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Actinide Colloids in Natural Aquifer Systems

Published online by Cambridge University Press:  29 November 2013

J.I. Kim
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Extract

Immobilization and geological isolation are the general goals of nuclear waste disposal. The appropriate isolation of immobilized long-lived radionuclides, mostly actinide elements, from interaction with water for a period of many thousands of years in any given geological formation is a scientific and technological challenge. This challenge can be met by considering a multibarrier concept that appraises engineered, geoengineered, and geological barriers designed to confine the migration of long-lived actinides. Once interaction with water occurs, one may expect many complex geochemical reactions of immobilized actinides; actinides will therefore be distributed into two kinds of chemical states, mobile and immobile species. Reflecting results in laboratory systems, the two species are expected to be chemical partners in equilibrium reactions. In multicomponent geochemical systems, however, the chemistry of the mobile and immobile species of actinides in trace concentration is, in general, masked by geochemical reactions of natural aquatic constituents, which are found in much higher concentrations. The mobile species are either complexed anions or colloidal species, whereas the immobile species are new solid phases of very low solubility, which are thermodynamically better stabilized than in the original host phases.

Type
Nuclear Waste Disposal
Information
MRS Bulletin , Volume 19 , Issue 12 , December 1994 , pp. 47 - 53
Copyright
Copyright © Materials Research Society 1994

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References

1. The Proceedings of the International Conferences on the Chemistry and Migration Behavior of Actinides and Fission Products in the Geosphere: Radiochim. Acta 44/45 (1988) p. 3429; 52/53 (1991) p. 3-521; 58/59 (1992) p. 3-469.Google Scholar
2.Kim, J.I., in Handbook on the Physics and Chemistry of the Actinides, edited by Freeman, A.J. and Keller, C. (Elsevier, Amsterdam, 1988) Chap. 8, p. 413.Google Scholar
3.Kim, J.I., in Scientific Basis for Nuclear Waste Management XVI, edited by Interrante, C.G. and Pabalan, R.T. (Mater. Res. Soc. Symp. Proc. 294, Pittsburgh, PA, 1993) p. 3.Google Scholar
4.Kim, J.I., Radiochim. Acta 52/53 (1991) p. 71.CrossRefGoogle Scholar
5.Lutze, W. and Grambow, B., Radiochim. Acta 58/59 (1992) p. 3 and references therein.CrossRefGoogle Scholar
6.Yariv, S. and Cross, H., Geochemistry of Colloid Systems (Springer-Verlag, Berlin, 1979).CrossRefGoogle Scholar
7.McCarthy, J.F. and Degueldre, C., in Environmental Particles, edited by Bufile, J. and van Leenwen, H.P. (Lewis Publishers, Boca Raton, 1993) p. 248.Google Scholar
8.Kim, J.I., Zeh, P., and Delakowitz, B., Radiochimica Acta 58/59 (1992) p. 147.CrossRefGoogle Scholar
9.Kim, J.I., Buckau, G., Baumgärtner, F., Moon, H.C., and Lux, D., in Scientific Basis for Nuclear Waste Management VII, edited by McVay, Gary (Mater. Res. Soc. Symp. Proc. 26, Pittsburgh, PA, 1984) p. 31.Google Scholar
10.Kim, J.I., Delakowitz, B., Zeh, P., Klotz, D., and Lazik, D., Radiochim. Acta, 66/67 (1994) p. 165.CrossRefGoogle Scholar
11.Ahn, T.M., to be published.Google Scholar
12.Ahn, T.M., Interrante, C.G., and Weller, R.A., in Scientific Basis for Nuclear Waste Management XVI, edited by Interrante, C.G. and Pabalan, R.T. (Mater. Res. Soc. Symp. Proc. 294, Pittsburgh, PA, 1993) p. 599.Google Scholar
13.Bates, J.K., Bradley, J.P., Teetrov, A., Bradley, C.R., and Brink, M. Buchholtz ten, Science 256 (1992) p. 649.CrossRefGoogle Scholar
14.Finn, P.A., Buck, E.K., Gong, M., Ho, J.C., Emery, J.W., Hafenrichter, L.D., and Bates, J.K., Radiochim. Acta, in print.Google Scholar
15.Choppin, G.R., Radiochim. Acta 32 (1983) p. 43.CrossRefGoogle Scholar
16.Wadt, W.R., J. Am. Chem. Soc. 103 (1981) p. 6053.CrossRefGoogle Scholar
17.Neck, V., Kim, J.I., and Kanellakopulos, B., Radiochim. Acta 56 (1992) p. 25.CrossRefGoogle Scholar
18.Lloyd, M.H. and Haire, R.G., Radiochim. Acta 25 (1978) p. 139.CrossRefGoogle Scholar
19.Newton, T.W., Hobart, D.E., and Palmer, P.D., Radiochim. Acta 39 (1986) p. 139.CrossRefGoogle Scholar
20.Kim, J.I. and Kanellakopulos, B., Radiochim. Acta 48 (1989) p. 145.CrossRefGoogle Scholar
21.Pashalidis, I., Kim, J.I., Lierse, Ch., and Sullivan, J.C., Radiochim. Acta 61 (1993) p. 29.CrossRefGoogle Scholar
22.Buckau, G., Stumpe, R., and Kim, J.I., J. Less-Common Metals 122 (1986) p. 555.CrossRefGoogle Scholar
23.Clark-Monk, C. and Ellis, B., J. Colloid Interface Sci. 44 (1979) p. 37.CrossRefGoogle Scholar
24.Cloos, P., Leonard, A.J., Moreau, J.P., Habillon, A., and Fripiat, J.J., Clays Clay Miner. 17 (1969) p. 270.CrossRefGoogle Scholar
25.Stumm, W., Environ. Sci. Technol. 11 (1977) p. 1066.CrossRefGoogle Scholar
26.Klenze, R., Kim, J.I., and Wimmer, H., Radiochim. Acta 52/53 (1991) p. 97.CrossRefGoogle Scholar
27.Kim, J.I., Buckau, G., and Zhuang, W., in Scientific Basis for Nuclear Waste Management X, edited by Bates, J.K. and Seefeldt, W.B. (Mater. Res. Soc. Symp. Proc. 84, Pittsburgh, PA, 1987) p. 747.Google Scholar
28.Buckau, G., PhD Thesis, Free University of Berlin, Germany, 1991.Google Scholar
29.Ormsby, W.C., Shartsis, J.M., and Woodside, K.H., J. Am. Ceram. Soc. 45 (1962) p. 361.CrossRefGoogle Scholar
30.Smith, B.H. and Emerson, W.W., Aust. J. Soil Res. 14 (1976) p. 43.CrossRefGoogle Scholar
31.Schnitzer, M. and Kahn, S.U., Humic Substances in the Environment (Marcel Dekker, New York, 1972).Google Scholar
32.Kim, J.I., Buckau, G., Rommel, H., and Sohnius, B., in Scientific Basis for Nuclear Waste Management XII, edited by Lutze, W. and Ewing, R.C. (Mater. Res. Soc. Symp. Proc. 127, Pittsburgh, PA, 1989) p. 849.Google Scholar
33.Degueldre, C.et al., The Grimsel Colloid Exercise, NAGRA Report NTB-90-01 (NAGRA, Wettingen, Switzerland, 1991).Google Scholar
34.Avery, R.G. and Ramsay, J.D.F., J. Colloid Interface Sci. 109 (1986) p. 448.CrossRefGoogle Scholar
35.Stadler, S. and Kim, J.I., Radiochim. Acta 44/45 (1988) p. 39.CrossRefGoogle Scholar
36.Righetto, L., Bidoglio, G., Marcandalli, B., and Bellobono, R., Radiochim. Acta 44/45 (1988), p. 73.CrossRefGoogle Scholar
37.Degueldre, C. and Wernli, B., J. Environ. Radioactivity 20 (1993) p. 151.CrossRefGoogle Scholar
38.Stätmark, B. and Albinsson, Y., Radiochim. Acta 58/59 (1992) p. 155.CrossRefGoogle Scholar
39.Krauskopf, K.B., Geochem. Cosmochim. Acta 10 (1956) p. 1.CrossRefGoogle Scholar
40.Wey, R. and Siffert, B., Colloq. Int. CNRS (France) 105 (1961) p. 11.Google Scholar
41.Helm, J.D. and Roberson, C.E., U.S. Geol. Survey Water-Suppl. Paper 1827-A (1967).Google Scholar
42.Stol, R.J., van Helden, A.K., and de Bruyn, P.L., J. Colloid Interface Sci. 37 (1976) p. 115.CrossRefGoogle Scholar
43.Moon, H.C. and Kim, J.I., to be published.Google Scholar
44.Rhee, D.S., PhD Thesis, Technical University of Munich, Germany, 1992.Google Scholar
45.Kim, J.I., Buckau, G., Bryant, E., and Klenze, R., Radiochim. Acta 48 (1989) p. 135.CrossRefGoogle Scholar
46.Wilson, C.N., PNL Report PNL-7170 (1990).Google Scholar
47.Feng, X., Buck, E.C., Merz, C., Bates, J.K., Cunnane, J.C., and Chaiko, D.J., Radiochim. Acta, in print.Google Scholar
48.Forsyth, R.S. and Werme, L.O., J. Nucl. Mat. 190 (1992) p. 3.CrossRefGoogle Scholar
49.Radioactive Waste Forms for the Future, edited by Lutze, W. and Ewing, R.C. (North Holland, Amsterdam, 1988).Google Scholar
50.Avogadro, A. and Lanza, F., in Scientific Basis for Nuclear Waste Management V, edited by Lutze, W. (Mater. Res. Soc. Symp. Proc. 11, North-Holland, Amsterdam, 1982) p. 103.Google Scholar
51.Saltelli, A., Avogadro, A., and Bidoglio, G., Nucl. Technol. 67 (1984) p. 245.CrossRefGoogle Scholar
52.Rommel, H. and Kim, J.I., in Application of Distribution Coefficients to Radiological Assessment Models, edited by Silbey, T.H. and Myttenare, C. (Elsevier, Amsterdam, 1986) p. 120.Google Scholar
53.Smith, P.A. and Degueldre, C., J. Contaminant Hydrology 13 (1993) p. 143.CrossRefGoogle Scholar
54.Grindrod, P., J. Contaminant Hydrology 13 (1993) p. 167.CrossRefGoogle Scholar
55.Adamczyk, Z. and van der Ven, T.G.M., J. Colloid Interface Sci. 80 (1981) p. 340; 97 (1984) p. 68; 97 (1984) p. 91.CrossRefGoogle Scholar