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A heptamethine cyanine dye suitable as antenna in biohybrids based on bacterial photosynthetic reaction center

Published online by Cambridge University Press:  19 December 2018

Roberta Ragni
Affiliation:
Dipartimento di Chimica, Università degli Studi di Bari “Aldo Moro”, via Orabona 4, I-70126 Bari
Gabriella Leone
Affiliation:
Dipartimento di Chimica, Università degli Studi di Bari “Aldo Moro”, via Orabona 4, I-70126 Bari
Simona la Gatta
Affiliation:
Dipartimento di Chimica, Università degli Studi di Bari “Aldo Moro”, via Orabona 4, I-70126 Bari Istituto per i Processi Chimico-Fisici CNR-IPCF, Dipartimento di Chimica, via Orabona 4, I-70126 Bari
Giorgio Rizzo
Affiliation:
Dipartimento di Chimica, Università degli Studi di Bari “Aldo Moro”, via Orabona 4, I-70126 Bari
Marco Lo Presti
Affiliation:
Dipartimento di Chimica, Università degli Studi di Bari “Aldo Moro”, via Orabona 4, I-70126 Bari
Vincenzo De Leo
Affiliation:
Dipartimento di Chimica, Università degli Studi di Bari “Aldo Moro”, via Orabona 4, I-70126 Bari
Francesco Milano
Affiliation:
CNR-ISPA, Institute of Sciences of Food Production, Lecce Unit, Via Prov.le Monteroni, 73100Lecce, Italy.
Massimo Trotta*
Affiliation:
Istituto per i Processi Chimico-Fisici CNR-IPCF, Dipartimento di Chimica, via Orabona 4, I-70126 Bari
G. M. Farinola*
Affiliation:
Dipartimento di Chimica, Università degli Studi di Bari “Aldo Moro”, via Orabona 4, I-70126 Bari
*
* Authors to whom correspondence should be addressed [email protected][email protected]
* Authors to whom correspondence should be addressed [email protected][email protected]
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Abstract:

Sunlight is the most environmental friendly energy source available on Earth; many efforts devoted to design artificial photoconversion systems are ongoing, nevertheless they are still expensive and poorly efficient. Photoconversion devices made with organic-biological hybrids, or biohybrids, based on the photosynthetic reaction center (RC) have been introduced. In these systems, the photoenzyme is garnished with artificial antennas to enhance the photoactivity of the RC. Here we present a newly synthesized heptamethine cyanine dye that fulfills requisites to act as efficient RC light harvesting antenna.

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Articles
Copyright
Copyright © Materials Research Society 2018 

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Footnotes

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Permanent address: Istituto per i Processi Chimico-Fisici CNR-IPCF.

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