Hostname: page-component-586b7cd67f-t7czq Total loading time: 0 Render date: 2024-11-26T03:56:32.435Z Has data issue: false hasContentIssue false

Molten Polymers in Strong Flows: A Nonclassical Proposal

Published online by Cambridge University Press:  29 November 2013

Get access

Extract

In spite of its importance for extrusion and molding, the rheology of polymer melts under high shear rates is not fully explained by the classical theory of Doi and Edwards. In this theory, each polymer chain is trapped in a confining “tube.” When the tube is suddenly stretched, the chain follows at first, but it soon shrinks back to its original length (“retraction process”). I propose a different view: Upon stretching, the tube becomes thinner so the chain is squeezed and tends to span a longer length of tube; there is no retraction.

Type
Complex Materials
Copyright
Copyright © Materials Research Society 1991

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1.Doi, M. and Edwards, S., The Theory of Polymer Dynamics (Clarendon Press, 1986).Google Scholar
2.Boue, F., Nierlich, M., Jannik, G., and Bail, R., J. Physique 43 (1982) p. 137148.CrossRefGoogle Scholar
3.Ferry, J.D., Viscoelastic Propcrtics of Polymers (Wiley 1970); W. Stockmayer, in Fluides Molculaires, edited by R. Balian and G. Weil (Gordon and Breach, 1976).Google Scholar
4.Daoud, M. and de Gennes, P.-G., J. Polymer Sci. (Physics) 17 (1979) p. 19711983.CrossRefGoogle Scholar
5.Wyart, F. Brochard, to be published.Google Scholar
6.de Gennes, P.-G., J. Chem. Phys. 55 (1971) p. 572584.CrossRefGoogle Scholar
7.Pincus, P., Macromolecules 9 (1976) p. 386391.CrossRefGoogle Scholar
8.Vinogradov, G.V. and Malkin, A.Y., Rheology of Polymers (Springer, 1980).CrossRefGoogle Scholar