Hostname: page-component-cd9895bd7-jn8rn Total loading time: 0 Render date: 2025-01-05T14:02:56.689Z Has data issue: false hasContentIssue false
  • English
  • Français

Polymer Behavior at the Air-Water Interface

Published online by Cambridge University Press:  31 January 2011

Ligia Gargallo
Ligia Gargallo
Affiliation:
Pontificia Universidad Católica de Chile, Department of Physical-Chemistry, Santiago, Chile; tel. 56-2-6864748; and e-mail [email protected].
Get access

Abstract

This article reviews polymer behavior at the air-water interface with a focus on the Langmuir technique and spreading processes to gain insight into this interface. The influence of the solvent and the water subphase on some polymer monolayers is discussed. The surface pressure–area isotherms (π–A) are described in terms of the chemical structure and the hydrophilic-hydrophobic balance of selected polymeric systems, with an emphasis on the behavior of the specific diblock copolymer films at the air-water interface. In some cases, molecular dynamic simulation studies can be used to visualize the organization and orientation of polymers at the air-water interface and to identify the main molecular interactions involved in such processes.

Type
Research Article
Information
MRS Bulletin , Volume 35 , Issue 8: Engineering Materials for Regenerative Medicine , August 2010 , pp. 615 - 622
Copyright
Copyright © Materials Research Society 2010

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1.Jones, R., Richards, R., Polymer at Surfaces and Interfaces (Cambridge University Press, UK, 1999).CrossRefGoogle Scholar
2.Gaines, G., Insoluble Monolayers at Liquid-Gas Interfaces (Interscience Publishers, NY, 1996).Google Scholar
3.Gaines, G.L., Langmuir, 7, 834 (1991).CrossRefGoogle Scholar
4.Ulman, A., An Introduction to Ultrathin Organic Films from Langmuir-Blodgett to Self-Assembly (Academic Press, NY, 1991).Google Scholar
5.Crisp, D.J., J. Colloid Sci., 1, 49 (1946).CrossRefGoogle Scholar
6.Kumaki, J., Macromolecules, 19, 2258 (1988).CrossRefGoogle Scholar
7.Kajiyama, T., Oishi, Y., Trends Polym. Sci., 3, 30 (1995).Google Scholar
8.Leiva, A., Gargallo, L., González, A., Radić, D., Eur. Polym. J. 40, 2349 (2004).CrossRefGoogle Scholar
9.Gargallo, L., Leiva, A., Urzúa, M., Alegría, L., Miranda, B., Radić, D., Polym. Int. 53, 1652 (2004).CrossRefGoogle Scholar
10.Miranda, B., Gargallo, L., Urzúa, M., Leiva, A., González-Nilo, F., Radić, D., Polymer 44, 3969 (2003).CrossRefGoogle Scholar
11.Ringard-Lefebre, C., Baszkin, A., Langmuir 10, 2376 (1994).CrossRefGoogle Scholar
12.Gargallo, L., Leiva, A., Alegría, L., Miranda, B., González, A., Radić, D., J. Macromol. Sci. Part B 43, 913 (2004).CrossRefGoogle Scholar
13.Ho, P.S., Appl. Surf. Sci. 41–42, 559 (1989).Google Scholar
14.Napper, D.H., Polymeric Stabilization of Colloidal Dispersion (Academic Press, London, 1983).Google Scholar
15.Leiva, A., Gargallo, L., González, A., Radić, D., J. Colloid Interface Sci., 292, 397 (2005).CrossRefGoogle Scholar
16.Luckham, P.F., in Polymer Surfaces and Interfaces, Feast, W.J., Munro, H.S., Eds. (Wiley, NY, 1987).Google Scholar
17.Blum, F.D., Ann. Rep. NMR Spectrosc. 28, 277 (1994).CrossRefGoogle Scholar
18.Blum, F.D., Colloids Surf 45, 361 (1990).CrossRefGoogle Scholar
19.Siegfried, E., Keul, H., Hocker, H., Macromolecules 29, 553 (1996).Google Scholar
20.Langevin, D., Ed., Light Scattering by Liquid Surfaces and Complementary Techniques (Marcel Dekker, NY, 1992).Google Scholar
21.Sauer, B.B., Walsh, D.J., Macromolecules, 27, 432 (1994).CrossRefGoogle Scholar
22.Li, B., Wu, Y., Liu, M., Esker, A.R., Langmuir 22, 4902 (2006).CrossRefGoogle ScholarPubMed
23.Faure, M.C., Bassereau, P., Lee, L.T., Menelle, A., Lheveder, C., Macromol. 32, 8538 (1999).CrossRefGoogle Scholar
24.Petty, M.C., Langmuir-Blodgett Films. An Introduction (Cambridge University Press, NY, 1996).CrossRefGoogle Scholar
25.Gonzalves da Silva, A.M., Filipe, J.M., d'Oliveira, J.M.R., Martinho, J.M.G., Langmuir 12, 6547 (1996).CrossRefGoogle Scholar
26.Currie, E.P.K., Leermarkers, F.A.M., Cohen Stuart, M.A., Fleer, G.J., Macromolecules 32, 487 (1999).CrossRefGoogle Scholar
27.Noskov, B.A., Akentiev, A.V., Miller, R., J. Colloid Interface Sci. 247, 117 (2002).CrossRefGoogle Scholar
28.Tadros, T.F., Vincent, B., Becher, P., Encyclopedia of Emulsion Technology (Marcel Dekker, NY, 1983).Google Scholar
29.Adamson, A.W., Physical Chemistry of Surfaces, 5th ed. (Wiley-Interscience, NY, 1990).Google Scholar
30.Crisci, L., Della Volpe, C., Maglio, G., Nese, G., Palumbo, R., Rachiero, G.P., Vignola, M.C., Macromol. Biosci. 3, 749 (2003).CrossRefGoogle Scholar
31.Allen, C., Han, J., Yu, Y., Maysinger, d., Eisenberg, A., J. Controlled Release 63, 275 (2000).CrossRefGoogle Scholar
32.Forster, S., Schmidt, M., Adv. Polym. Sci. 120, 50 (1995).Google Scholar
33.Dautzenberg, H., Jaeger, W., Kolz, B.P.J., Seidel, C., Stscherbina, D.K., Polyelectrolyte: Formation, Characterization and Application (Hanser Publishers, Munich, 1994).Google Scholar
34.Sugi, M., J. Mol. Electron. 1, 3 (1985).Google Scholar
35.Khanarian, G., Thin Solid Films 152, 265 (1987).CrossRefGoogle Scholar
36.Reichert, W., Bruckner, C., Joseph, J., Thin Solid Films 152, 335 (1987).CrossRefGoogle Scholar
37.Gargallo, L., Miranda, B., Ríos, A.H., González-Nilo, F., Radić, D., Polymer Inter. 50, 858 (2001).CrossRefGoogle Scholar
38.Glazer, J., J. Polym. Sci. 33, 355 (1954).CrossRefGoogle Scholar
39.Trapeznikov, A.A., Ogarev, V.A., Vysokomol. Soed. 3, 1708 (1961).Google Scholar
40.Bergeron, A., Gaines, G.L., Bellamy, W.D., J. Colloid Interface Sci. 25, 97 (1967).CrossRefGoogle Scholar
41.Yamashita, T., Nature 231, 445 (1971).CrossRefGoogle Scholar
42.Labbauf, A., Zack, J.R., J. Colloid Interface Sci. 35, 569 (1971).CrossRefGoogle Scholar
43.Gabrielli, G., Pugelli, M., Faccioli, R., J. Colloid Interface Sci. 37, 213 (1971).CrossRefGoogle Scholar
44.Gabrielli, G., Maddij, A., J. Colloid Interface Sci., 64, 19 (1978).CrossRefGoogle Scholar
45.Nakamae, K., Takeya, T., Fujimura, Y., Sakai, I., Matsumoto, T., J. Macromol. Sci. Phys. B 21, 157 (1982).CrossRefGoogle Scholar
46.Numby, S.Y., Swalen, J.D., Rabolt, J.F., Macromolecules 19, 1054 (1986).Google Scholar
47.McNally, E.J., Zografi, G.J., J. Colloid Interface Sci. 128, 61 (1990).CrossRefGoogle Scholar
48.Gargallo, L., Miranda, B., Leiva, A., Radić, D., Polimeri 46, 824 (2001).Google Scholar
49.Gargallo, L., Miranda, B., Leiva, A., Radić, D., Urzúa, M., Ríos, H., Polymer 45, 5145 (2004).CrossRefGoogle Scholar
50.Maleev, I.I., Tsvetkov, N.S., Twardon, J.E., Fisiko, S., Khim. Polim. 16, 111 (1975).Google Scholar
51.Baglioni, P., Gallori, E., Gabrielli, G., Ferroni, C., J. Colloid Interface Sci., 88, 221 (1982).CrossRefGoogle Scholar
52.Israelachvili, J., Langmuir 10, 3774 (1994).CrossRefGoogle Scholar
53.Hendlinger, P., Laschewsky, A., Bertrand, P., Delcorte, A., Legras, R., Nysten, B., Möbius, D., Langmuir 13, 310 (1997).CrossRefGoogle Scholar
54.Gargallo, L., Radić, D., Curr. Trends in Polym. Sci. 6, 121 (2001).Google Scholar
55.Takayuki, U., Satoshi, S., Shusaku, N., Takahiro, S., Trans. Mat. Res. Soc. Jpn. 31, 265 (2006).Google Scholar
56.Kawaguchi, M., Komatsu, S., Matsuzumi, M., Takahashi, A., J. Colloid Interface Sci. 102, 356 (1984).CrossRefGoogle Scholar
57.des Cloizeaux, J., Jannick, G., Polymers in Solutions (Clarendon Press, UK, 1990).Google Scholar
58.Poupinet, D., Vilanove, R., Rondelez, F., Macromolecules 22, 2491 (1989).CrossRefGoogle Scholar
59.de Gennes, P.G., Scaling Concepts in Polymer Physics (Cornell University Press, NY, 1979).Google Scholar
60.de Gennes, P.G., Phys. Lett. A 38, 339 (1972).CrossRefGoogle Scholar
61.Vilanove, R., Rondelez, F., Phys Rev Lett. 45, 1502 (1980).CrossRefGoogle Scholar
62.de Cloizeau, J., J. Phys (Paris) 36, 1199 (1975).Google Scholar
63.Reiter, J., Macromolecules 22, 3497 (1989).Google Scholar
64.Vilanove, R., Poupinet, D., Rondelez, F., Macromolecules 21, 2880 (1988).CrossRefGoogle Scholar
65.Derrida, B., Saleur, H., J. Phys. A: Math Gen. 18, L–1075 (1985).Google Scholar
66.Havlin, S., Ben Avraham, D., Phys. Rev. A 27, 2759 (1983).CrossRefGoogle Scholar
67.Derrida, B., J. Phys. A: Math Gen. 14, L-5 (1981).CrossRefGoogle Scholar
68.Chattoraj, D.K., Birdi, K.S., Adsorption and the Gibbs Surface Excess (Plenum Press, NY, 1984).CrossRefGoogle Scholar
69.Jaffe, J., Ruyschaert, J.M., Hecq, W., Bioquim. Biophys. Acta 207, 11 (1970).CrossRefGoogle Scholar
70.Romeu, N.V., Trillo, J.M., Conde, O., Casas, M., Iribarnegaray, E., Langmuir 13, 71 (1997).CrossRefGoogle Scholar
71.Huilin, Z., Weixing, L., Shufang, Y., Pingsheng, H., Langmuir 16, 2797 (2000).Google Scholar
72.Fleer, G.J., Cohen Stuart, M.A., Schentjens, J.M.H.M., Crosgrove, T., Vincent, B., Polymers at Interfaces (Chapman & Hill, London, 1993).Google Scholar
73.Riou, S.A., Chien, B.T., Ling Hsu, S., Studham, H.D., J. Polym. Sci. Part B, Polym. Phys. 35, 2843 (1997).3.0.CO;2-R>CrossRefGoogle Scholar
74.Reda, T., Hermel, H., Höltje, H.-D., Langmuir 12, 6452 (1996).CrossRefGoogle Scholar
75.McConnell, H.M., Annu. Rev. Phys. Chem. 42, 171 (1991).CrossRefGoogle Scholar
76.Möhwald, H., Annu. Rev. Phys. Chem. 41, 141 (1990).CrossRefGoogle Scholar
77.Knobler, C.M., Dessai, R.C., Annu. Rev. Phys. Chem. 43, 207 (1992).CrossRefGoogle Scholar
78.Hönig, D., Overbeck, G.A., Möbius, D., Adv. Mater. 4, 419 (1992).CrossRefGoogle Scholar
79.Riou, S.A., Hsu, S.L., Stidham, H.D., Langmuir 14, 3062 (1998).CrossRefGoogle Scholar
80.Dynarowicz-Latka, P., Dhanabalan, A., Cavalli, A., Oliveira, O.N., J. Phys. Chem. B104, 1701 (2000).CrossRefGoogle Scholar
81.Li, Z., Zhao, W., Quinn, J., Rafailovich, M.H., Sokolov, J., Lennox, R.B., Eisenberg, A., Wu, X.Z., Kim, M.W., Sinha, S.K., Tolan, M., Langmuir 11, 4785 (1995).CrossRefGoogle Scholar
82.Zhu, J., Eisenberg, A., Lennox, R.B., Macromolecules 25, 6547 (1992).CrossRefGoogle Scholar
83.Chovino, C., Gramain, P., Macromolecules 31, 7111 (1998).CrossRefGoogle Scholar
84.Dann, J.R., J. Colloid Interface Sci. 32, 302 (1970).CrossRefGoogle Scholar
85.de Gennes, P.G., Adv. Colloid Interface Sci. 27, 189 (1987).CrossRefGoogle Scholar
86.Urzúa, M., Gargallo, L., Radic, D., J. Macromol. Sci. Pure Appl. Chem. A37, 37 (2000).CrossRefGoogle Scholar
87.Gargallo, L., Miranda, B., Leiva, A., González, A., Sandoval, C., Radić, D., Tagle, L.H., J. Macromol. Sci. Part B. Physics 45, 105 (2006).CrossRefGoogle Scholar
88.Gargallo, L., Miranda, B., Leiva, A., Ríos, H., González-Nilo, F., Radić, D., J. Colloid Interface Sci. 271, 181 (2004).CrossRefGoogle Scholar
89.Carminati, G., Gabrielli, G., Ferroni, E., Colloids Surfaces 41, 189 (1989).CrossRefGoogle Scholar
90.Poncet, C., Tiberg, F., Audebert, R., Langmuir 14, 1897 (1998).CrossRefGoogle Scholar
91.Miranda, B., Hilles, H.M., Rubio, R.G., Ritacco, H., Radić, D., Gargallo, L., Sferrazza, M., Ortega, F., Langmuir 25, 21, (2009).CrossRefGoogle Scholar
92.Chen, Z.Y., Phys. Rev. Lett. 71, 93 (1993).CrossRefGoogle Scholar
93.Dhathathreyan, A., Collins, S.J., Langmuir 18, 928 (2002).CrossRefGoogle Scholar
94.Okamura, E., Fukushima, N., Hayashi, S., Langmuir 15, 3589 (1999).CrossRefGoogle Scholar
95.Rovillard, S., Perez, E., Ionov, R., Voue, M., de Coninck, J., Langmuir 15, 2749 (1999).CrossRefGoogle Scholar
96.Bandyopadhyay, S., Chanda, J., Langmuir 19, 10443 (2003).CrossRefGoogle Scholar
97.Chanda, J., Bandyopadhyay, S., J. Chem. Theory Comput. 1, 963 (2005).CrossRefGoogle Scholar
98.Dominguez, H., Berkowitz, M.L., J. Phys. Chem. B 104, 5302 (2000).CrossRefGoogle Scholar
99.Schweighofer, K.J., Essmann, U., Berkowitz, M., J. Phys. Chem. B 101, 10775 (1997).CrossRefGoogle Scholar
100.Collins, S.J., Dhathathreyan, A., Ramasami, T., J. Coll. Interf. Sci. 203, 249 (1998).CrossRefGoogle Scholar
101.Gallet, X., Deleu, M., Razafindralambo, H., Jacques, P., Yhonart, P., Paquot, M., Brasseur, R., Langmuir 15, 2409 (1999).CrossRefGoogle Scholar
102.Kawaguchi, M., Kamatsu, S., Matsuzumi, M., Takahashi, A., J. Colloid Inter. Sci. 102, 356 (1984).CrossRefGoogle Scholar