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Interfacial Reaction Mechanism between Molten Ag-Cu-Based Active Brazing Alloys and Untreated or Pre-Oxidized PLS-SiC

Published online by Cambridge University Press:  27 September 2019

J. López-Cuevas Open the ORCID record for J. López-Cuevas [Opens in a new window] ,
J.C. Rendón-Angeles ,
J.L. Rodríguez-Galicia  and
C.A. Gutiérrez-Chavarría
J. López-Cuevas*
Affiliation:
Cinvestav Unidad Saltillo, Calle Industria Metalúrgica No. 1062, Parque Industrial Saltillo - Ramos Arizpe, 25900, Ramos Arizpe, Coahuila, México.
J.C. Rendón-Angeles
Affiliation:
Cinvestav Unidad Saltillo, Calle Industria Metalúrgica No. 1062, Parque Industrial Saltillo - Ramos Arizpe, 25900, Ramos Arizpe, Coahuila, México.
J.L. Rodríguez-Galicia
Affiliation:
Cinvestav Unidad Saltillo, Calle Industria Metalúrgica No. 1062, Parque Industrial Saltillo - Ramos Arizpe, 25900, Ramos Arizpe, Coahuila, México.
C.A. Gutiérrez-Chavarría
Affiliation:
Cinvestav Unidad Saltillo, Calle Industria Metalúrgica No. 1062, Parque Industrial Saltillo - Ramos Arizpe, 25900, Ramos Arizpe, Coahuila, México.
*
*Author to whom any correspondence should be addressed ([email protected].)
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Abstract

Based on wettability and reaction interfaces previously reported, as well as on thermodynamic considerations, a likely mechanism has been proposed for the chemical interaction taking place at the metal/ceramic interface during wettability experiments carried out by the so-called “sessile drop” method. The experiments involved three Ag-Cu-based brazing alloys [Cusil (Ag-28wt.%Cu), Cusil-ABA (Ag-34.6wt.%Cu-1.58wt.%Ti) and Incusil-ABA (Ag-26.6wt.%Cu-12.4wt.%In-0.89wt.%Ti)] and as polished and pre-oxidized pressure-less sintered silicon carbide (PLS-SiC), with a total holding time of 90 minutes at 850 °C, under a Zr sponge-gettered vacuum of 10-4/10-5 Torr.

Keywords

brazinginterfacejoiningTichemical reaction
Type
Articles
Information
MRS Advances , Volume 4 , Issue 57-58: International Materials Research Congress XXVIII , 2019 , pp. 3153 - 3161
Copyright
Copyright © Materials Research Society 2019 

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