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Electrical Characterization of Silicon - Nickel Iron Oxide Heterojunctions

Published online by Cambridge University Press:  19 July 2019

James N. Talbert
Affiliation:
Department of Physics, Texas State University, 78666San Marcos, Texas, United States
Samuel R. Cantrell
Affiliation:
Department of Physics, Texas State University, 78666San Marcos, Texas, United States
Md. Abdul Ahad Talukder
Affiliation:
Materials Science Engineering and Research Commercialization, Department of Physics, Texas State University, 78666San Marcos, Texas, United States.
Luisa M. Scolfaro
Affiliation:
Department of Physics, Texas State University, 78666San Marcos, Texas, United States
Wilhelmus J. Geerts*
Affiliation:
Department of Physics, Texas State University, 78666San Marcos, Texas, United States
*
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Abstract

The electrical properties of Radio Frequency Sputtered NiFeO and NiO films deposited on n and p-type Silicon is investigated for two different oxygen flows. Rectifying properties for Ni0.8Fe0.2O1+ α on n-Si showed Iforward/Ireverse >10,000 for α>0 and Iforward/Ireverse >50 for α<0. Both types of devices have opposite forward biases. Results suggest that NiFeO sputtered at high oxygen flow is p-type. For NiO and NiFeO on p-Si no strong rectifying properties were observed. The specific contact resistivity of Pt/Ni0.9Fe0.1O1+ α (α>0) was estimated from the difference between the two and four-point probe resistances (0.0007 ± 0.0003 Ω cm2). Using density functional theory calculations, density of state and charge density plots were obtained for systems modelled after experiment, showing that states introduced by O vacancies in NiFeO are localized and prefer locations near Ni explaining the observed hysteresis effects in the IV curves of devices sputtered at low oxygen flow.

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Articles
Copyright
Copyright © Materials Research Society 2019 

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References

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