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Surface Electrolyte Interphase Control on Magnetite, Fe3O4, Electrodes: Impact on Electrochemistry

Published online by Cambridge University Press:  16 March 2018

Lisa M. Housel ,
Alyson Abraham ,
Genesis D. Renderos ,
Kenneth J. Takeuchi ,
Esther S. Takeuchi  and
Amy C. Marschilok
Lisa M. Housel
Affiliation:
Department of Chemistry, Stony Brook University, Stony Brook, NY11794
Alyson Abraham
Affiliation:
Department of Chemistry, Stony Brook University, Stony Brook, NY11794
Genesis D. Renderos
Affiliation:
Department of Chemistry, Stony Brook University, Stony Brook, NY11794
Kenneth J. Takeuchi
Affiliation:
Department of Chemistry, Stony Brook University, Stony Brook, NY11794 Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, NY11794
Esther S. Takeuchi
Affiliation:
Department of Chemistry, Stony Brook University, Stony Brook, NY11794 Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, NY11794 Energy Sciences Directorate, Brookhaven National Laboratory, Upton NY11973
Amy C. Marschilok*
Affiliation:
Department of Chemistry, Stony Brook University, Stony Brook, NY11794 Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, NY11794 Energy Sciences Directorate, Brookhaven National Laboratory, Upton NY11973
*
*corresponding author: [email protected].
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Abstract

In battery systems, a solid electrolyte interphase (SEI) is formed through electrolyte reaction on an electrode surface. The formation of SEI can have both positive and negative effects on electrochemistry. The initial formation of the layer protects the electrode from further reactivity, which can improve both shelf and cycle life. However, if the layer continues to form, it can impede charge transfer, which increases cell resistance and limits cycle life. The role of SEI is particularly important when studying conversion electrodes, since phase transformations which unveil new electroactive surfaces during reduction/oxidation can facilitate electrolyte decomposition. This manuscript highlights recent developments in the understanding and control of SEI formation for magnetite (Fe3O4) conversion electrodes through electrolyte and electrode modification.

Keywords

Feenergy storageLi
Type
Articles
Information
MRS Advances , Volume 3 , Issue 11: Theory, Characterization and Modeling , 2018 , pp. 581 - 586
Copyright
Copyright © Materials Research Society 2018 

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Footnotes

ŧ

Equivalent contributions.

References

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