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Structural and Magnetic Properties of Well-Ordered Inverted Core-Shell α-Cr2O3/ α-MxCr2-xO3 (M=Co, Ni, Mn, Fe) Nanoparticles

Published online by Cambridge University Press:  12 May 2016

M.D. Hossain ,
S. Dey ,
R. A. Mayanovic  and
M. Benamara
M.D. Hossain*
Affiliation:
Department of Physics, Astronomy, and Materials Science, Missouri State University, 901 South National Avenue, Springfield, MO 65897, USA
S. Dey
Affiliation:
Department of Physics, Astronomy, and Materials Science, Missouri State University, 901 South National Avenue, Springfield, MO 65897, USA
R. A. Mayanovic
Affiliation:
Department of Physics, Astronomy, and Materials Science, Missouri State University, 901 South National Avenue, Springfield, MO 65897, USA
M. Benamara
Affiliation:
Institute for Nanoscience and Engineering, University of Arkansas, Fayeteville, AR 72701, USA
*
† (Email: [email protected])
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Abstract

Magnetic core shell nanoparticles (NPs) have potential for applications in magnetic random access memory, spintronic devices, and drug delivery systems. Our investigations are focused on the synthesis of inverted core shell nanoparticles and characterization of their structural and magnetic properties. By using our hydrothermal nanophase epitaxy technique, we are able to synthesize well-ordered α-Cr2O3@α-MxCr2-xO3 (M = Co, Ni, Mn, Fe) inverted core-shell nanoparticles. This typically results in the formation of novel phases of MxCr2-xO3 shells having ferromagnetic/ferrimagnetic (FM/FiM) spin ordering and an antiferromagnetic (AFM) Cr2O3 core structure. The combined results from XRD and high-resolution TEM (HRTEM) provide evidence of the presence of corundum phase both in the shell and in the core regions. HRTEM results also show a sharp interface exhibiting epitaxial atomic registry of shell atoms over highly ordered core atoms whereas TEM-EDX analyses show that the M atoms reside predominantly in the shell regions. The XPS analyses of the NPs indicate the M transition metals incorporated in the shell are in the +2 oxidation state. Magnetic measurements show well developed hysteresis loops: The field cooled hysteresis loops reveal horizontal shifts in the applied field axis and vertical shifts in the magnetization axis, relative to the zero-field cooled hysteresis loops. This provides direct evidence for the exchange bias effect between the AFM α-Cr2O3 core and the FM/FiM α-MxCr2-xO3 shell. The XPS data are consistent with oxygen vacancy formation in order to maintain charge neutrality upon substitution of the M2+ ion for the Cr3+ ion in the α-MxCr2-xO3 shell. The FM/FiM ordering in the shell may at least partially result from the F-center exchange coupling between the oxygen-vacancy induced bound magnetic polaron and nearby cations.

Keywords

core/shellmagnetic propertiesnanostructure
Type
Articles
Information
MRS Advances , Volume 1 , Issue 34: Materials Design , 2016 , pp. 2387 - 2392
Copyright
Copyright © Materials Research Society 2016 

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References

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