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Synthesis and characterization of CeO2 nanoparticles on porous carbon for Li-ion battery

Published online by Cambridge University Press:  21 June 2017

Hoejin Kim ,
Mohammad Arif Ishtiaque Shuvo ,
Hasanul Karim ,
Juan C. Noveron ,
Tzu-liang Tseng  and
Yirong Lin
Hoejin Kim*
Affiliation:
Department of Mechanical Engineering, University of Texas at El Paso, El Paso, TX 79968, USA.
Mohammad Arif Ishtiaque Shuvo
Affiliation:
Department of Mechanical Engineering, University of Texas at El Paso, El Paso, TX 79968, USA.
Hasanul Karim
Affiliation:
Department of Mechanical Engineering, University of Texas at El Paso, El Paso, TX 79968, USA.
Juan C. Noveron
Affiliation:
Department of Chemistry, University of Texas at El Paso, El Paso, TX 79968, USA.
Tzu-liang Tseng
Affiliation:
Department of Industrial, Systems, and Manufacturing, University of Texas at El Paso, El Paso, TX 79968, USA.
Yirong Lin
Affiliation:
Department of Mechanical Engineering, University of Texas at El Paso, El Paso, TX 79968, USA.
*
*(Email: [email protected])

Abstract

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Carbon based materials have long been investigated as anodes for lithium ion batteries. Among these materials, porous carbon holds several advantages such as high stability, high specific surface area, and excellent cycling capability. To further enhance the energy storage performance, ceramic nanomaterials have been combined with carbon based materials as hybrid anodes for enhanced specific capacity. The use of metal oxide ceramic nanomaterials could enhance the surface electrochemical reactivity thus leads to the increasing of capacity retention at higher number of cycles. In this research, we synthesized ceria (CeO2) nano-particles on porous carbon to form inorganic-organic hybrid composites as an anode material for Li-ion battery. The high redox potential of ceria is expected to increase the specific capacity and energy density of the system. The electrochemical performance was determined by a battery analyzer. It is observed that the specific capacity could be improved by 77% using hybrid composites anode. The material morphology, crystal structure, and thermal stability were characterized by Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), X-Ray Diffraction (XRD), and Thermogravimetric Analysis (TGA).

Keywords

chemical synthesisnanostructureenergy storage
Type
Articles
Information
MRS Advances , Volume 2 , Issue 54: Energy Storage and Conversion , 2017 , pp. 3299 - 3307
Copyright
Copyright © Materials Research Society 2017 

References

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