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In Situ Investigations of Chemical Reactions on Surfaces by X-Ray Diffraction at Atomospheric Pressures

Published online by Cambridge University Press:  31 January 2011

S. Ferrer ,
M. D. Ackermann  and
E. Lundgren
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Abstract

Catalytic reactions occurring at metal surfaces and nanoparticles have been an established research field for decades, yielding information on adsorption sites and reaction pathways under ultrahigh-vacuum conditions. Recent experimental developments have made it possible to perform well-controlled in situ surface x-ray diffraction measurements from single-crystal surfaces and nanoparticles under industrially relevant conditions. In this way, a new understanding of atomic-scale processes at surfaces and nanoparticles occurring during catalytic reactions under realistic conditions has been gained. In particular, the identification of the formation of thin oxides on model catalysts and their role in oxidation reactions demonstrates the importance of in situ probes under relevant conditions.

Type
Research Article
Information
MRS Bulletin , Volume 32 , Issue 12: Novel In Situ Probes for Nanocatalysis , December 2007 , pp. 1010 - 1014
Copyright
Copyright © Materials Research Society 2007

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References

1.Ertl, G., Angew. Chem. Int. Ed. Engl. 29, 1219 (1990).CrossRefGoogle Scholar
2.Bernard, P., Peters, K., Alvarez, J., Ferrer, S., Rev. Sci. Instrum. 70, 1478 (1999).CrossRefGoogle Scholar
3.Ferrer, S., Comin, F., Rev. Sci. Instrum. 66, 1674 (1995).CrossRefGoogle Scholar
4.Stierle, A., Steinhäuser, A., Rühm, A., Renner, F.U., Weigel, R., Kasper, N., Dosch, H., Rev. Sci. Instrum. 75, 5302 (2004).CrossRefGoogle Scholar
5.Kasper, N., Stierle, A., Nolte, P., Jin-Phillipp, Y., Wagner, T., De Oteyza, D.G., Dosch, H., Surf. Sci. 600, 2860 (2006).CrossRefGoogle Scholar
6.Peters, K.F., Walker, C.J., Steadman, P., Robach, O., Isern, H., Ferrer, S., Phys. Rev. Lett. 86, 5325 (2001).CrossRefGoogle Scholar
7.Quiros, C., Robach, O., Isern, H., Ordejon, P., Ferrer, S., Surf. Sci. 522, 161 (2003).CrossRefGoogle Scholar
8.Ackermann, M.D., Robach, O., Walker, C., Quiros, C., Isern, H., Ferrer, S., Surf. Sci 557, 21 (2001).CrossRefGoogle Scholar
9.Kelley, R.D., Goodman, D.W., Surf. Sci. 123, 743 (1982).CrossRefGoogle Scholar
10.Over, H., Kim, Y.D., Seitsonen, A.P., Wendt, S., Lundgren, E., Schmid, M., Varga, P., Morgante, A., Ertl, G., Science 287, 1474 (2000).CrossRefGoogle Scholar
11.Hendriksen, B.L.M., Frenken, J.W.M., Phys. Rev. Lett. 89, 046101 (2002).CrossRefGoogle Scholar
12.Todorova, M., Lundgren, E., Blum, V., Mikkelsen, A., Gray, S., Gustafson, J., Borg, M., Rogal, J., Reuter, K., Andersen, J.N., Scheffler, M., Surf. Sci. 541, 101 (2003).CrossRefGoogle Scholar
13.Lundgren, E., Gustafson, J., Mikkelsen, A., Andersen, J.N., Stierle, A., Dosch, H., Todorova, M., Rogal, J., Reuter, K., Scheffler, M., Phys. Rev. Lett. 92, 046101 (2004).CrossRefGoogle Scholar
14.Stierle, A., Kasper, N., Dosch, H., Gustafson, J., Mikkelsen, A., Andersen, J.N., Lundgren, E., J. Chem. Phys. B 122, 044706 (2005).CrossRefGoogle Scholar
15.Kostelnik, P., Seriani, N., Kresse, G., Mikkelsen, A., Lundgren, E., Blum, V., Sikola, T., Varga, P., Schmid, M., Surf. Sci. 601, 1574 (2007).CrossRefGoogle Scholar
16.Gustafson, J., Mikkelsen, A., Borg, M., Lundgren, E., Köhler, L., Kresse, G., Schmid, M., Varga, P., Yuhara, J., Torrelles, X., Quiros, C., Andersen, J.N., Phys. Rev. Lett. 92, 126102 (2004).CrossRefGoogle Scholar
17.He, Y.B., Knapp, M., Lundgren, E., Over, H., J. Phys. Chem. B 109, 21825 (2005).CrossRefGoogle Scholar
18.Schmid, M., Reicho, A., Stierle, A., Costina, I., Klikovits, J., Kostelnik, P., Dubay, O., Kresse, G., Gustafson, J., Lundgren, E., Andersen, J.N., Dosch, H., Varga, P., Phys. Rev. Lett. 96, 146102 (2006).CrossRefGoogle Scholar
19.Reicho, A., Stierle, A., Costina, I., Dosch, H., Surf. Sci. 601, 19 (2007).CrossRefGoogle Scholar
20.Hendriksen, B.L.M., Frenken, J.W.M., Surf. Sci. 552, 229 (2004).CrossRefGoogle Scholar
21.Mars, P., van Krevelen, D.W., Chem. Eng. Sci. 3, 41 (1954).CrossRefGoogle Scholar
22.Lundgren, E., Mikkelsen, A., Andersen, J.N., Kresse, G., Schmid, M., Varga, P., J. Phys. Condens. Matter 18, 481 (2006).CrossRefGoogle Scholar
23.Ackermann, M.D., Pedersen, T.M., Hendriksen, B.L.M., Robach, O., Bobaru, S.C., Popa, I., Quiros, C., Kim, H., Hammer, B., Ferrer, S., Frenken, J.W.M., Phys. Rev. Lett. 95, 255505 (2005).CrossRefGoogle Scholar
24.Nørskov, J.K., Scheffler, M., Toulhoat, H., MRS Bull. 31, 669 (2006).CrossRefGoogle Scholar