Hostname: page-component-cc8bf7c57-hbs24 Total loading time: 0 Render date: 2024-12-11T22:09:39.605Z Has data issue: false hasContentIssue false
  • English
  • Français

Template-Synthesis of Conjugated Poly(3-Hexylselenophene) (P3HS) Nanofibers Using Femtosecond Laser Machined Fused Silica Templates

Published online by Cambridge University Press:  08 May 2017

L. Costa ,
M. Al-Hashimi ,
M. Heeney ,
A. Terekhov ,
D. Rajput ,
W. Hofmeister  and
A. Verma
L. Costa
Affiliation:
Department of Materials Science and Engineering, University of Tennessee - Knoxville, Tullahoma, Tennessee 37388, USA Center for Laser Applications, University of Tennessee Space Institute, Tullahoma, Tennessee 37388, USA
M. Al-Hashimi
Affiliation:
Department of Chemistry, Texas A&M University at Qatar, P.O. Box 23874, Doha, Qatar
M. Heeney
Affiliation:
Department of Chemistry and Centre for Plastic Electronics, Imperial College London, London SW7 2AZ, UK
A. Terekhov
Affiliation:
Center for Laser Applications, University of Tennessee Space Institute, Tullahoma, Tennessee 37388, USA
D. Rajput
Affiliation:
Department of Materials Science and Engineering, University of Tennessee - Knoxville, Tullahoma, Tennessee 37388, USA Center for Laser Applications, University of Tennessee Space Institute, Tullahoma, Tennessee 37388, USA
W. Hofmeister
Affiliation:
Department of Materials Science and Engineering, University of Tennessee - Knoxville, Tullahoma, Tennessee 37388, USA Center for Laser Applications, University of Tennessee Space Institute, Tullahoma, Tennessee 37388, USA
A. Verma*
Affiliation:
Department of Electrical Engineering & Computer Science, Texas A&M University - Kingsville, Kingsville, TX 78363, USA
*
*(Email: [email protected])
Get access

Abstract:

We report on the preparation of conjugated polymer nanofibers via template-synthesis. A femtosecond laser machined fused silica template, with a micro-patterned array of high-aspect ratio surface nanopores, was first spin-coated with a polyvinyl alcohol (PVA) solution to form a water-soluble release layer. The PVA-lined template was then coated with a conjugated poly(3-hexylselenophene) (P3HS) – solvent solution. The solvent was allowed to dissipate, and the resulting {template / PVA liner / conjugated P3HS film} stack was then submerged in water to dissolve the PVA and release the conjugated polymer film from the template. The resulting conjugated polymer film exhibits an array of micro-patterned polymer nanofibers that constitute a negative replica of the PVA-lined template. The nanofibers come arranged in a vertical architecture that spans over the surface of the supporting film.

Keywords

nanostructurepolymerorganic
Type
Articles
Information
MRS Advances , Volume 2 , Issue 51: Electronic Devices and Materials , 2017 , pp. 2957 - 2960
Copyright
Copyright © Materials Research Society 2017 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Rajput, D., Costa, L., Lansford, K., Terekhov, A., and Hofmeister, W., ACS Appl. Mater. Interfaces 5(1), 1–5 (2013).Google Scholar
Rajput, D., Costa, L., Terekhov, A., Lansford, K., and Hofmeister, W., Nanotechnology 23, 105304 (2012).Google Scholar
Hofmeister, L.H., Costa, L., Balikov, D.A., Crowder, S.W., Terekhov, A., Sung, H.-J., and Hofmeister, W.H., J. Biol. Eng. 9(18), (2015).Google Scholar
Pensabene, V., Costa, L., Terekhov, A., Gnecco, J.S., Wikswo, J.P., and Hofmeister, W.H., ACS Appl. Mater. Interfaces 8(34), 22629–22636 (2016).Google Scholar
Rajput, D., Crowder, S.W., Hofmeister, L., Costa, L., Sung, H.-J., and Hofmeister, W., Colloid Surf. B-Biointerfaces 102, 111–116 (2013).Google Scholar
Choi, D., Kim, H., Persson, N., Chu, P.-H., Chang, M., Kang, J.-H., Graham, S., and Reichmanis, E., Chem. Mat. 28(4), 1196–1204 (2016).Google Scholar
Printz, A.D., and Lipomi, D.J., Appl. Phys. Rev. 3, 021302 (2016).Google Scholar
Oosterhout, S.D., Wienk, M.M., Al-Hashimi, M., Heeney, M., and Janssen, R.A.J., J. Phys. Chem. C 115(38), 18901–18908 (2011).Google Scholar
Bannock, J.H., Al-Hashimi, M., Krishnadasan, S.H., Halls, J.J.M., Heeney, M., and de Mello, J.C., Mater. Horiz. 1, 214–218 (2014).CrossRefGoogle Scholar
Tsoi, W.C., James, D.T., Domingo, E.B., Kim, J.S., Al-Hashimi, M., Murphy, C.E., Stingelin, N., Heeney, M., and Kim, J.-S., ACS Nano 6(11), 9646–9656 (2012).Google Scholar
Lilliu, S., Agostinelli, T., Verploegen, E., Pires, E., Hampton, M., Al- Hashimi, M., Heeney, M.J., Toney, M.F., Nelson, J., and Macdonald, J.E., Macromol. Rapid. Commun. 32, 1454–1460 (2011).Google Scholar
Martin, C.R., Chem. Mat. 8(8), 1739–1746, (1996).Google Scholar
Martin, J., and Mijangos, C., Langmuir 25, 1181–1187 (2009).Google Scholar
Martin, J., Maiz, J., Sacristan, J., and Mijangos, C., Polymer 53, 1149–1166 (2012).Google Scholar
Steinhart, M., Wendorff, J.H., Greiner, A., Wehrspohn, R.B., Nielsch, K., Schilling, J., Choi, J., and Gosele, U., Science 296, 1997 (2002).CrossRefGoogle Scholar
Schlitt, S., Greiner, A., and Wendorff, J.H., Macromolecules 41, 3228–3234 (2008).Google Scholar