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High-Temperature Oxidation of Stainless Steels

Published online by Cambridge University Press:  29 November 2013

J.C. Colson  and
J.P. Larpin
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The first stainless steels, mainly low carbon chromium-iron alloys, have been known since the beginning of this century. These steels show good resistance against wet corrosion and high-temperature corrosion. This article focuses on high-temperature corrosion, with emphasis on gaseous sulfidizing and oxidizing environments. The discussion is limited to these two gases since corrosion involving halogen-and/or carbon-containing gases involves other specific processes. The behavior of binary and ternary alloys will be successively examined, then the role of minor elements will be considered.

Fundamental Mechanisms of High-Temperature Corrosion of Stainless Steel

Usually, a dry corrosion process results in the formation of corrosion products, giving a simple or complex oxide or sulfide scale on a metallic substrate, separating it from the aggressive gaseous environment and, consequently, acting as a protective barrier. Scale growth is controlled by the conductivity of the reaction products which are solid electrolytes. Generally, the mechanism of scale growth is governed by outward cation or inward anion diffusion processes. This is the basis of the model originally put forward by Wagner for a single metal and subsequently developed for alloys, and particularly, for stainless steels. This one-way point-defect diffusion process is responsible for the observed parabolic scaling kinetics characterized by a parabolic rate constant kp. This model is well described in the literature.

In the case of stainless steels, formation of a protective scale is required; this is possible if the oxide or sulfide products have a low diffusivity to cations or anions due to a low density of point defects in the crystal lattice. The protective characteristics of the corrosion products may be experimentally determined by measurement of their electrical conductivity, although the scales should also be effective against short-circuit transport of ions, atoms, or molecules. The best barriers consist of oxides, such as Al2O3, SiO2, and Cr2O3.

Type
Corrosion and Coating
Information
MRS Bulletin , Volume 19 , Issue 10 , October 1994 , pp. 23 - 25
Copyright
Copyright © Materials Research Society 1994

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References

1.Lacombe, P., Barroux, B., and Beranger, , Stainless Steel (Editions de Physique, Paris, 1993).Google Scholar
2.Kroger, F.O., The Chemistry of Imperfect Crystals (North Holland, Amsterdam, 1964).CrossRefGoogle Scholar
3.Mrowec, S., Defects and Diffusion in Solids (Elsevier, Amsterdam, 1980).Google Scholar
4.Birks, N. and Meier, G.H., Introduction to High Temperature Oxidation of Metals (Arnold, London, 1983).Google Scholar
5.Wagner, C., Z. Phys. Chem. (Frankfurt) 21, 25 (1933).CrossRefGoogle Scholar
6.Wagner, C., Atom Movements (American Society of Metals, Cleveland, OH, 1951) p. 151.Google Scholar
7.Bedard, J., L'Oxydation des Metaux, Volumes I and II (Gauthier Villars, Paris, 1962).Google Scholar
8.Hauffe, K., Oxidation of Metals (Plenum Press, New York, 1965).Google Scholar
9.Davidson, J.H, in Corrosion des Matériaux à Haute Température, edited by Beranger, G., Colson, J.C., and Dabosi, F., (Editions de Physique, Paris, 1985) p. 395.Google Scholar
10.Lambertin, M. and Colson, J.C., Oxid. Met. 6 (1973) p. 164.Google Scholar
11.Aguilar, G., Dupont, L., Foissy, A., Larpin, J.P., Colson, J.C., Mem. Sci. Rev. Met. 12 (1993) p. 1607.Google Scholar
12.Jackson, P.R.S. and Wallwork, G.R., Oxid. Met. 20 (1983) p. 365.CrossRefGoogle Scholar
13.Buscail, H., Sotto, P., and Larpin, J.P., J. Phys. 3 (1993) p. 309.Google Scholar
14.Wallwork, G.R. and Hed, Z., Oxid. Met. 1 (1969) p. 635.Google Scholar
15.Brasunas, A., Gow, J.T., and Harder, O.E., Proc. ASTM 46 (1946) p. 870.Google Scholar
16.Aguilar, G., Colson, J.C., and Larpin, J.P., Mem. Sci. Rev. Met. 7–8 (1992) p. 447.Google Scholar
17.Strafford, K.N. and Manifold, R., Corros. Sci. 9 (1969) p. 489.CrossRefGoogle Scholar
18.Colson, J.C. and Larpin, J.P., Mater. Sci. Eng. 87 (1987) p. 11.CrossRefGoogle Scholar
19.Stott, F.H. and Wood, G.C., Corros. Sci. 11 (1971) p. 799.CrossRefGoogle Scholar
20.Ham, J.L. and Cairns, R.E., Product Eng. 29 (1958) p. 10.Google Scholar
21.Jackson, P.R.S and Wallwork, G.R., Oxid. Met. 20 (1983) p. 1.CrossRefGoogle Scholar
22.Rhys-Jones, T.N. and Grabke, H.J., Mater. Sci. Tech. 11 (1988) p. 446.CrossRefGoogle Scholar
23.Bonnet, G., Aguilar, G., Colson, J.C., and Larpin, J.P., Corros. Sci. 35 (1993) p. 5–8, p. 893.CrossRefGoogle Scholar
24.Mrowec, S., Walec, T., and Werber, T., Oxid. Met. 1 (1969) p. 93.CrossRefGoogle Scholar
25.Narita, T. and Nishida, K., Oxid. Met. 3 (1973) p. 157 and 181.CrossRefGoogle Scholar
26.Perez, M. and Larpin, J.P., Oxid. Met. 24 (1985) p. 29.CrossRefGoogle Scholar
27.Nishida, K., Narita, T., Tani, T., and Sasaki, G., Oxid. Met. 14 (1980) p. 75.CrossRefGoogle Scholar
28.Mrowec, S., Werber, T., and Podorodecki, J., Corros. Sci. 9 (1969) p. 815.Google Scholar
29.Mrowec, S., Werber, T., and Podorodecki, J., Corros. Sci. 7 (1967) p. 697.CrossRefGoogle Scholar
30.Larpin, J.P., Lambertin, M., and Colson, J.C., C.R. Acad. Sci. 285 (1977) p. 229.Google Scholar
31.Giggins, C.S. and Pettit, F.S., Oxid. Met. 14 (1980) p. 363.CrossRefGoogle Scholar
32.Larpin, J.P., Mari, P.A., Chaix, J.M., and Colson, J.C., Solid State Ionics 12 (1984) p. 459.CrossRefGoogle Scholar