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A Historical Perspective on the Occurrence of Piezoelectricity in Materials*

Published online by Cambridge University Press:  29 November 2013

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This article provides an overview of the piezoelectric effect in all the classes of materials in which it is found to occur. This includes select materials from the categories of naturally occurring single crystals, polycrystalline ceramics, and semicrystalline polymers. Throughout this development, an attempt is made to point out the common factor for the piezoelectric effect in all these materials, namely, the presence of dipolar moieties, whose orientation brings about a net polarization in the material as a whole.

The applications of each of these classes of materials are covered briefly. Each such application has a specific value based on the aggregate properties of the material as a whole, making each material complementary rather than competitive in device applications.

Brief mention is made of the mathematics and geometry of the piezoelectric effect in order to define the piezoelectric constants by which the properties of these materials are described. The article then focuses on the basis of the piezoelectric response in synthetic polymers.

Piezoelectricity or “pressure electricity” was coined from the Greek verb “piezen,” to press, by Pierre and Jacques Curie in the 1880s during an investigation of the symmetry in crystals. In this work it was found that certain crystals, lacking a center of symmetry, produced an electrical charge when mechanically deformed. The converse effect was also found to occur, whereby applying an electric field caused the crystal to change its shape. This phenomenon was attributed to a deformation of the net internal polarization in the crystal. When no external forces are present, the centers of positive and negative charges will coincide, and there is no net polarization. The application of a stress, be it mechanical (pressure) or electrical (applied field), causes a displacement of the centers of gravity of the positive and negative charges. In the absence of a center of symmetry, the charge displacement will be nonsymmetrical and thereby produce an induced dipole moment. This dipole moment, if produced by a mechanical stress, will cause the surfaces to develop an effective charge. If an external field displaces the charges, by electrostatic attraction or repulsion, it produces a mechanical strain which causes the material to deform. The mathematical relations describing this effect were developed in the few years following their discovery, making use of tensor notation to describe the directionality of the applied stress and the resultant strain.

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Technical Features
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Copyright © Materials Research Society 1989

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Footnotes

*

An earlier version of this article was published in Journal of Materials Education, Vol. 9, No. 3. Reprinted with permission.

References

1.Cady, W.G., Piezoelectricity, 1st ed., (McGraw-Hill, 1946) Ch. 8.Google Scholar
2.Mason, W.P., Piezoelectric Crystals and Their Applications to Ultrasonics (Van Nostrand, 1949).Google Scholar
3.Fatuzzo, E. and Merz, W.J., Selected Topics in Solid State Physics: Ferroelectrics, (North Holland, 1967) Ch. 1,2.Google Scholar
4.Technical Manual, Kynar Piezo Film Dept., Penwalt Corp., 900 First Ave., P.O. Box C, King of Prussia, PA. 19406-0018.Google Scholar
5.Burfoot, J.C., Ferroelectrics: an Introduction to the Physical Principals (Van Nostrand, 1967).Google Scholar
6.Ruby, D., Popular Science (July 1982) p. 69.Google Scholar
7.Oshry, H.I. and Minkowski, J.M., Physical Properties of Piezoelectric Barium Titanate Ceramics, Erie Resistor Corp., Report 3004, (February 1952).Google Scholar
8.Hayakawa, R. and Wada, Y., Adv. in Polym. Sci. 11 (1973) p. 1.CrossRefGoogle Scholar
9.Fukada, E., Ultrasonics 6(4) (1968) p. 229.CrossRefGoogle Scholar
10.Hayakawa, R. and Wada, Y., Adv. in Polymer Sci. 11(1) (1973) p. 1.CrossRefGoogle Scholar
11.Kasai, K., J. Phys. Soc. Jpn. 27 (5) (1969) p. 1268.CrossRefGoogle Scholar
12.English, J.P.. Vanderbilt, D.P., and McNeeley, G.W., Report No. NADC- 87184-60 (September 1987).Google Scholar
13.Kepler, R.G. and Anderson, R.A., CRC Critical Revs. Solid State and Mat. Sci. 9(4) (19801982) p. 339.Google Scholar
14.Kepler, R.G., Ann. Rev. Phys. Chem. 29 (1978) p. 497.CrossRefGoogle Scholar
15.Namiki, K., Hayakawa, R. and Wada, Y., J. Polym. Sci., Polym. Phys. Ed. 18 (1980) p. 993.CrossRefGoogle Scholar
16.Holcroft, B., Petty, M.C., Roberts, G.G. and Russel, G.J., Thin Solid Films 134 (1985) p. 83.CrossRefGoogle Scholar
17.Kawai, H., Jpn. J. Appl. Phys. 8 (1969) p. 975.CrossRefGoogle Scholar
18.Legrand, J.F.et. al., Ferroelectrics 78 (1988) p. 151.CrossRefGoogle Scholar
19.Mathur, S.C., Scheinbeim, J.I., and Newman, B.A., J. Appt. Phys. 56 (9) (1984) p. 2419.CrossRefGoogle Scholar
20.Electrical Properties of Polymers, edited by Seanor, D.A. (Academic Press, 1983) Ch. 5.Google Scholar
21.Betz, R., Ferroelectrics 75 (1987) p. 397.CrossRefGoogle Scholar
22.Smith, W.A. and Shaulov, A.A., Ferroelectrics (1988).Google Scholar
23.Topics in Applied Physics: Electrets, edited by Sessler, G.M., (Springer-Verlag, 1987) Ch. 5.Google Scholar
24.Lovinger, A.J., Science 220 (4602) (1983) p. 1115.CrossRefGoogle Scholar
25.Litt, M.H., Hsu, C., and Basu, P., J. Appl. Phys. 48 (6) (1977) p. 2208.CrossRefGoogle Scholar
26.Broadhurst, M.G. and Davis, G.T., Ferroelectrics 60 (1984) p. 3.CrossRefGoogle Scholar
27.Kinoshita, Y., Makromol. Cnem. 33 (1959) p. 1.CrossRefGoogle Scholar
28.Scheinbeim, J.I., J. Appl. Phys. 52(10) (1981) p. 5939.CrossRefGoogle Scholar
29.Adams, L.M. and Silvus, H.S., J. Appl. Polym. Sci. 25 (1980) p. 2445.CrossRefGoogle Scholar
30.Geiss, D., Danz, R., Janke, A., and Kunstler, W., IEEE Trans. Elec. Insul. EI-22(3) (1987) p. 347.CrossRefGoogle Scholar
31.Litt, M.H. and Lin, J.C., Ferroelectrics 57 (1984) p. 171.CrossRefGoogle Scholar
32.Tashiro, K., Tadokoro, H., and Kobatashi, M., Ferroelectrics 32 (1981) p. 167.CrossRefGoogle Scholar
33.Scheinbeim, J.I., Mathur, S.C., and Newman, B.A., J. Polym. Sci.: Pt. B 24 (1986) p. 1791.CrossRefGoogle Scholar
34.Jacobs, E.W. and Hicks, J.C., Appl. Phys. Lett. 44 (4) (1984) p. 402.CrossRefGoogle Scholar
35.Ueda, H. and Carr, S.H., Polymer J. 16(9) (1984) p. 661.CrossRefGoogle Scholar
36.Topics in Applied Physics: Electrets, edited by Sessler, G.M. (Springer-Verlag, 1987) Ch. 3.Google Scholar
37.Wu, G., Yano, O., and Soen, T., Polymer Journal 18 (1986) p. 51.CrossRefGoogle Scholar
38.Inoue, Y.et. al., Polymer Commun. 29 (1988) p. 105.CrossRefGoogle Scholar
39.Tasaka, S.et al., Ferroelectrics 57 (1984) p. 267.CrossRefGoogle Scholar
40.Hall, H.K., J. Macromol. Sci. - Chem. A25(5-7) (1988) p. 729.CrossRefGoogle Scholar
41.Humphrey, K.J., Garner, G.M., and Whatmore, R.W., Ferroelectrics 76 (1987) p. 383.CrossRefGoogle Scholar
42.Magill, J.H., J. Polym. Sci. A-2(9) (1971) p. 815.Google Scholar
43.Newman, B.A.et. al., J. Appl. Phys. 51(10) (1980) p. 5161.CrossRefGoogle Scholar
44.Mathur, S.C., “Piezoelectric Properties of Nylon 11 and Nylon 7 (Plasticization), PhD thesis, Rutgers University, 1986.Google Scholar
45.Jaffe, B., A Primer on Ferroelectricity and Piezoelectric Ceramics, Clevite Corp., Electronics Research Div., Cleveland, OH.Google Scholar
46.Topics in Applied Physics: Electrets, edited by Sessler, G.M., (Springer-Verlag, 1987) p. 370.Google Scholar
47.Yagi, T.et. al., Ferroelectrics 57 (1984) p. 327.CrossRefGoogle Scholar