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Cathodoluminescence Microscopy: A Valuable Technique for Studying Ceramic Materials

Published online by Cambridge University Press:  29 November 2013

Richard D. Hagni  and
Musa Karakus
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Over the past 10 to 20 years, cathodo-luminescence microscopy (CLM) has become an important, standard technique for studying many geological materials, but its application to ceramic material has not been fully realized. CLM has been found to be especially valuable in determining original porosity in carbonate rocks, a feature that was extremely important in determining the ability of petroleum and related fluids to migrate through the rocks and concentrate in the favorable structures where petroleum is found today. CLM constitutes one of the most significant techniques employed in the exploration for petroleum, but the results of those investigations remain largely unpublished in company files. A number of investigations have discussed the application of cathodoluminescence (CL) to studies of porosity in carbonates.

Other applications of CLM to geology involve metals exploration. Halos of red CL feldspar in the rocks around carbon-atite deposits, which may contain rare earths, copper, and other metals, contrast with feldspar crystals with blue or blue-green CL that are distal from the ore deposits. Dolomite associated with lead-zinc ores may exhibit growth zoning by CL that can be used to trace the path of the ore fluids for distances of 100 miles or more. The detection of host rock limestone alteration in the Tri-State zinc-lead district, potassic and argillic alteration at the Henderson molybdenite mine, and ore guides in other metallic deposits by CL was discussed by Hagni.

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Refractories
Information
MRS Bulletin , Volume 14 , Issue 11 , November 1989 , pp. 54 - 59
Copyright
Copyright © Materials Research Society 1989

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References

1.Grover, G. Jr. and Read, J.F., Amer. Assoc. Petroleum Geologists Bull. 67 (1983) p. 1275.Google Scholar
2.Dorobek, S.L., Amer. Assoc. Petroleum Geologists Bull. 71 (1987) p. 492.Google Scholar
3.Kaufman, J., Cander, H.S., Daniels, L.D., and Meyers, W.J., J. Sedimentary Petrology 58 (1988) p. 312.Google Scholar
4.Amieux, P. and Jeanbourquin, P., Bull. Soc. Geol. France 8 (1989) p. 123.CrossRefGoogle Scholar
5.Mariano, A.N., in Proceedings of the International Symposium on Carbonatites, edited by Braga, C.J. 1st (Pocos de Caldas, Minas Gerais, Brazil, 1976) p. 39.Google Scholar
6.Ebers, M.L. and Kopp, O.C., Econ. Geol. 74 (1979) p. 908.CrossRefGoogle Scholar
7.Voss, R.L. and Hagni, R.D., Chap. 5 in Mineralogy-Applications to the Minerals Industry, Proceedings of the Paul F. Kerr Memorial Symposium, edited by Hausen, D.M. and Kopp, O.C. (AIME, New York, NY, 1985) p. 51.Google Scholar
8.Kopp, O.C., Ebers, M.L., Cobb, L.B., Crattie, T.B., Ferguson, T.L., Larsen, R.M., Potosky, R.A., and Steinberg, R.T., in Process Mineralogy VI: Applications to Precious Metals Deposits, Industrial Minerals, Coal, Liberation, Mineral Processing, Agglomeration, Metallurgical Products, and Refractories, with Special Emphasis on Cathodoluminescence Microscopy, edited by Hagni, R.D. (TMS-AIME, Warrendale, PA, 1986) p. 53.Google Scholar
9.Voss, R.L., Hagni, R.D., and Gregg, J.M., Carbonates and Evaporites, in press.Google Scholar
10.Hagni, R.D., in Applied Mineralogy, Proceedings of the Second International Congress on Applied Mineralogy in the Minerals Industry, edited by Park, W.C., Hausen, D.M., and Hagni, R.D. (AIME, New York, 1985) p. 41.Google Scholar
11.Hagni, R.D., in Process Mineralogy VI: Applications to Precious Metals Deposits, Industrial Minerals, Coal, Liberation, Mineral Processing, Agglomeration, Metallurgical Products, and Refractories, with Special Emphasis on Cathodoluminescence Microscopy, edited by Hagni, R.D. (TMS-AIME, Warrendale, PA, 1986) p. 37.Google Scholar
12.Derham, C.J., Geake, J.E., and Walker, G., Nature 203 (1964) p. 134.CrossRefGoogle Scholar
13.Hutcheon, I.D., Steele, I.M., Smith, J.V., and Clayton, R.N., Proc. Lunar Planet. Sci. Conf. (1978) p. 1345.Google Scholar
14.Dudley, R.J., J. Soil Science 27 (1976) p. 487.CrossRefGoogle Scholar
15.Barker, C.E. and Wood, T., in Process Mineralogy VI: Applications to Precious Metals Deposits, Industrial Minerals, Coal, Liberation, Mineral Processing, Agglomeration, Metallurgical Products, and Refractories, with Special Emphasis on Cathodoluminescence Microscopy, edited by Hagni, R.D. (TMS-AIME, Warrendale, PA, 1986b) p. 159.Google Scholar
16.Marshall, D.J., Cathodoluminescence of Geological Materials (Unwin Hyman, Boston, MA, 1988).Google Scholar
17.Hagni, R.D. and Cooper, M., Characterization of Accessory Minerals in the Birmingham Red Iron Ores and Eufaula Ferruginous Bauxite Deposits in Alabama, U.S. Bureau of Mines, NTIS microfiche, 1981.Google Scholar
18.Hagni, R.D. and Cooper, M., in Process Mineralogy II: Applications in Metallurgy, Ceramics, and Geology, edited by Hagni, R.D. (AIME, New York, NY, 1982) p. 95.Google Scholar
19.Karakus, M. and Hagni, R.D., AIME Annual Meeting, Las Vegas, Nevada (1989) p. 141.Google Scholar
20.Yacobi, B.G. and Holt, D.B., J. Appl. Physics 59 (1986) p. R1.CrossRefGoogle Scholar
21.Harmer, P.R., Ford, S.D., and Dugdale, R.A., J. Sci. Inst. Series 2 1, p. 59.CrossRefGoogle Scholar
22.Czernuszka, J.T. and Page, T.F., J. Am. Ceram. Soc. 68 (1985) p. C–196.Google Scholar
23.Rincon, J.M., Fernandez, P., and Llopis, J., Appl. Physics A 44 (1987) p. 299.CrossRefGoogle Scholar
24.Karakus, M., Hagni, R.D., Moore, R.E., and Mendoza, J.L., American Ceramic Society, 91st Annual Meeting, Indianapolis, Indiana (1989a), p. 394.Google Scholar
25.Karakus, M., Hagni, R.D., and Moore, R.E., Intl. Symp. Appl. Mineralogy sponsored by the Mineralogical Assoc. Canada, the Intl. Cong, on Mineralogy Appl. to the Minerals Industry, and the Intl. Mineralogical Assoc.—Commission on Appl. Mineralogy, Montreal, Quebec, Canada, 1986b, p. 134.Google Scholar
26.Frank, J.R., Carpenter, A.B., and Oglesby, T.W., J. Sedimentary Petrology 52 (1982) p. 631.Google Scholar
27.Barker, C.E. and Wood, T., in Process Mineralogy VI: Applications to Precious Metals Deposits, Industrial Minerals, Coal, Liberation, Mineral Processing, Agglomeration, Metallurgical Products, and Refractories, with Special Emphasis on Cathodoluminescence Microscopy, edited by Hagni, R.D. (TMS-AIME, Warrendale, PA, 1986a) p. 137.Google Scholar
28.Goebel, V.W. and Patzelt, W.J., Leitz Sci. & Tech. Info. VI (1976) p. 263.Google Scholar
29.Reid, L.R. and Smith, J.P., Review Sci. Inst. 40 (1969) p. 316.CrossRefGoogle Scholar
30.Lebiedzik, J., White, E.W., and Shalla, R.J.R.S.B., Review of Scientific Instruments 45 (1974) p. 451.CrossRefGoogle Scholar
31.Mariano, A.N. and Ring, P.J., Geochimica et Cosmochimica Acta 39 (1975) p. 649.CrossRefGoogle Scholar
32.Mariano, A.N., Chap. 8 in Cathodoluminescence of Geological Materials, by Marshall, D.J., Unwin Hyman, (Boston, MA, 1988) p. 76.Google Scholar
33.Marshall, D.J., Giles, J., and Mariano, A.N., in Process Mineralogy VI: Applications to Precious Metals Deposits, Industrial Minerals, Coal, Liberation, Mineral Processing, Agglomeration, Metallurgical Products, and Refractories, with Special Emphasis on Cathodoluminescence Microscopy, edited by Hagni, R.D. (TMS-AIME, Warrendale, PA, 1986) p. 117.Google Scholar
34.Gregg, J.M. and Karkus, M., in review.Google Scholar