Hostname: page-component-586b7cd67f-gb8f7 Total loading time: 0 Render date: 2024-11-26T00:52:48.234Z Has data issue: false hasContentIssue false
  • English
  • Français

New 1212-Molybdo-Cuprate phases using High pressure and high temperature synthesis

Published online by Cambridge University Press:  19 February 2016

Sourav Marik ,
A. J. Dos santos-Garcia ,
Emilio Morán ,
O. Toulemonde  and
M. A. Alario-Franco
Sourav Marik
Affiliation:
Dpto. Química Inorgánica, Facultad de CC.Químicas, Universidad Complutense de Madrid, 28040-Madrid (Spain) CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr. A. Schweitzer, Pessac, F-33608, France
A. J. Dos santos-Garcia
Affiliation:
Dpto. Química Inorgánica, Facultad de CC.Químicas, Universidad Complutense de Madrid, 28040-Madrid (Spain) Dpto. Química Industrial y Polímeros, E. U. I. T. I, Universidad Politécnica de Madrid, 28012, Madrid (Spain)
Emilio Morán
Affiliation:
Dpto. Química Inorgánica, Facultad de CC.Químicas, Universidad Complutense de Madrid, 28040-Madrid (Spain)
O. Toulemonde
Affiliation:
CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr. A. Schweitzer, Pessac, F-33608, France
M. A. Alario-Franco*
Affiliation:
Dpto. Química Inorgánica, Facultad de CC.Químicas, Universidad Complutense de Madrid, 28040-Madrid (Spain)
*
*E mail:[email protected]
Get access

Abstract

New 1212- type Molybdo-Cuprates of with composition Mo0.5Cu0.5Sr2RECu2O7.5 (RE = Rare Earth) have been prepared by High Pressure and High Temperature (HPHT) synthesis. Their crystal structures are characterized by combining the X-Ray/Neutron powder diffraction and electron diffraction techniques. All the materials show tetragonal symmetry, crystallizing in the P4/mmm space group (S.G.). The chain oxygens are randomly distributed in the two different oxygen sites, which are not completely filled and the defect induced by oxygen vacancies in fact makes the chain fragmented and disordered. The microstructure of these compounds is interpreted by a well-known diagonal cell √2ap × √2ap × 3ap, as confirmed by the Electron diffraction (ED) and transmission electron microscope (TEM). X-ray photoelectron spectroscopy (XPS) studies show the predominance of the non magnetic MoVI state over the MoV one. At the same time oxidation state of copper is found to be dominated by CuII.

Keywords

magnetic propertiesoxidesuperconducting
Type
Articles
Information
MRS Advances , Volume 1 , Issue 17: Mechanical Behaviour and Failure of Materials , 2016 , pp. 1215 - 1225
Copyright
Copyright © Materials Research Society 2016 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Tokura, Y., Takagi, H. and Uchida, S. Nature 1989, 337, 345. See also: Alario-Franco, M. A. Adv. Mater. 1994, 7(2), 229.Google Scholar
Joshi, D. G., Subbrarao, M. V., Shah, A. N., Kuberkar, D. G. and Kulkarni, R.G. Applied superconductivity 1998 6, 7-9, pp. 471–481.CrossRefGoogle Scholar
Bauernfeind, L., Widder, W. and Braun, H. F. Physica C 1995, 254, 151–158.Google Scholar
J. Lynn, W., Keimer, B., Ulrich, C., Bernhard, C., and Tallon, J. L. Phys Rev. B. 2000, 61, R14964.CrossRefGoogle Scholar
Felner, I., Asaf, U., Reich, S. and Tsabba, Y. Physica C 1999, 311, 163.CrossRefGoogle Scholar
Pringle, J. D., Tallon, J. L., Walker, B. G. and Trodahl, H. J. Phys Rev. B. 1999, 59, R11679.Google Scholar
Rukang, L., Yingjie, Z., Daoyuang, Z., Chen, X., Yitai, Q., Zuyao, C. and Guien, Z. J. Alloy Compd. 1992, 185, 45.Google Scholar
Mclaughlin, A. C., Morrice, D. and Sher, F. J. Solid State Chem. 2005, 178, 2274.Google Scholar
Adachi, S., Kubo, K –I., Takano, S. and Yamauchi, H. Physica C 1992, 191, 174.CrossRefGoogle Scholar
Eder, M. H. and Gritzner, G. Supercond. Sci. Technol. 2005, 18, 87.CrossRefGoogle Scholar
Dos santos-Garcia, A. J., Aguirre, M. H., Saez Puche, R. and Alario-Franco, M. A. J. Solid State Chem. 2006, 179, 1296.Google Scholar
Dos santos-Garcia, A. J., Van Duijn, J. and Alario-Franco, M. A. J. Solid State Chem. 2008, 181, 3317–3321.Google Scholar
Takayama-Muromachi, E. Chem. Mater. 1998, 10, 2686.CrossRefGoogle Scholar
Ruiz-Bustos, R., Gallardo-Amores, J. M., Saez-Puche, R.; Moran, E. and Alario-Franco, M. A. Physica C 2002, 382, 395–400.CrossRefGoogle Scholar
Ruiz-Bustos, R., Aguirre, M. H. and Alario-Franco, M. A. Inorg. Chem. 2005, 44, 3063–3069.Google Scholar
Alario-Franco, M. A., Ruiz-Bustos, R. and Dos santos-Garcia, A. J. Inorg. Chem. 2008, 47, 6475–6481.Google Scholar
Felner, I. and Galstyan, E. Phys. Rev. B 2004, 69, 024512.CrossRefGoogle Scholar
Balchev, N., Nenkov, K., Mihova, G., Kunev, B., Pirov, J. and Dimitrov, D. A. JMMM 2009, 321, 388–391.Google Scholar
Marik, S., Moran, E., Labrugere, C., Toulemonde, O. and Alario-Franco, M. A. J. Solid State Chem. 2012, 191, 40–45.Google Scholar
Marik, S., Dos santos-Garcia, A. J., Moran, E., Labrugere, C., Toulemonde, O. and Alario-Franco, M. A. Supercond. Science and technology 2015, 28, 045007.CrossRefGoogle Scholar
Marik, S., Moran, E., Dos santos-Garcia, A. J., Toulemonde, O. and Alario-Franco, M. A. JPCM. 2013, 25, 165704.Google Scholar
Marik, S., Moran, E., Dos santos-Garcia, A. J., Toulemonde, O. and Alario-Franco, M. A. J Supercond Nov Magn 2013, 26, 1151–1154.CrossRefGoogle Scholar
Tsay, H. L., Shih, C. R., Chen, Y. C., Lee, W. H., Meen, T. H. and Yang, H. D. Physica C 1995, 252, 79–86.Google Scholar
Tsay, H. L., Chen, Y. C., Weng, S. S., Chang, C. F. and Yang, H. D. Phys. Rev. B 1999 -I, 59, 636–640.CrossRefGoogle Scholar
Rodriguez-Carvajal, JAn introduction to the programme FULL-PROF, 2001, Labratoire Leon Brillouin, CEA-CNRS: Saclay, France.Google Scholar
William, T. A., Harrison, S. R., Vaughey, J. T., Liu, L. and Jacobson, A. J. J. Solid State Chem. 1995, 119, 115–119.Google Scholar
Antipov, E. V., Abukamov, A. M. and Putilin, S. N. Supercond. Sci.Technol. 2002, 15, R31–R49.Google Scholar
Putilin, S. N., Antipov, E. V., Chmaissem, O. and Marezio, M. Nature (London) 1993, 362, 226.CrossRefGoogle Scholar
Balagurov, A. M., Sheptyakov, D. V., Aksenov, V. L., Antipov, E. V., Putilin, S. N., Radaelli, P. G. and Marezio, M. Phys. ReV. B: Solid State 1999, 59(10) 7209.Google Scholar
Shannon, R. D. Acta Crystallogr. 1976, A 32, 751.Google Scholar
Poole, C., Creswick, R. C. and Farach, H. Handbook of Superconductivity; Elsevier: Amsterdam, 1999, p 136.Google Scholar
Vegas, A., Vallet-Regi, M., Gonzalez-Calbet, J. and Alario-Franco, M. A. Acta Crystallogr. 1986, B42, 167.Google Scholar
Alario- Franco, M. A., Vallet-Regi, M. and Gonzalez-Calbet, J. Cryst. Lattice Defects Amorphous Mater. 1987, 16, 387.Google Scholar
Alario- Franco, M. A., Joubert, J. C. and Levi, J. P. Mater. Res. Bull. 1982, 21, 733.Google Scholar
Alario-Franco, M. A., Henche, M. J. R., Vallet, M., Calbet, J. M., Grenier, J. C., Wattiaux, A. and Hagenmuller, P. J. Solid State Chem. 1983, 46, 23–40.CrossRefGoogle Scholar
Aguirre, M., Ruiz-Bustos, R. and Alario-Franco, M. A. J. Mater. Chem. 2003, 13, 1156–1160.Google Scholar
Garcia-Martin, S., Alario-Franco, M. A., Ehrenberg, H. and Amador, U. J. Am. Chem. Soc. 2004. 224 3587.CrossRefGoogle Scholar
Hiena, T. D., Mana, N. K. and Gargb, K.B. JMMM. 2003, 262, 508–513Google Scholar
Katrib, A., Logie, V., Peter, M., Wehrer, P., Hilaire, L. and Maire, G. J. Chim. Phys. Phys.- Chim. Biol. 1997, 94, 1923.Google Scholar
Jalili, H., Heinig, N. F. and Leung, K. T. Phys. Rev. B 2009, 79, 174427.Google Scholar
Larsson, S. Chem. Phys. Lett. 1976, 40, 362.Google Scholar
Van der Laan, G., Westra, C., Haas, C. and Sawatzky, G. A. Phys. Rev. B 1981, 23, 4369.Google Scholar
Parmigiani, F. and Sangaletti, L. J. Electron Spectrosc. Relat. Phenom. 1994, 66, 223.CrossRefGoogle Scholar
Vasquez, R. P., Novikov, D. L., Freeman, A. J. and Siegal, M. P. Phys. Rev. B 1997 -I, 55, 21.Google Scholar
Parmigiani, F., Depero, L. E., Minerva, T. and Torrance, J. B. J. Electron Spectrosc. Relat. Phenom. 1992, 58, 315.Google Scholar
Parmigiani, F. and Sangaletti, L. J. Electron Spectrosc. Relat. Phenom. 1994, 66, 223.Google Scholar
Parmigiani, F., Pacchioni, G., Illas, F. and Bagus, P.S.J. Electron Spectrosc. Relat. Phenom. 1992, 59, 255.Google Scholar
Parmigiani, F., Shen, Z. X., Mitzi, D. B., Lindau, I., Spicer, W.E. and Kapitulnik, A. Phys. Rev. B 1991, 43, 3085.Google Scholar
Fink, J., Niicker, N., PeUegrin, E., Romberg, H., Alexander, M. and Knupfer, M. J. Electron Spectrosc. Relat. Phenom. 1994, 66, 395.Google Scholar
Martinho, H., Martin, A. A., Moreno, N. O., Sanjurjo, J. A., Rettori, C., Oseroff, S. B., Fisk, Z., Pagliuso, P. G. and Sarrao, J. L. Physica B 2001, 305, 48–55.Google Scholar