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Synthesis of Polymeric Nancocomposites by Infiltration. Applications in 3D (Fused Filament Molding) Printing

Published online by Cambridge University Press:  20 November 2018

Kevin Riberi
Affiliation:
Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados (IITEMA), Universidad Nacional de Río Cuarto-CONICET. Enlace Rutas 8 y 36, km 601 (5800), Río Cuarto, Argentina
Jesica Yanina Pereyra
Affiliation:
Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados (IITEMA), Universidad Nacional de Río Cuarto-CONICET. Enlace Rutas 8 y 36, km 601 (5800), Río Cuarto, Argentina
Gabriel A. Planes
Affiliation:
Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados (IITEMA), Universidad Nacional de Río Cuarto-CONICET. Enlace Rutas 8 y 36, km 601 (5800), Río Cuarto, Argentina
Silvestre Bongiovanni Abel
Affiliation:
Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados (IITEMA), Universidad Nacional de Río Cuarto-CONICET. Enlace Rutas 8 y 36, km 601 (5800), Río Cuarto, Argentina
Diego F. Acevedo
Affiliation:
Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados (IITEMA), Universidad Nacional de Río Cuarto-CONICET. Enlace Rutas 8 y 36, km 601 (5800), Río Cuarto, Argentina
Cesar Alfredo Barbero*
Affiliation:
Instituto de Investigaciones en Tecnologías Energéticas y Materiales Avanzados (IITEMA), Universidad Nacional de Río Cuarto-CONICET. Enlace Rutas 8 y 36, km 601 (5800), Río Cuarto, Argentina
*
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Abstract

The generation of filaments constituted by nanocomposites allows printing pieces with functional properties. A method is proposed for incorporating nanoparticles in plastic filaments (thermoplastic polyurethane, PU) by diffusion in the swollen material. The nanoparticles must be dispersed in solvents (or solvent mixtures) in which the polymer swells but does not dissolve. Nanoparticles are incorporated mainly at the surface as revealed by SEM/EDS mapping. The thermal properties (studied by DSC and TGA) of the PU are only slightly affected by the presence of NPs. Test pieces successfully are printed using the modified filaments. Incorporation of solid lubricant (MoS2) nanoparticles decreases the coefficient of friction of the printed test samples.

Type
Articles
Copyright
Copyright © Materials Research Society 2018 

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References

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