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Synthesis, Characterization of Elastic and Electrical Properties of Diamond-like BCx Nano-Phases Synthesized under High and Low Pressures

Published online by Cambridge University Press:  09 January 2018

Pavel V. Zinin ,
Alla V. Nozhkina ,
Roman I. Romanov ,
Vladimir P. Filonenko ,
Sergey A. Titov ,
Ivan Trojan ,
Vyacheslav. Y. Fominski ,
Kamil M. Bulatov ,
Aleksey A. Bykov  and
Igor B. Kutuza
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Pavel V. Zinin*
Affiliation:
Scientific and Technological Center of Unique Instrumentation, Russian Academy of Sciences, Moscow, Russia Hawaii Institute of Geophysics and Planetology, University of Hawaii, Honolulu, HI, USA
Alla V. Nozhkina
Affiliation:
National University of Science and Technology MISiS, Moscow, Russia
Roman I. Romanov
Affiliation:
National Research Nuclear University MEPhI (Moscow Engineering Physics Institute), Moscow, Russia
Vladimir P. Filonenko
Affiliation:
Institute for High Pressure Physics, Russian Academy of Sciences, Troitsk, Russia
Sergey A. Titov
Affiliation:
Scientific and Technological Center of Unique Instrumentation, Russian Academy of Sciences, Moscow, Russia
Ivan Trojan
Affiliation:
Shubnikov Institute of Crystallography, FSRC Crystallography and Photonics, Russian Academy of Sciences, Moscow, Russia
Vyacheslav. Y. Fominski
Affiliation:
National Research Nuclear University MEPhI (Moscow Engineering Physics Institute), Moscow, Russia
Kamil M. Bulatov
Affiliation:
Scientific and Technological Center of Unique Instrumentation, Russian Academy of Sciences, Moscow, Russia
Aleksey A. Bykov
Affiliation:
Scientific and Technological Center of Unique Instrumentation, Russian Academy of Sciences, Moscow, Russia
Igor B. Kutuza
Affiliation:
Scientific and Technological Center of Unique Instrumentation, Russian Academy of Sciences, Moscow, Russia
Alexander Anokhin
Affiliation:
Institute for High Pressure Physics, Russian Academy of Sciences, Troitsk, Russia
Aleksey M. Lomonosov
Affiliation:
Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow, Russia
*
*(Email: [email protected])
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Abstract

This paper presents experimental results on the synthesis of boron rich diamond-like carbon phases (BCx) obtained by high pressure sintering (s-BCx) and pulsed laser deposition (PLD-BCx). It has been shown that sintering of a mixture of a powder of micro-diamonds with a powder of boron in the toroid type high pressure device leads to the creation of s-BCx phase with a low resistivity, and high elastic moduli. The PLD-BCx film found to be rigid with the resistivity as low as that of best conductive boron–doped diamond films. It indicates that the presence of B atoms in a laser plasma leads to the formation of sp3 bonds in the material in the process of chemical sputtering. The combination of unique characteristics can be achieved by changing the ratio B/C.

Keywords

elastic propertiessuperconductingelectrical properties
Type
Articles
Information
MRS Advances , Volume 3 , Issue 1-2: Nanomaterials , 2018 , pp. 45 - 52
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Copyright
Copyright © Materials Research Society 2018 

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References

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