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Critical Fluids in Porous Media

Published online by Cambridge University Press:  29 November 2013

B.J. Frisken ,
Andrea J. Liu  and
David S. Cannell
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The behavior of fluids confined in porous materials has been of interest to engineers and scientists for many decades. Among the applications driving this research are the use of porous membranes to achieve liquid-liquid separations and to deionize water, the use of porous materials as beds for catalysis, and the need to extract liquids (especially oil and water) from such media. Many of these applications depend on transport, which is governed by flow or diffusion in the imbibed fluids. Both the flow and diffusion of multiphase fluids in porous media, however, strongly depend on the morphology of phase-separated domains, and on the kinetics of domain growth. Thus, it is worthwhile to study the behavior of multiphase fluids in porous media in the absence of flow. Recently, much attention has focused on even simpler systems that still capture these essential features, namely, near-critical binary liquid mixtures and vapor-liquid systems in model porous media, such as Vycor and dilute silica gels. Although near-critical fluids may seem rather artificial as models for multiphase liquids, there are several advantages associated with them. In general, domain morphology and growth kinetics are governed primarily by competition between interfacial tension and the preferential attraction of one phase to the surface of the medium. In near-critical fluids, the relative strength of these two energy scales is sensitive to temperature, and can therefore be altered in a controlled fashion. In addition, the kinetics of domain growth are sensitive to the temperature quench depth, and can be controlled.

Type
Mesoscopic Disorder
Information
MRS Bulletin , Volume 19 , Issue 5 , May 1994 , pp. 19 - 24
Copyright
Copyright © Materials Research Society 1994

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References

1. See, for example, Zeolites: Facts, Figures, Future; Studies in Surface Science and Catalysis, Vol. 49, edited by Jacobs, P.A. and van Santen, R.A. (Elsevier, New York, 1989).Google Scholar
2.Goh, M.C., Goldburg, W.I., and Knobler, C.M., Phys. Rev. Lett. 58 (1987), p. 1008.Google Scholar
3.Dierker, S.B. and Wiltzius, P., Phys Rev. Lett. 58 (1987) p. 1865; Wilzius, P., Dierker, S.B., and Dennis, B.S., Phys Rev. Lett. 62 (1989), p. 804.CrossRefGoogle Scholar
4.Dierker, S.B. and Wiltzius, P., Phys. Rev. Lett. 66 (1991) p. 1185.CrossRefGoogle Scholar
5.Aliev, F., Goldburg, W.I., and Wu, X-l., Phys. Rev. E 47 (1993) p. 3834.CrossRefGoogle Scholar
6.Lin, M.Y., Sinha, S.K., Drake, J.M., Wu, X-L., Thiyagarajan, P., and Stanley, H.B., preprint.Google Scholar
7.Wong, A.P.Y. and Chan, M.H.W., Phys. Rev. Lett. 65 (1990) p. 2567.CrossRefGoogle Scholar
8.Frisken, B.J., Ferri, F., and Cannell, D.S., Phys. Rev. Lett. 66 (1991) p. 2754.CrossRefGoogle Scholar
9.Frisken, B.J. and Cannell, D.S., Phys. Rev. Lett. 69 (1992) p. 632.CrossRefGoogle Scholar
10.Wong, A.PY., Kim, S.B., Ma, J., Goldburg, W.I., and Chan, M.H.W., Phys. Rev. Lett. 70 (1993) p. 954.CrossRefGoogle Scholar
11.Frisken, B.J., Cannell, D.S., Lin, M.Y., and Sinha, S.K., unpublished.Google Scholar
12.Fisher, M.E., in Critical Phenomena, edited by Hahne, F.J.W. (Springer Verlag, New York, 1983).Google Scholar
13.Levitz, P. and Drake, J.M., Phys. Rev. Lett. 58 (1987) p. 686; Levitz, P., Ehret, G., Sinha, S.K., and Drake, J.M., J. Chem. Phys. 95 (1991) p. 6151.CrossRefGoogle Scholar
14.Goldburg, W.I., in Physics of Complex and Supramolecular Fluids, edited by Safran, S.A. and Clark, N.A. (Wiley & Sons, New York, 1987) p. 475.Google Scholar
15.Ferri, F., Frisken, B.J., and Cannell, D.S., Phys. Rev. Lett. 67 (1991) p. 3626.CrossRefGoogle Scholar
16.Liu, A.J. and Fisher, M.E., Phys. Rev. A 40 (1989) p. 7202.CrossRefGoogle Scholar
17. See, e.g., Evans, R., Marconi, U.M.B., and Tarazona, P., J. Chem. Phys. 84 (1986) p. 2376; Peterson, B.K., Gubbins, K.E., Heffelfinger, G.S., Marconi, U.M.B., and Swol, F. van, J. Chem. Phys. 88 (1988) p. 6487 and references therein.CrossRefGoogle Scholar
18.Cole, M.W. and Saam, W.F., Phys. Rev. Lett. 32 (1974) p. 985; Phys. Rev. B 11 (1975) p. 1086.CrossRefGoogle Scholar
19. See, e.g., Gregg, S.J. and Sing, K.S.W., Adsorption, Surface Area and Porosity (Academic Press, New York, 1967).CrossRefGoogle Scholar
20.Awschalom, D.D., Warnock, J., and Shafer, M.W., Phys. Rev. Lett. 57 (1986) p. 1607.CrossRefGoogle Scholar
21.Page, J.H., Liu, J., Abeles, B., Deckman, H.W., and Weitz, D.A., Phys. Rev. Lett. 71 (1993) p. 1216.CrossRefGoogle Scholar
22.Liu, A.J., Durian, D.J., Herbolzheimer, E., and Safran, S.A., Phys. Rev. Lett. 65 (1990) p. 1897.CrossRefGoogle Scholar
23.Huse, D.A., Phys. Rev. B 36 (1987) p. 5383.CrossRefGoogle Scholar
24.Brochard, F. and de Gennes, P-G., J. Phys. Lett. (Paris) 44 (1983) p. 785.CrossRefGoogle Scholar
25.de Gennes, P-G., J. Phys. Chem. 88 (1984) p. 6469.CrossRefGoogle Scholar
26.Andelman, D. and Joanny, J-F., in Scaling Phenomena in Disordered Systems, edited by Pynn, R. and Skjeltorp, A. (Plenum, New York, 1985).Google Scholar
27.Maritan, A., Swift, M.R., Cieplak, M., Chan, M.H.W., Cole, M.W., and Banavar, J.R., Phys. Rev. Lett. 67 (1991) p. 1821.CrossRefGoogle Scholar
28.Mezard, M. and Young, A.P., Europhys. Lett. 18 (1992) p. 653; Guagnelli, M., Marinari, E., and Parisi, G., J. Phys. A. 26 (1993) p. 5675.CrossRefGoogle Scholar
29.Liu, A.J. and Grest, G.S., Phys. Rev. A 44 (1991) p. 7879; Monette, L., Liu, A.J., and Grest, G.S., Phys. Rev. A 46 (1992) p. 7664.Google Scholar
30.Chakrabarti, A., Phys. Rev. Lett. 69 (1992) p. 1548.CrossRefGoogle Scholar
31.Tanaka, H., Phys. Rev. Lett. 70 (1992) p. 53.CrossRefGoogle Scholar
32.Rao, M. and Chakrabarti, A., Phys. Rev. E 48 (1993) p. 25.Google Scholar
33.Grunau, D.W., Lookman, T., Chen, S.Y., and Lapedes, A.S., Phys. Rev. Lett. 71 (1993) p. 4198.CrossRefGoogle Scholar
34.Lee, J.C., Phys. Rev. B 46 (1992) p. 8648.CrossRefGoogle Scholar
35.Lee, J.C., Phys. Rev. Lett. 70 (1993) p. 3599.CrossRefGoogle Scholar
36.Lee, J.C., preprint.Google Scholar
37.Madden, W.G. and Glandt, E.D., J. Stat. Phys. 51 (1988) p. 537; Madden, W.G., J. Chem. Phys. 96 (1992) p. 5422.CrossRefGoogle Scholar
38.Rosinberg, M.L., Tarjus, G., and Stell, G., preprint, and references therein.Google Scholar