Hostname: page-component-586b7cd67f-gb8f7 Total loading time: 0 Render date: 2024-11-26T16:59:10.821Z Has data issue: false hasContentIssue false
  • English
  • Français

Mechanically Compliant Electrodes and Dielectric Elastomers from PEG-PDMS Copolymers

Published online by Cambridge University Press:  24 May 2016

Aliff Hisyam A Razak ,
Frederikke Bahrt Madsen  and
Anne Ladegaard Skov
Aliff Hisyam A Razak
Affiliation:
Danish Polymer Center, Department of Chemical and Biochemical Engineering, Technical University of Denmark, Building 227, 2800 Kgs. Lyngby, Denmark. Faculty of Engineering Technology, University of Tun Hussein Onn Malaysia, 86400 Parit Raja, Batu Pahat, Johor, Malaysia.
Frederikke Bahrt Madsen
Affiliation:
Danish Polymer Center, Department of Chemical and Biochemical Engineering, Technical University of Denmark, Building 227, 2800 Kgs. Lyngby, Denmark.
Anne Ladegaard Skov*
Affiliation:
Danish Polymer Center, Department of Chemical and Biochemical Engineering, Technical University of Denmark, Building 227, 2800 Kgs. Lyngby, Denmark.
*
*(Email: [email protected])
Get access

Abstract

Soft conducting elastomers have been prepared from polydimethylsiloxane-polyethyleneglycol (PDMS-PEG) copolymer and surfactant-stabilized multi-walled carbon nanotubes (MWCNTs). The copolymer was chain-extended with PDMS of molecular weight 17.2 kg mol-1 in order to obtain a crosslinkable PDMS with molecular weight around 20 – 30 kg mol-1. MWCNTs were treated with surfactant and sonicated for better dispersion in the polymer matrix. The conductivity and mechanical properties of conducting elastomers were thoroughly investigated including stress and strain at break. The developed conducting elastomers showed high conductivity combined with inherent softness. The high conductivity and softness, PDMS-PEG copolymers with incorporated MWCNTs hold great promises as compliant and highly stretchable electrodes for stretchable devices such as electro-mechanical transducers.

Keywords

dielectric propertieselastic propertiesactuator
Type
Articles
Information
MRS Advances , Volume 1 , Issue 52: Soft Materials and Biomaterials , 2016 , pp. 3497 - 3508
Copyright
Copyright © Materials Research Society 2016 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Kim, D., Lu, N., Ma, R., Kim, Y.-S., Kim, R.-H., Wang, S., Wu, J., Won, S. M., Tao, H., Islam, A., Yu, K. J., Kim, T., Chowdhury, R., Ying, M., Xu, L., Li, M., Chung, H.-J., Keum, H., McCormick, M., Liu, P., Zhang, Y., Omenetto, F. G., Huang, Y., Coleman, T., and Rogers, J. A., “Epidermal electronics,” Science, vol. 333, pp. 838–843, 2011.Google Scholar
Rosset, S. and Shea, H. R., “Flexible and stretchable electrodes for dielectric elastomer actuators,” Appl. Phys. A Mater. Sci. Process., vol. 110, pp. 281–307, 2013.CrossRefGoogle Scholar
Lipomi, D. J. and Bao, Z., “Stretchable, elastic materials and devices for solar energy conversion,” Energy Environ. Sci., vol. 4, no. 9, pp. 3314–3328, 2011.Google Scholar
A Razak, A. H., Szabo, P., and Skov, A. L., “Enhancement of dielectric permittivity by incorporating PDMS-PEG multiblock copolymers in silicone elastomers,” RSC Adv., vol. 5, pp. 53054–53062, 2015.Google Scholar
Thess, A., Lee, R., Nikolaev, P., Dai, H., Petit, P., Xu, C., Lee, Y. H., Kim, S. G., Rinzler, A. G., Colbert, D. T., Scuseria, G. E., Tománek, D., Fischer, J. E., Smalley, R. E., Robert, J., and Tomanek, D., “All use subject to JSTOR Terms and Conditions Crystalline Ropes of Metallic Carbon Nanotubes,” Science, vol. 273, pp. 483–487, 2014.Google Scholar
Ma, P. C., Wang, S. Q., Kim, J.-K., and Tang, B. Z., “In-Situ amino functionalization of carbon nanotubes using ball milling,” J. Nanosci. Nanotechnol., vol. 9, pp. 749–753, 2009.Google Scholar
Geng, Y., Liu, M. Y., Li, J., Shi, X. M., and Kim, J. K., “Effects of surfactant treatment on mechanical and electrical properties of CNT/epoxy nanocomposites,” Compos. Part A Appl. Sci. Manuf., vol. 39, no. 12, pp. 1876–1883, 2008.Google Scholar
Park, K. C., Hayashi, T., Tomiyasu, H., Endo, M., and Dresselhaus, M. S., “Progressive and invasive functionalization of carbon nanotube sidewalls by diluted nitric acid under supercritical conditions,” J. Mater. Chem., vol. 15, no. 3, pp. 407–411, 2005.Google Scholar
Kim, Y. J., Shin, T. S., Do Choi, H., Kwon, J. H., Chung, Y.-C., and Yoon, H. G., “Electrical conductivity of chemically modified multiwalled carbon nanotube/epoxy composites,” Carbon N. Y., vol. 43, pp. 23–30, 2005.Google Scholar
Rastogi, R., Kaushal, R., Tripathi, S. K., Sharma, A. L., Kaur, I., and Bharadwaj, L. M., “Comparative study of carbon nanotube dispersion using surfactants,” J. Colloid Interface Sci., vol. 328, no. 2, pp. 421–428, 2008.Google Scholar
Vladár, A. E., “Strategies for scanning electron microscopy sample preparation and characterization of multiwall carbon nanotube polymer composites,” NIST Spec. Publ. 1200-17, vol. 1, pp. 1–16, 2015.Google Scholar
Yu, L., Madsen, F. B., Hvilsted, S., and Skov, A. L., “High energy density interpenetrating networks from ionic networks and silicone,” Proc. SPIE, vol. 9430, pp. 94300T–1–94300T–11, 2015.Google Scholar
Wu, D. Y., Meure, S., and Solomon, D., “Self-healing polymeric materials: A review of recent developments,” Prog. Polym. Sci., vol. 33, no. 5, pp. 479–522, 2008.Google Scholar