Affiliation:
QD Vision;[email protected]
Trisha L. Andrew
Affiliation:
University of Wisconsin–Madison;[email protected]
Moungi G. Bawendi
Affiliation:
Massachusetts Institute of Technology;[email protected]
Vladimir Bulović
Affiliation:
Massachusetts Institute of Technology;[email protected]
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Abstract

The mainstream commercialization of colloidal quantum dots (QDs) for light-emitting applications has begun: Sony televisions emitting QD-enhanced colors are now on sale. The bright and uniquely size-tunable colors of solution-processable semiconducting QDs highlight the potential of electroluminescent QD light-emitting devices (QLEDs) for use in energy-efficient, high-color-quality thin-film display and solid-state lighting applications. Indeed, this year’s report of record-efficiency electrically driven QLEDs rivaling the most efficient molecular organic LEDs, together with the emergence of full-color QLED displays, foreshadow QD technologies that will transcend the optically excited QD-enhanced products already available. In this article, we discuss the key advantages of using QDs as luminophores in LEDs and outline the 19-year evolution of four types of QLEDs that have seen efficiencies rise from less than 0.01% to 18%. With an emphasis on the latest advances, we identify the key scientific and technological challenges facing the commercialization of QLEDs. A quantitative analysis, based on published small-scale synthetic procedures, allows us to estimate the material costs of QDs typical in light-emitting applications when produced in large quantities and to assess their commercial viability.

Keywords

Colloidal quantum-dotlight-emitting devicenanotechnologysolid-state lighting
Type
Quantum dot light-emitting devices
Information
MRS Bulletin , Volume 38 , Issue 9: Quantum dot light-emitting devices , September 2013 , pp. 703 - 711
Copyright
Copyright © Materials Research Society 2013 

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References

Shirasaki, Y., Supran, G.J., Bawendi, M.G., Bulović, V., Nat. Photonics 7, 13 (2013).CrossRefGoogle Scholar
Norris, D.J., Bawendi, M.G., Brus, L.E., Molecular Electronics: A “Chemistry for the 21st Century” Monograph, Chap. 9 (Blackwell Science, NY, 1997).Google Scholar
Anikeeva, P.O., Halpert, J.E., Bawendi, M.G., Bulović, V., Nano Lett. 9, 2532 (2009).CrossRefGoogle Scholar
Niu, Y.H., Munro, A.M., Cheng, Y.-J., Tian, Y.Q., Liu, M.S., Zhao, J.L., Bardecker, J.A., Jen-La Plante, I., Ginger, D.S., Jen, A.K.-Y., Adv. Mater. 19, 3371 (2007).CrossRefGoogle Scholar
Qian, L., Zheng, Y., Xue, J., Holloway, P.H., Nat. Photonics 5, 543 (2011).CrossRefGoogle Scholar
Sun, Q., Wang, Y.A., Li, L.S., Wang, D., Zhu, T., Xu, J., Yang, C., Li, Y., Nat. Photonics 1, 717 (2007).CrossRefGoogle Scholar
Kwak, J., Bae, W.K., Lee, D., Park, I., Lim, J., Park, M., Cho, H., Woo, H., Yoon, D., Char, K., Lee, S., Lee, C., Nano Lett. 12, 2362 (2012).CrossRefGoogle Scholar
Wood, V., Bulović, V., Nano Reviews 1, 5202, doi: 10.3402/nano.v1i0.5202 (2010).CrossRefGoogle Scholar
Bourzac, K., Nature 493, 283 (2013).CrossRefGoogle Scholar
Coe-Sullivan, S., Liu, W., Allen, P., Steckel, J.S., ECS J. Solid State Sci. Technol. 2, R3026 (2013).CrossRefGoogle Scholar
Chen, J.A., “High-Efficiency Wide-Color-Gamut Solid-State Backlight System for LCDs Using Quantum-Dot Enhancement Film,” SID Display Week 2012 (2012).Google Scholar
Sun, L., Choi, J.J., Stachnik, D., Bartnik, A.C., Hyun, B.-R., Malliaras, G.G., Hanrath, T., Wise, F.W., Nat. Nanotechnol. 7, 369 (2012).CrossRefGoogle Scholar
Konstantatos, G., Huang, C., Levina, L., Lu, Z., Sargent, E.H., Adv. Funct. Mater. 15, 1865 (2005).CrossRefGoogle Scholar
Supran, G.J., Song, K.W., Hwang, G.W., Correa, R.E., Scherer, J., Dauler, E.A., Shirasaki, Y., Bawendi, M.G., Bulović, V., “High-Efficiency and Brightness Near-Infrared Quantum-Dot LEDs Using Core-Shell (PbS-CdS) Colloidal Quantum-Dots,” presented at the MRS Spring Meeting, San Francisco, CA (2013).Google Scholar
Hollingsworth, J.A., Klimov, V.I., Nanocrystal Quantum Dots, Second Edition (CRC Press, NY, 2010).Google Scholar
Chen, O., Zhao, J., Chauhan, V.P., Cui, J., Wong, C., Harris, D.K., Wei, H., Han, H.-S., Fukumura, D., Jain, R.K., Bawendi, M.G., Nat. Mater. 12, 1 (2013).Google Scholar
Sommer, J.R., Farley, R.T., Graham, K.R., Yang, Y., Reynolds, J.R., Xue, J., Schanze, K.S., ACS Applied Materials & Interfaces 1, 274 (2009).CrossRefGoogle Scholar
Pietryga, J.M., Werder, D.J., Williams, D.J., Casson, J.L., Schaller, R.D., Klimov, V.I., Hollingsworth, J.A., J. Am. Chem. Soc. 130, 4879 (2008).CrossRefGoogle Scholar
Sargent, E.H., Adv. Mater. 17, 515 (2005).CrossRefGoogle Scholar
Rogach, A.L., Eychmüller, A., Hickey, S.G., Kershaw, S.V., Small 3, 536 (2007).CrossRefGoogle Scholar
Oliver, J., BCC Research paper NAN027C, Quantum Dots: Global Market Growth and Future Commercial Prospects (2011).Google Scholar
www.displaysearch.com.Google Scholar
Colvin, V.L., Schlamp, M.C., Alivisatos, A.P., Nature 370, 354 (1994).CrossRefGoogle Scholar
Dabbousi, B.O., Bawendi, M.G., Onitsuka, O., Rubner, M.F., Appl. Phys. Lett. 66, 1316 (1995).CrossRefGoogle Scholar
Coe, S., Woo, W.-K., Bawendi, M.G., Bulović, V., Nature 420, 800 (2002).CrossRefGoogle Scholar
Kim, L., Anikeeva, P.O., Coe-Sullivan, S.A., Steckel, J.S., Bawendi, M.G., Bulović, V., Nano Lett. 8, 4513 (2008).CrossRefGoogle Scholar
Steckel, J.S., Snee, P., Coe-Sullivan, S., Zimmer, J.P., Halpert, J.E., Anikeeva, P., Kim, L.-A., Bulović, V., Bawendi, M.G., Angew. Chem. 45, 5796 (2006).CrossRefGoogle Scholar
Rizzo, A., Mazzeo, M., Palumbo, M., Lerario, G., D’Amone, S., Cingolani, R., Gigli, G., Adv. Mater. 20, 1886 (2008).CrossRefGoogle Scholar
Mueller, A.H., Petruska, M.A., Achermann, M., Werder, D.J., Akhadov, E.A., Koleske, D.D., Hoffbauer, M.A., Klimov, V.I., Nano Lett. 5, 1039 (2005).CrossRefGoogle Scholar
Achermann, M., Petruska, M.A., Kos, S., Smith, D.L., Koleske, D.D., Klimov, V.I., Nature 429, 642 (2004).CrossRefGoogle Scholar
Panzer, M.J., Aidala, K.E., Anikeeva, P.O., Halpert, J.E., Bawendi, M.G., Bulović, V., Nano Lett. 10, 2421 (2010).CrossRefGoogle Scholar
Anikeeva, P.O., Madigan, C.F., Halpert, J.E., Bawendi, M.G., Bulović, V., Phys. Rev. B 78, 085434 (2008).CrossRefGoogle Scholar
Friend, R.H., Gymer, R.W., Holmes, A.B., Burroughes, J.H., Marks, R.N., Taliani, C., Bradley, D.D.C., Dos Santos, D.A., Bredas, J.L., Lögdlund, M., Salaneck, W.R., Nature 397, 121 (1999).CrossRefGoogle Scholar
Burrows, P.E., Bulović, V., Forrest, S.R., Sapochak, L.S., McCarty, D.M., Appl. Phys. Lett. 65, 2922 (1994).CrossRefGoogle Scholar
Caruge, J.M., Halpert, J.E., Wood, V., Bulović, V., Bawendi, M.G., Nat. Photonics 2, 247 (2008).CrossRefGoogle Scholar
Wood, V., Panzer, M.J., Halpert, J.E., Caruge, J.-M., Bawendi, M.G., Bulović, V., ACS Nano 3, 3581 (2009).CrossRefGoogle Scholar
Cho, S.H., Sung, J., Hwang, I., Kim, R.H., Choi, Y.S., Jo, S.S., Lee, T.W., Park, C., Adv. Mater. 24, 4540 (2012).CrossRefGoogle Scholar
Stouwdam, J.W., Janssen, R.A.J., J. Mater. Chem. 18, 1889 (2008).CrossRefGoogle Scholar
Caruge, J.-M., Halpert, J.E., Bulović, V., Bawendi, M.G., Nano Lett. 6, 2991 (2006).CrossRefGoogle Scholar
Mashford, B.S., Stevenson, M., Popovic, Z., Hamilton, C., Zhou, Z., Breen, C., Steckel, J., Bulović, V., Bawendi, M.G., Coe-Sullivan, S., Kazlas, P.T., Nat. Photonics 7, 407 (2013).CrossRefGoogle Scholar
Meerheim, R., Scholz, S., Olthof, S., Schwartz, G., Reineke, S., Walzer, K., Leo, K., J. Appl. Phys. 104, 014510 (2008).CrossRefGoogle Scholar
Meerheim, R., Furno, M., Hofmann, S., Lüssem, B., Leo, K., Appl. Phys. Lett. 97, 253305 (2010).CrossRefGoogle Scholar
Kim, T.-H., Cho, K.-S., Lee, E.K., Lee, J.S., Chae, J., Kim, J.W., Kim, D.H., Kwon, J.-Y., Amaratunga, G., Lee, S.Y., Choi, B.L., Kuk, Y., Kim, J.M., Kim, K., Nat. Photonics 5, 176 (2011).CrossRefGoogle Scholar
Anikeeva, P.O., Halpert, J.E., Bawendi, M.G., Bulović, V., Nano Lett. 7, 2196 (2007).CrossRefGoogle Scholar
Li, Y.Q., Rizzo, A., Cingolani, R., Gigli, G., Adv. Mater. 18, 2545 (2006).CrossRefGoogle Scholar
Coe-Sullivan, S., OECD/NNI Symposium, QD Vision, Inc. presenting work from AFOSR grant number FA9550–07-C-0056 (2012).Google Scholar
Qian, G., Zhong, Z., Luo, M., Yu, D., Zhang, Z., Wang, Z.Y., Ma, D., Adv. Mater. 21, 111 (2009).CrossRefGoogle Scholar
Klem, E.J.D., Levina, L., Sargent, E.H., Appl. Phys. Lett. 87, 053101 (2005).CrossRefGoogle Scholar
Lim, Y.T., Kim, S., Nakayama, A., Stott, N.E., Bawendi, M.G., Frangioni, J.V., Mol. Imaging 2, 50 (2003).CrossRefGoogle Scholar
Kim, S., Lim, Y.T., Soltesz, E.G., De Grand, A.M., Lee, J., Nakayama, A., Parker, J.A., Mihaljevic, T., Laurence, R.G., Dor, D.M., Cohn, L.H., Bawendi, M.G., Frangioni, J.V., Nat. Biotechnol. 22, 93 (2004).CrossRefGoogle Scholar
Medintz, I.L., Uyeda, H.T., Goldman, E.R., Mattoussi, H., Nat. Mater. 4, 435 (2005).CrossRefGoogle Scholar
Frasco, M.F., Chaniotakis, N., Sensors 9, 7266 (2009).CrossRefGoogle ScholarPubMed
Tessler, N., Medvedev, V., Kazes, M., Kan, S., Banin, U., Science 295, 1506 (2002).CrossRefGoogle Scholar
Bourdakos, K.N., Dissanayake, D.M.N.M., Lutz, T., Silva, S.R.P., Curry, R.J., Appl. Phys. Lett. 92, 153311 (2008).CrossRefGoogle Scholar
Bakueva, L., Musikhin, S., Hines, M.A., Chang, T.-W.F., Tzolov, M., Scholes, G.D., Sargent, E.H., Appl. Phys. Lett. 82, 2895 (2003).CrossRefGoogle Scholar
Choudhury, K.R., Song, D.W., So, F., Org. Electron. 11, 23 (2010).CrossRefGoogle Scholar
Solomeshch, O., Kigel, A., Saschiuk, A., Medvedev, V., Aharoni, A., Razin, A., Eichen, Y., Banin, U., Lifshitz, E., Tessler, N., J. Appl. Phys. 98, 074310 (2005).CrossRefGoogle Scholar
Supran, G.J., Song, K.W., Hwang, G.W., Correa, R.E., Scherer, J., Dauler, E.A., Shirasaki, Y., Bawendi, M.G., Bulović, V., Patent Application 61/735, 344 (2012).Google Scholar
Cheng, K.-Y., Anthony, R., Kortshagen, U.R., Holmes, R.J., Nano Lett. 10, 1154 (2010).CrossRefGoogle Scholar
Cheng, K.-Y., Anthony, R., Kortshagen, U.R., Holmes, R.J., Nano Lett. 11, 1952 (2011).CrossRefGoogle Scholar
Zhang, Y.Q., Cao, X.A., Appl. Phys. Lett. 97, 253115 (2010).CrossRefGoogle Scholar
Bae, W.K., Kwak, J., Lim, J., Lee, D., Nam, M.K., Char, K., Lee, C., Lee, S., Nano Lett. 10, 2368 (2010).CrossRefGoogle Scholar
Jing, P., Zheng, J., Zeng, Q., Zhang, Y., Liu, X., Liu, X., Kong, X., Zhao, J., J. Appl. Phys. 105, 044313 (2009).CrossRefGoogle Scholar
Shirasaki, Y., Supran, G.J., Tisdale, W.A., Bulović, V., Phys. Rev. Lett. 110, 217403 (2013).CrossRefGoogle Scholar
Bozyigit, D., Yarema, O., Wood, V., Adv. Funct. Mater. 23, 3024 (2013).CrossRefGoogle Scholar
Zhao, J., Bardecker, J.A., Munro, A.M., Liu, M.S., Niu, Y., Ding, I.-K., Luo, J., Chen, B., Jen, A.K.-Y., Ginger, D.S., Nano Lett. 6, 463 (2006).CrossRefGoogle Scholar
Stouwdam, J.W., Janssen, R.A.J., Adv. Mater. 21, 2916 (2009).CrossRefGoogle Scholar
Huang, H., Dorn, A., Nair, G.P., Bulović, V., Bawendi, M.G., Nano Lett. 7, 3781 (2007).CrossRefGoogle Scholar
Wang, Z.-B., Zhang, H.-C., Zhang, J.-Y., Chin. Phys. Lett. 27, 127803 (2010).CrossRefGoogle Scholar
Sun, L., Bartnik, A., Hyun, B., Wise, F., Reed, J., Slinker, J., Malliaras, G., Zhong, Y., Bao, L., Abruna, H., Conference on Lasers and Electro-Optics (Optical Society of America), paper CThS6, doi:10.1109/CLEO.2008.4551522 (2008).CrossRefGoogle Scholar
Woo, W.-K., Shimizu, K.T., Jarosz, M.V., Neuhauser, R.G., Leatherdale, C.A., Rubner, M.A., Bawendi, M.G., Adv. Mater. 14, 1068 (2002).3.0.CO;2-1>CrossRefGoogle Scholar
Galland, C., Ghosh, Y., Steinbrück, A., Sykora, M., Hollingsworth, J.A., Klimov, V.I., Htoon, H., Nature 479, 203 (2011).CrossRefGoogle Scholar
Pandey, A., Guyot-Sionnest, P., J. Phys. Chem. Lett. 1, 45 (2010).CrossRefGoogle Scholar
Chang, T.-W.F., Musikhin, S., Bakueva, L., Levina, L., Hines, M.A., Cyr, P.W., Sargent, E.H., Appl. Phys. Lett. 84, 4295 (2004).CrossRefGoogle Scholar
Achermann, M., Petruska, M.A., Koleske, D.D., Crawford, M.H., Klimov, V.I., Nano Lett. 6, 1396 (2006).CrossRefGoogle Scholar
Shik, A., Konstantatos, G., Sargent, E.H., Ruda, H.E., J. Appl. Phys. 94, 4066 (2003).CrossRefGoogle Scholar
Coe-Sullivan, S., “M-5: Nanotechnology for Displays: A Potential Breakthrough for OLED Displays and LCDs (QD Vision, Inc.),” Display Week 2012.Google Scholar
Cho, K.-S., Lee, E.K., Joo, W., Jang, E., Kim, T., Lee, S.J., Kwon, S., Han, J.Y., Kim, B., Choi, B.L., Kim, J.M., Nat. Photonics 3, 341 (2009).CrossRefGoogle Scholar
Meerheim, R., Scholz, S., Olthof, S., Schwartz, G., Reineke, S., Walzer, K., Leo, K., J. Appl. Phys. 104, 014510 (2008).CrossRefGoogle Scholar
Osedach, T.P., Andrew, T.L., Bulović, V., Energy Environ. Sci. 6, 711 (2013).CrossRefGoogle Scholar
Murray, C.B., Norris, D.J., Bawendi, M.G., J. Am. Chem. Soc. 115, 8706 (1993).CrossRefGoogle Scholar
Hines, M.A., Guyot-Sionnest, P., J. Phys. Chem. 100, 468 (1996).CrossRefGoogle Scholar
Helander, M.G., Wang, Z.B., Qiu, J., Greiner, M.T., Puzzo, D.P., Liu, Z.W., Lu, Z.H., Science 332, 944 (2011).CrossRefGoogle Scholar
US Department of Energy, “Solid-State Lighting Research and Development: Manufacturing Roadmap” (2012).Google Scholar
Haverinen, H.M., Myllylä, R.A., Jabbour, G.E., J. Display Technol. 6, 87 (2010).CrossRefGoogle Scholar
Panzer, M.J., Wood, V., Geyer, S.M., Bawendi, M.G., Bulović, V., J. Display Technol. 6, 90 (2010).CrossRefGoogle Scholar
Shiang, J.J., Kadavanich, A.V., Grubbs, R.K., Alivisatos, A.P., J. Phys. Chem. 99, 17417 (1995).CrossRefGoogle Scholar
Dabbousi, B.O., Bawendi, M.G., Onitsuka, O., Rubner, M.F., Appl. Phys. Lett. 66, 1316 (1995).CrossRefGoogle Scholar
Mattoussi, H., Radzilowski, L.H., Dabbousi, B.O., Thomas, E.L., Bawendi, M.G., Rubner, M.F., J. Appl. Phys. 83, 7965 (1998).CrossRefGoogle Scholar
Schlamp, M.C., Peng, X., Alivisatos, A.P., J. Appl. Phys. 82, 5837 (1997).CrossRefGoogle Scholar
Coe-Sullivan, S., Steckel, J.S., Woo, W.-K., Bawendi, M.G., Bulović, V., Adv. Funct. Mater. 15, 1117 (2005).CrossRefGoogle Scholar
Coe-Sullivan, S., “12.2: Quantum-Dot Light-Emitting Diodes for Near-to-Eye and Direct-View Display Applications (QD Vision, Inc.),” Display Week 2011.CrossRefGoogle Scholar
Tang, C.W., VanSlyke, S.A., Chen, C.H., J. Appl. Phys. 65, 3610 (1989).CrossRefGoogle Scholar
Hamada, Y., Kanno, H., Tsujioka, T., Takahashi, H., Usuki, T., Appl. Phys. Lett. 75, 1682 (1999).CrossRefGoogle Scholar
Chen, B., Lin, X., Cheng, L., Lee, C.-S., Gambling, W.A., Lee, S.T., J. Phys. D: Appl. Phys. 34, 30 (2001).CrossRefGoogle Scholar
Leung, M., Chang, C.-C., Wu, M.-H., Chuang, K.-H., Lee, J.-H., Shieh, S.-J., Lin, S.-C., Chiu, C.-F., Org. Lett. 8, 2623 (2006).CrossRefGoogle Scholar
Steckel, J.S., Coe-Sullivan, S., Bulovic, V., Bawendi, M.G., Adv. Mater. 15, 1862 (2003).CrossRefGoogle Scholar
Koktysh, D.S., Gaponik, N., Reufer, M., Crewett, J., Scherf, U., Eychmüller, A., Lupton, J.M., Rogach, A.L., Feldmann, J., ChemPhysChem 5, 1435 (2004).CrossRefGoogle Scholar
O’Connor, É., O’Riordan, A., Doyle, H., Moynihan, S., Cuddihy, A., Redmond, G., Appl. Phys. Lett. 86, 201114 (2005).CrossRefGoogle Scholar
Ma, X., Xu, F., Benavides, J., Cloutier, S.G., Org. Electron. 13, 525 (2012).CrossRefGoogle Scholar
Zhao, N., Osedach, T.P., Chang, L.-Y., Geyer, S.M., Wanger, D., Binda, M.T., Arango, A.C., Bawendi, M.G., Bulović, V., ACS Nano 4, 3743 (2010).CrossRefGoogle Scholar
Horihata, T., Okamoto, K., Hidaka, J., Einaga, H., Bull. Chem. Soc. Jpn. 61, 2999 (1988).CrossRefGoogle Scholar
Furugori, M., Igawa, S., Kamatani, J., Miura, S., Mizutani, H., Moriyama, T., Okada, S., Takiguchi, T., Tsuboyama, A., Metal Coordination Compound and Electroluminescence Device, US Patent 20030235712 (2003).Google Scholar
US Department of Health and Human Services, “Toxicological Profile for Cadmium” (2012).Google Scholar
Lee, K.-H., Lee, J.-H., Song, W.-S., Ko, H., Lee, C., Lee, J.-H., Yang, H., ACS Nano, doi: 10.1021/nn402870e (2012).Google Scholar