Hostname: page-component-586b7cd67f-r5fsc Total loading time: 0 Render date: 2024-11-26T19:46:20.505Z Has data issue: false hasContentIssue false

Molecular Tribology

Published online by Cambridge University Press:  29 November 2013

Get access

Extract

Molecular tribology—the study of tribology at atomic and molecular scales—constitutes a new frontier of tribology research. In a major surge of activity, experimental methods have recently been developed to measure dynamic interfacial forces in shear. Building partly on earlier, somewhat neglected friction studies, striking new findings have been obtained. The new methods include the surface forces apparatus for measuring adhesion and static interfacial forces as a function of surface separation, new molecular tribometers for measuring friction in shear, atomic force microscopy, use of UHV tribometers, and the quartz-crystal microbalance. Theoretical calculations and molecular dynamics simulations are also emerging for friction in dry and lubricated sliding.

On the scientific side, appreciation is growing that scientific understanding of these systems, so complex and so far from equilibrium, is possible. Tribology is becoming recognized as an area with many exciting and useful surface science opportunities.

The engineering significance is that while tribology design and tribology-based applications are rooted in our economic life, too often the technologies and formulations are empirically derived. One tends to take friction, wear, and tear for granted. A scientific understanding is needed so that better design can emerge by rational extension.

This review seeks to bring out the excitement of new developments. The reader is referred to the original literature for full accounts.

Type
Materials Tribology
Copyright
Copyright © Materials Research Society 1991

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1.Bailey, A.I. and Courtney-Pratt, J.S., Proc. R. Soc. A 227 (1955) p. 500.Google Scholar
2.Israelachvili, J.N. and Tabor, D., Wear 24 (1973) p. 386.CrossRefGoogle Scholar
3.Buckley, D.H., Surface Effects in Adhesion, Friction, Lubrication, and Wear (Elsevier, Amsterdam, 1981).Google Scholar
4.Tabor, D. and Winterton, R.H.S., Proc. R. Soc. A 312 (1969) p. 435.Google Scholar
5.Israelachvili, J.N. and Adams, G.E., J. Chem. Soc. Faraday Trans. II 74 (1978) p. 975.CrossRefGoogle Scholar
6.Israelachvili, J.N., McGuiggan, P.M., and Homola, A. M., Science 240 (1988) p. 189.CrossRefGoogle Scholar
7.Van Alsten, J. and Granick, S., Phys. Rev. Lett. 61 (1988) p. 2570.CrossRefGoogle Scholar
8.Peachey, J., Van Alsten, J., and Granick, S., Rev. Sci. Instrum. 62 (1991) p. 463.CrossRefGoogle Scholar
9.Mate, C.M., McClelland, G.M., Erlandsson, R., and Chiang, S., Phys. Rev. Lett. 59 (1987) p. 1942.CrossRefGoogle Scholar
10.Erlandsson, R., Hadziioannou, G., Mate, C.M., McClelland, G.M., and Chiang, S., J. Chem. Phys. 89 (1988) p. 5190.CrossRefGoogle Scholar
11.Mate, C.M., Lorenz, M.R., and Novotny, V.J., J. Chem. Phys. 90 (1989) p. 7550.CrossRefGoogle Scholar
12.Blackman, G.S., Mate, C.M., and Philpott, C.M., Vacuum, in press.Google Scholar
13.Ogletree, F.D., private communication.Google Scholar
14.Gellman, A.J., unpublished experiments.Google Scholar
15.Watts, E.T., Krim, J., and Widom, A., Phys. Rev. B 41 (1990) p. 3466.CrossRefGoogle Scholar
16.Krim, J., Watts, E.T., and Digel, J., J. Vac. Sci. Technol. A 8 (1990) p. 3417.CrossRefGoogle Scholar
17.Krim, J. and Widom, A., Phys. Rev. B 38 (1988) p. 184.CrossRefGoogle Scholar
18.Krim, J., Solina, D.H., and Chiarello, R., Phys. Rev. Lett. 66 (1991) p. 181.CrossRefGoogle Scholar
19.Landman, U., Luedtke, W.D., and Ribarsky, M.W, J. Vac. Sci. Technol. A 7 (1990) p. 2829.CrossRefGoogle Scholar
20.Landman, U., Luedtke, W.D., Burnham, N.A., and Colton, R.J., Science 248 (1990) p. 454.CrossRefGoogle Scholar
21.Sokoloff, J.B.Phys. Rev. B 42 (1990) p. 760.CrossRefGoogle Scholar
22.Zhong, W. and Tomanek, D., Phys. Rev. Lett. 64 (1990) p. 3054.CrossRefGoogle Scholar
23.Sokoloff, J.B., Phys. Rev. Lett. 66 (1991) p. 965.CrossRefGoogle Scholar
24.Schoen, M., Diestler, D.J., and Cushman, J.H., J. Chem. Phys. 87 (1987) p. 5464.CrossRefGoogle Scholar
25.Schoen, M., Cushman, J.H., Diestler, D.J., and Rhykerd, C.L. Jr., J. Chem. Phys. 88 (1988) p. 1394.CrossRefGoogle Scholar
26.Schoen, M., Rhykerd, C.L. Jr., Diestler, D.J., and Cushman, J.H., Science 245 (1989) p. 1223.CrossRefGoogle Scholar
27.Koplich, J., Banavar, J., and Willemsen, J., Phys. Rev. Lett. 60 (1988) p. 1282.CrossRefGoogle Scholar
28.Thompson, P.A. and Robbins, M.O., Phys. Rev. A 41 (1990) p. 6830.CrossRefGoogle Scholar
29.Thompson, P.A. and Robbins, M.O., Science 250 (1990) p. 792.CrossRefGoogle Scholar
30.Suh, N.P., Tribophysics (Prentice-Hall, Englewood Cliffs, New Jersey, 1986).Google Scholar
31.McClelland, G.M., talk at American Physical Society (Cincinnati, OH, March, 1991); also private communication.Google Scholar
32.Van Alsten, J. and Granick, S., Langmuir 6 (1990) p. 214.CrossRefGoogle Scholar
33.Van Alsten, J. and Granick, S., Macro-molecules 23 (1990) p. 4856.CrossRefGoogle Scholar
34.Van Alsten, J. and Granick, S., Tribology Trans. 33 (1990) p. 436.CrossRefGoogle Scholar
35.Hu, H-W., Carson, G.A., and Granick, S., Phys. Rev. Lett. 66 (1991) p. 2758.CrossRefGoogle Scholar
36.Carson, G.A., Hu, H-W., and Granick, S., Tribology Trans., in press.Google Scholar
37.Granick, S., Science, in press.Google Scholar
38.Gee, M.L., McGuiggan, P.M., Israelachvili, J.N., and Homola, A.M., J. Chem. Phys. 93 (1990) p. 1895.CrossRefGoogle Scholar
39.Homola, A.M., Israelachvili, J.N., Gee, M.L., and McGuiggan, P.M., J. Tribology 111 (1989) p. 675.CrossRefGoogle Scholar
40.McGuiggan, P.M., Israelachvili, J.N., Gee, M.L., and Homola, A.M., in New Approaches to Tribology: Theory and Applications, edited by Pope, L.E., Fehrenbacher, L., and Winer, W.O. (Mater. Res. Soc. Symp. Proc. 140, Pittsburgh, PA, 1989) p. 79.Google Scholar
41.Homola, A.M., Israelachvili, J.N., McGuiggan, P.M., and Gee, M.L., Wear 136 (1990) p. 65.CrossRefGoogle Scholar
42.Alder, B.J. and Wainwright, T.E., Phys. Rev. A 1 (1970) p. 18.CrossRefGoogle Scholar
43.Brockley, C.A. and Davis, H.R.,J. Lubrication Tech. 99 (1968) p. 35.CrossRefGoogle Scholar
44.Dowson, D., History of Tribology (Longman, London, 1979).Google Scholar