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Ferroelectric glass-ceramics

Published online by Cambridge University Press:  06 March 2017

Manuel Pedro Fernandes Graça  and
Manuel Almeida Valente
Manuel Pedro Fernandes Graça
Affiliation:
Institute of Nanostructures, Nanofabrication, and Nanomodeling, Universidade de Aveiro, Portugal; [email protected]
Manuel Almeida Valente
Affiliation:
Institute of Nanostructures, Nanofabrication, and Nanomodeling, Universidade de Aveiro, Portugal; [email protected]
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Abstract

Many current technological applications are based on the electrical properties of materials. Among these, ferroelectricity, antiferroelectricity, paraelectricity, and resistivity are the most important to be studied and controlled. To overcome important drawbacks of sintered ceramics or single crystals with these characteristics, the preparation of glass-ceramics with these phases dispersed in a glass matrix is a possible solution. The formation of glass-ceramics shows great advantages—their properties (optical, electrical, mechanical, and chemical) can be controlled via the volume fraction of the dispersed active phase. Thus, the preparation and properties of glass-ceramics containing ferroelectric crystallites embedded in the glass matrix have received considerable interest. This article discusses state-of-the-art preparation of glass-ceramics with one important technological ferroelectric crystal, lithium niobate (LiNbO3). Since the preparation of LiNbO3 single crystals by traditional growth techniques is technically difficult and economically costly—and with dense ceramics, it is difficult to achieve a congruent composition—scientific research on the fabrication methods of inorganic glasses containing LiNbO3 crystallites is an important current topic.

Keywords

ferroelectricNbamorphouscrystal growthdielectric properties
Type
Research Article
Information
MRS Bulletin , Volume 42 , Issue 3: Glass-ceramics , March 2017 , pp. 213 - 219
Copyright
Copyright © Materials Research Society 2017 

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