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Electrosynthesis of thin films of polythiophenes containing pyrene groups and flexible spacers, useful in the preparation of graphene polymer composites

Published online by Cambridge University Press:  04 November 2019

Bianca X. Valderrama-García ,
Israel González-Méndez ,
Alix Sournia-Saquet ,
Marine Tasse ,
Kathleen I. Moineau-Chane Ching  and
Ernesto Rivera
Bianca X. Valderrama-García
Affiliation:
Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior Ciudad Universitaria C.P.04510, Ciudad de México, México. CNRS; LCC (Laboratoire de Chimie de Coordination); 205, route de Narbonne, 31077Toulouse, France
Israel González-Méndez
Affiliation:
Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior Ciudad Universitaria C.P.04510, Ciudad de México, México.
Alix Sournia-Saquet
Affiliation:
CNRS; LCC (Laboratoire de Chimie de Coordination); 205, route de Narbonne, 31077Toulouse, France Université de Toulouse; UPS, INP; LCC; 31077Toulouse, France
Marine Tasse
Affiliation:
CNRS; LCC (Laboratoire de Chimie de Coordination); 205, route de Narbonne, 31077Toulouse, France Université de Toulouse; UPS, INP; LCC; 31077Toulouse, France
Kathleen I. Moineau-Chane Ching*
Affiliation:
CNRS; LCC (Laboratoire de Chimie de Coordination); 205, route de Narbonne, 31077Toulouse, France Université de Toulouse; UPS, INP; LCC; 31077Toulouse, France
Ernesto Rivera*
Affiliation:
Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior Ciudad Universitaria C.P.04510, Ciudad de México, México.
*
*[email protected] (K. M. C.); Tel.: +33 561 33 31 33 [email protected] (E.R.), Tel.: +52 55 56 22 47 33
*[email protected] (K. M. C.); Tel.: +33 561 33 31 33 [email protected] (E.R.), Tel.: +52 55 56 22 47 33
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Abstract

Thin polythiophene films were prepared by electrodeposition, using two novel thiophene monomers containing a pyrene unit linked via a flexible spacer. The obtained polymers have a suitable architecture for the further preparation of polymer composites with graphene via π-π interactions. Physicochemical characterization of the precursor polymers demonstrated that the resulting films are made of homogeneous electroactive polythiophene with pendant pyrene units regularly located on the polymer surface. These compounds are highly emissive and easily form excimers as other high pyrene content polymers. The polymer emission can be drastically quenched by the interaction with graphene after dipping the film into an aqueous suspension of reduced graphite oxide. The presence of aggregated graphene onto pyrene rich content areas by non-covalent interactions has been confirmed by AFM analysis. This kind of polythiophene/pyrene thin films showed to be a good matrix for the elaboration of fluorescent polymer composites.

Keywords

graphenepolymercomposite
Type
Articles
Information
MRS Advances , Volume 4 , Issue 59-60: International Materials Research Congress XXVIII , 2019 , pp. 3233 - 3242
Copyright
Copyright © Materials Research Society 2019 

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