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Study of the performance of SnxSbySz/carbon nanofibers composite as anode of sodium-ion batteries

Published online by Cambridge University Press:  09 October 2020

L.A. Rodríguez-Guadarrama ,
J. Escorcia-García Open the ORCID record for J. Escorcia-García [Opens in a new window] ,
E. Quiroga-González  and
I.L. Alonso-Lemus
L.A. Rodríguez-Guadarrama
Affiliation:
CINVESTAV, Unidad Saltillo, Sustentabilidad de los Recursos Naturales y Energía, Av. Industria Metalúrgica 1062, Parque Industrial, Ramos Arizpe25900, Coahuila, Mexico
J. Escorcia-García
Affiliation:
CONACYT-CINVESTAV, Unidad Saltillo, Av. Industria Metalúrgica 1062, Parque Industrial, Ramos Arizpe25900, Coahuila, México
E. Quiroga-González
Affiliation:
Institute of Physics, Benemérita Universidad Autónoma de Puebla, San Claudio and 184 Sur 72574, Puebla, Mexico
I.L. Alonso-Lemus*
Affiliation:
CONACYT-CINVESTAV, Unidad Saltillo, Sustentabilidad de los Recursos Naturales y Energía, Av. Industria Metalúrgica 1062, Parque Industrial, Ramos Arizpe25900, Coahuila, México
*
*Email: I.L. Alonso-Lemus ([email protected])
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Abstract

Sodium-ion batteries (SIBs) have emerged as a promising alternative for energy storage. In this work, it has been synthesized a nanocomposite material of SbxSbySz/Carbon nanofibers (CNFs) using low-cost synthesizing methods. First, CNFs have been obtained by electrospinning method with subsequent carbonation at 700°C. Afterward, a SbxSbySz thin coating is deposited on the CNFs by chemical bath deposition technique to obtain the SbxSbySz/CNFs. In order to obtain the SnSb2S4 crystalline phase, the composite is heated at 300°C in nitrogen atmosphere. The evaluation of this nanocomposite as the anode for SIBs has a reversible discharge capacity of 180 mAh g-1 and a columbic efficiency of 61.4% after 9 cycles. On the other hand, the resistance associated to the charge transfer to the CNFs decreases from 115.03 Ω to 77.86 Ω due to the incorporation of SnxSbySz. Finally, an easy and inexpensive route has been proposed for the synthesis of SbxSbySz/CNFs composite with great potential to be used as anode material for SIBs.

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Articles
Information
MRS Advances , Volume 5 , Issue 57-58: International Materials Research Congress XXIX , 2020 , pp. 2917 - 2927
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Copyright
Copyright © The Author(s), 2020, published on behalf of Materials Research Society by Cambridge University Press

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