Hostname: page-component-cd9895bd7-jkksz Total loading time: 0 Render date: 2024-12-23T23:35:39.888Z Has data issue: false hasContentIssue false
  • English
  • Français

Materials for third-order nonlinear optics

Published online by Cambridge University Press:  08 January 2016

Seth R. Marder
Seth R. Marder*
Affiliation:
Georgia Institute of Technology, USA; [email protected]
Get access

Abstract

This article provides a brief introduction to third-order nonlinear optical materials, including both the real and imaginary components, and is intended to be a personal perspective of the field. It describes applications that can be enabled by molecules with large two-photon absorption (2PA) cross sections and how symmetrical donor–(π-bridge)–donor molecules exhibit large cross sections associated with significant changes in quadrupole moment between the ground- and first-excited electronic states. The application of such materials for 2PA three-dimensional microfabrication is described. The article then turns its focus to materials for all-optical switching applications and explains how cyanine-like molecules can be developed to have both very large real third-order nonlinear coefficients and small 2PA cross sections, both of which are necessary for efficient all-optical switching materials.

Keywords

organicoptical propertiesoptical
Type
Research Article
Information
MRS Bulletin , Volume 41 , Issue 1: Atom Probe Tomography , January 2016 , pp. 53 - 62
Copyright
Copyright © Materials Research Society 2016 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Meyers, F., Marder, S.R., Pierce, B.M., Brédas, J.-L., J. Am. Chem. Soc. 116 (23), 10703 (1994).CrossRefGoogle Scholar
Albota, M., Beljonne, D., Brédas, J.-L., Ehrlich, J.E., Fu, J.-Y., Heikal, A.A., Hess, S.E., Kogej, T., Levin, M.D., Marder, S.R., McCord-Maughon, D., Perry, J.W., Röckel, H., Rumi, M., Subramaniam, G., Webb, W.W., Wu, X.-L., Xu, C., Science 281 (5383), 1653 (1998).CrossRefGoogle Scholar
Cumpston, B.H., Ananthavel, S.P., Barlow, S., Dyer, D.L., Ehrlich, J.E., Erskine, L.L., Heikal, A.A., Kuebler, S.M., Lee, I.-Y.S., McCord-Maughon, D., Qin, J., Röckel, H., Rumi, M., Wu, X.-L., Marder, S.R., Perry, J.W., Nature 398, 51 (1999).CrossRefGoogle Scholar
Rumi, M., Ehrlich, J.E., Heikal, A.A., Perry, J.W., Barlow, S., Hu, Z., McCord-Maughon, D., Parker, T.C., Röckel, H., Thayumanavan, S., Marder, S.R., Beljonne, D., Brédas, J.-L., J. Am. Chem. Soc. 122, 9500 (2000).CrossRefGoogle Scholar
Zhou, W., Kuebler, S.M., Braun, K.L., Yu, T., Cammack, J.K., Ober, C.K., Perry, J.W., Marder, S.R., Science 296, 1106 (2002).CrossRefGoogle Scholar
Hales, J.M., Zheng, S., Barlow, S., Marder, S.R., Perry, J.W., J. Am. Chem. Soc. 128 (35), 11362 (2006).CrossRefGoogle Scholar
Chung, S.-J., Zheng, S., Odani, T., Beverina, L., Fu, J., Padilha, L.A., Biesso, A., Hales, J.M., Zhan, X., Schmidt, K., Ye, A., Zojer, E., Barlow, S., Hagan, D.J., Van Stryland, E.W., Yi, Y., Shuai, Z., Pagani, G.A., Brédas, J.-L., Perry, J.W., Marder, S.R., J. Am. Chem. Soc. 128 (45), 14444 (2006).CrossRefGoogle Scholar
Marder, S.R., Brédas, J.-L., Perry, J.W., MRS Bull. 32 (7), 561 (2007).CrossRefGoogle Scholar
Haske, W., Chen, V.W., Hales, J.M., Dong, W., Barlow, S., Marder, S.R., Perry, J.W., Opt. Express 15 (6), 3426 (2007).CrossRefGoogle Scholar
Hales, J.M., Matichak, J., Barlow, S., Ohira, S., Yesudas, K., Brédas, J.-L., Perry, J.W., Marder, S.R., Science 327 (5972), 1485 (2010).CrossRefGoogle Scholar
Gieseking, R.L., Mukhopadhyay, S., Risko, C., Marder, S.R., Brédas, J.-L., Adv. Mater. 26, 68 (2014).CrossRefGoogle Scholar
Shahin, S., Kieu, K., Hales, J.M., Kim, H., Getmanenko, Y.A., Zhang, Y., Perry, J.W., Marder, S.R., Norwood, R.A., Peyghambarian, N., J. Opt. Soc. Am. B. 31, 2455 (2014).CrossRefGoogle Scholar
Barlow, S., Brédas, J.-L., Getmanenko, Y.A., Gieseking, R.L., Hales, J.M., Kim, H., Marder, S.R., Perry, J.W., Risko, C., Zhang, Y., Mater. Horiz. 1, 577 (2014).CrossRefGoogle Scholar
Li, Z.A., Ensley, T.R., Hu, H., Zhang, Y., Jang, S.-H., Marder, S.R., Hagan, D.J., Van Stryland, E.W., Jen, A.K.-Y., Adv. Opt. Mater. 3, 900 (2015).CrossRefGoogle Scholar
Hales, J.M., Barlow, S., Kim, H., Mukhopadhyay, S., Brédas, J.-L., Perry, J.W., Marder, S.R., Chem. Mater. 26, 549 (2014).CrossRefGoogle Scholar
Gorman, C.B., Marder, S.R., Proc. Natl. Acad. Sci. U.S.A. 90 (23), (1993) p. 11297.CrossRefGoogle Scholar
Mach, L., Z. Instrumentkd. 12, 89 (1892).Google Scholar
Zehnder, L., Z. Instrumentkd. 11, 275 (1891).Google Scholar