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Synthesis and Characterization of Ionene-Polyamide Materials as Candidates for New Gas Separation Membranes

Published online by Cambridge University Press:  06 June 2018

Jason E. Bara Open the ORCID record for Jason E. Bara [Opens in a new window] ,
Kathryn E. O’Harra ,
Marlow M. Durbin ,
Grayson P. Dennis ,
Enrique M. Jackson ,
Brian Thomas  and
Jamiu A. Odutola
Jason E. Bara*
Affiliation:
University of Alabama, Department of Chemical & Biological Engineering, Tuscaloosa, AL35487-0203USA
Kathryn E. O’Harra
Affiliation:
University of Alabama, Department of Chemical & Biological Engineering, Tuscaloosa, AL35487-0203USA
Marlow M. Durbin
Affiliation:
University of Alabama, Department of Chemical & Biological Engineering, Tuscaloosa, AL35487-0203USA
Grayson P. Dennis
Affiliation:
University of Alabama, Department of Chemical & Biological Engineering, Tuscaloosa, AL35487-0203USA
Enrique M. Jackson
Affiliation:
NASA Marshall Space Flight Center, Huntsville, AL35812
Brian Thomas
Affiliation:
Alabama A&M University, Department of Chemistry, Normal, AL35762:
Jamiu A. Odutola
Affiliation:
Alabama A&M University, Department of Chemistry, Normal, AL35762:
*
*(Email: [email protected])
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Abstract

A new family of six ionenes containing aromatic amide linkages has been synthesized from ready available starting materials at scales up to ∼50 g. These ionene-polyamides are all constitutional isomers and vary only in the regiochemistry of the amide linkages (para, meta) and xylyl linkages (ortho, meta, para) which are present in the polymer backbone. This paper details the synthesis of these ionenes and associated characterizations. Ionene-polyamides exhibit relatively low melting points (∼150 oC) allowing them to be readily processed into films and other objects. These ionene-polyamide materials are being developed for further study as polymer membranes for the separations of gases such as CO2, N2, CH4 and H2.

Keywords

polymermembranesyntheticsupramolecularorganic
Type
Articles
Information
MRS Advances , Volume 3 , Issue 52: Energy Materials and Technologies , 2018 , pp. 3091 - 3102
Copyright
Copyright © Materials Research Society 2018 

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