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Complex Oxide Materials for Potential Thermoelectric Applications

Published online by Cambridge University Press:  31 January 2011

Kunihito Koumoto ,
Ichiro Terasaki  and
Ryoji Funahashi
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Abstract

Layered CoO2 materials are excellent candidates for potential thermoelectric applications. Their single crystals show good p-type thermoelectric properties at temperatures higher than 800K in air.Recently, the mechanism of thermoelectric properties was clarified through a discussion of electronic and crystallographic structure. In order to fabricate thermoelectric modules possessing good power-generation properties, thermoelectric materials and metallic electrodes must be connected with low contact resistance and high mechanical strength.It has been found that good junctions can be formed using Ag paste including p- and n-type oxide powders.The role of spin entropy contributions to thermopower will be presented, in connection with strong electron correlation and triangular lattices.

Keywords

oxidethermal conductivitythermoelectricity
Type
Research Article
Information
MRS Bulletin , Volume 31 , Issue 3: Harvesting Energy through Thermoelectrics: Power Generation and Cooling , March 2006 , pp. 206 - 210
Copyright
Copyright © Materials Research Society 2006

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