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Nanocrystallization and Recoilless Fraction Determination of Fe68.5Co5Nb3Cu1Si15.5B7 Ferromagnetic Alloy

Published online by Cambridge University Press:  21 January 2019

Monica Sorescu  and
Kevin Byerly
Monica Sorescu*
Affiliation:
Duquesne University, Department of Physics, Fisher Hall, 600 Forbes Avenue, Pittsburgh, PA15282
Kevin Byerly
Affiliation:
U.S. Department of Energy, National Energy Technology Laboratory, 626 Cochrans Mill Road, Pittsburgh, PA15236
*
*(Email: [email protected])
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Abstract

Amorphous alloy Fe68.5Co5Nb3Cu1Si15.5B7 was obtained by melt spinning. Samples cut from the foil were annealed at 450, 550, 650 and 750 °C in a vacuum furnace. 57Fe Mӧssbauer spectroscopy was used to identify the crystalline phases formed and the orientation of the magnetic moments based on the refined values of the hyperfine parameters. The spectra of the samples annealed at 550, 650 and 750 °C were indicative of nanocrystallization, with the magnetic moments reoriented out-of-plane for the last sample. This behavior is in contradistinction to that of the Co-rich system, which was totally crystallized at these annealing temperatures. Our results show that small Co additions can lead to the formation of nanostructures over a whole range of annealing temperatures. A new series of Mӧssbauer spectra was obtained by recording simultaneously the intensity transmitted by a superposition of the sample with the stainless steel etalon, based on the dual absorber method previously introduced by us. The values of the recoilless fraction could be derived from the relative spectral areas. The f factor maintained values close to 0.7 for all samples measured, but dropped to 0.37 for the sample annealed at 750 °C. This behavior could be related to the presence of elastic stresses in the system, which caused the out-of-plane reorientation of the magnetic moment directions.

Keywords

magnetic propertiesMӧssbauer effectamorphous
Type
Articles
Information
MRS Advances , Volume 4 , Issue 25-26: Processing and Manufacturing , 2019 , pp. 1449 - 1455
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Copyright
Copyright © Materials Research Society 2019 

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References

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